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2012 Fiscal Year Final Research Report

Study of stereodynamics for intramolecular magnetism by means of spin-polarized metastable atomic beams

Research Project

  • PDF
Project/Area Number 20340102
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Atomic/Molecular/Quantum electronics
Research InstitutionTohoku University

Principal Investigator

KISHIMOTO Naoki  東北大学, 大学院・理学研究科, 准教授 (60302080)

Co-Investigator(Renkei-kenkyūsha) OHNO Koichi  豊田理化学研究所, フェロー (60012499)
Project Period (FY) 2008 – 2012
Keywords原子衝突反応 / 電子スピン / 反応動力学 / 電子構造 / 固体表面 / 衝突エネルギー
Research Abstract

In Penning ionization of high-spin open-shell compounds (M) by collision with an open-shell triplet He* metastable atomic beam, we have investigated complex electronic structure and strong He*-M interaction by the collision-energy-resolved/electron-energy- resolved 2D spectroscopy. We have found that the change of electronic states of deposited organic molecules (five-memberd hetero cyclic molecules) was started by open-shell alkali metal atoms with the gradual heating of the metal surface, which was observed by the collision energy dependence of partial ionization cross sections with the electron-energy/collision-energy-resolved 2D electron spectroscopy.

  • Research Products

    (31 results)

All 2013 2012 2011 2010 2009 2008

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (24 results)

  • [Journal Article] Two-Dimensional Penning Ionization Electron Spectroscopy of Open-Shell Metallocenes: Outer Valence Ionic States of Vanadocene and Nickelocene2013

    • Author(s)
      Naoki Kishimoto, Miku Kimura, and Koichi Ohno
    • Journal Title

      J. Phys. Chem.A

      Volume: 117 Pages: 3025-3033

    • DOI

      DOI:10.1021/jp310308k

    • Peer Reviewed
  • [Journal Article] Two-dimensional Penning Ionization Electron Spectroscopy of CH_3I and CH_2I_2 by He*(2^3S) Metastable Atoms2010

    • Author(s)
      Naoki Kishimoto, Andriy Borodin, Takuya Horio, Masakazu Yamazaki, and Koichi Ohno
    • Journal Title

      J. Phys. Conf. Ser.

      Volume: 235 Pages: 012014(1-8)

    • DOI

      DOI:10.1088/1742-6596/235/1/012014

    • Peer Reviewed
  • [Journal Article] Collision-energy-resolved metastable impact electron spectroscopy of thiophene and2,2'-bithiophene :Stereodynamics in gas phase and adsorbed layer on Ag(110)2010

    • Author(s)
      S. Kudo, N. Kishimoto, and K. Ohno
    • Journal Title

      J. Phys. Conf.Ser.

      Volume: 235 Pages: 012012(1-8)

    • DOI

      DOI:10.1088/1742-6596/235/1/012012

    • Peer Reviewed
  • [Journal Article] Valence ionized states of iron pentacarbonyl and η^5-cyclopentadienyl cobalt dicarbonyl studied by symmetry-adapted cluster-configuration interaction calculation and collision-energy resolved Penning ionization electron spectroscopy2010

    • Author(s)
      Ryoichi Fukuda, Masahiro Ehara, Hiroshi Nakatsuji, Naoki Kishimoto, and Koichi Ohno
    • Journal Title

      J. Chem. Phys.

      Volume: 132 Pages: 084302(1-12)

    • DOI

      DOI:10.1063/1.3319778

    • Peer Reviewed
  • [Journal Article] Anisotropic Interactions and Valence Ionic States of Dibenzenechromium Observed by Collision-Energy-Resolved Penning Ionization Electron Spectroscopy with He*(2^3S) Metastable Atoms2009

    • Author(s)
      Naoki Kishimoto and Koichi Ohno
    • Journal Title

      J. Phys. Conf. Ser.

      Volume: 185 Pages: 012020(1-4)

    • DOI

      DOI:10.1088/1742-6596/185/1/012020

    • Peer Reviewed
  • [Journal Article] OuterValence Ionic States of Cr(CO)_6 and(η^5-C_5H_5)Co(CO)_2 Observed by Two-dimensionalPenning Ionization Electron Spectroscopy2009

    • Author(s)
      Naoki Kishimoto and Koichi Ohno
    • Journal Title

      J. Phys. Chem. A

      Volume: 113 Pages: 14559-14564

    • DOI

      DOI:10.1021/jp9040524

    • Peer Reviewed
  • [Journal Article] Stereodynamics and Outer Valence Ionic States of Ferrocene in Collisional Ionization with a He*(2^3S) Metastable Atom by Two-Dimensional Penning Ionization Electron Spectroscopy2009

    • Author(s)
      Naoki Kishimoto and Koichi Ohno
    • Journal Title

      J. Phys. Chem. A

      Volume: 113 Pages: 521-526

    • DOI

      DOI:10.1021/jp805361z

    • Peer Reviewed
  • [Presentation] Valence ionized states of open-shell and closed-shell organometallic compounds studied by two-dimensional Penning ionization electron spectroscopy and ab initio MO calculations2013

    • Author(s)
      Naoki Kishimoto
    • Organizer
      International Symposium on (e, 2e), Double Photoionization and Related Topics & the 17th International Symposium on Polarization and Correlation in Electronic andAtomic Collisions
    • Place of Presentation
      中国安徽省合肥市
    • Year and Date
      20130801-03
  • [Presentation] 遷移金属錯体超薄膜の準安定励起原子衝突2次元電子分光2012

    • Author(s)
      岸本直樹、高野雄大
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京大学
    • Year and Date
      2012-09-20
  • [Presentation] Collision-energy/electron- energy-resolved two-dimensional Penning ionization electron spectroscopy of open-shelltransition metal complexes2012

    • Author(s)
      Naoki Kishimoto
    • Organizer
      2nd InternationalSymposium on Electron Momentum Spectroscopy
    • Place of Presentation
      ベルギー国ブッリュッセル市
    • Year and Date
      2012-08-23
  • [Presentation] 準安定励起原子衝突2次元電子分光法で観測する固体表面上の有機分子-アルカリ金属系の反応2012

    • Author(s)
      岸本直樹
    • Organizer
      原子衝突学会第7回年会
    • Place of Presentation
      電気通信大学
    • Year and Date
      2012-07-28
  • [Presentation] 準安定励起原子衝突2次元電子分光によるアルカリ金属原子-有機分子薄膜の電子構造の研究2012

    • Author(s)
      岸本直樹、工藤翔、重田由香
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学
    • Year and Date
      2012-03-27
  • [Presentation] 固体表面に吸着したアルカリ金属-有機分子薄膜の準安定励起原子衝突2次元電子分光2011

    • Author(s)
      岸本直樹、工藤翔、重田由香
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌
    • Year and Date
      2011-09-23
  • [Presentation] 準安定励起原子衝突2次元電子分光法による固体表面吸着分子の電子構造変化の研究2011

    • Author(s)
      岸本直樹、工藤翔
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟大学
    • Year and Date
      2011-03-28
  • [Presentation] 開殻励起原子衝突2次元電子分光法による低温銀系遷移金属錯体の2次元ペニングイオン化電子分光2010

    • Author(s)
      岸本直樹、木村美紅、大野公一
    • Organizer
      日本物理学会2010秋季大会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2010-09-26
  • [Presentation] 2次元ペニングイオン化電子分光法による開殻系メタロセン類の電子構造の研究2010

    • Author(s)
      岸本直樹、木村美紅、大野公一
    • Organizer
      第4回分子科学討論会
    • Place of Presentation
      大阪大学
    • Year and Date
      2010-09-17
  • [Presentation] Two-dimensional Penning ionization electron spectroscopy of open-shell organometallic compounds, Ni(η^5-C_5H_5)_2 and V(η^5-C_5H_5)_22010

    • Author(s)
      N. Kishimoto, M. Kimura, K. Ohno
    • Organizer
      International Conference on Many Particle Spectroscopy of Atoms, Molecules, Clusters and Surfaces
    • Place of Presentation
      仙台市
    • Year and Date
      2010-09-05
  • [Presentation] 表面に吸着した芳香族化合物の準安定励起原子衝突2次元電子分光2010

    • Author(s)
      工藤翔、木村美紅、岸本直樹
    • Organizer
      日本物理学会第65回年次大会
    • Place of Presentation
      岡山大学
    • Year and Date
      2010-03-21
  • [Presentation] Two-Dimensional Metastable Impact Electron Spectroscopy of Methyl Halides in Gas Phase and Adsorbed on Metal Surface by Collision with He*(2^3S) Atoms2009

    • Author(s)
      Naoki Kishimoto, Sho Kudo, and Koichi Ohno
    • Organizer
      International Workshop on Electron Spectroscopy for Gas-phase molecules and solid surface 2009(IWES)
    • Place of Presentation
      松島市
    • Year and Date
      2009-10-13
  • [Presentation] Observation of anisotropic interaction between He* and five-memberd unsaturated heterocyclic compounds using two-dimensional metastable impact electron spectroscopy2009

    • Author(s)
      S. Kudo, N. Kishimoto, and K. Ohno
    • Organizer
      International Workshop on Electron Spectroscopy for Gas-phase molecules and solid surface 2009(IWES)
    • Place of Presentation
      松島市
    • Year and Date
      2009-10-13
  • [Presentation] Application of 2D metastable impact electron spectroscopy to five-membered unsaturated heterocyclic compounds for studyinganisotropic interaction with He*2009

    • Author(s)
      Sho Kudo, Naoki Kishimoto, and Koichi Ohno
    • Organizer
      11th International Conference on ElectronicSpectroscopy and Structure(ICESS-11)
    • Place of Presentation
      奈良市
    • Year and Date
      2009-10-08
  • [Presentation] ハロゲン化メチルの準安定励起原子衝突2次元電子分光:気相と固体表面の比較2009

    • Author(s)
      岸本直樹、工藤翔
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2009-09-24
  • [Presentation] Study ofanisotropic interaction between He* and metastable impact electron spectroscopy2009

    • Author(s)
      工藤翔、岸本直樹、大野公一
    • Organizer
      第25回化学反応討論会
    • Place of Presentation
      大宮
    • Year and Date
      2009-06-01
  • [Presentation] 準安定励起原子衝突2次元電子分光法による低温銀基板上に吸着したチオフェンおよび2,2'-ビチオフェンの観測2009

    • Author(s)
      工藤翔、岸本直樹、大野公一
    • Organizer
      日本化学会第89回春季年会
    • Place of Presentation
      日本大学
    • Year and Date
      2009-03-28
  • [Presentation] 銀基板に吸着したビニル基をもつ共役系有機分子の準安定励起原子衝突2次元電子分光2009

    • Author(s)
      扇悠輔、岸本直樹、大野公一
    • Organizer
      日本化学会第89回春季年会
    • Place of Presentation
      日本大学
    • Year and Date
      2009-03-28
  • [Presentation] 準安定励起原子衝突2次元電子分光法によるアジン類薄膜の立体反応ダイナミクスの研究2009

    • Author(s)
      工藤泰彦、岸本直樹、大野公一
    • Organizer
      日本化学会第89回春季年会
    • Place of Presentation
      日本大学
    • Year and Date
      2009-03-28
  • [Presentation] Development of New Techniques to Study Collisional Reaction Dynamics and Interaction Potential Energy Surfaces2008

    • Author(s)
      Naoki Kishimoto, Satoshi Maeda, and Koichi Ohno
    • Organizer
      The 8th Asian International Seminar on Atomic andMolecular Physics(AISAMP8)
    • Place of Presentation
      オーストラリア国パース市
    • Year and Date
      2008-11-27
  • [Presentation] Two-dimensional metastable impact electron spectroscopy of organic molecules adsorbed on a metal surface2008

    • Author(s)
      Naoki Kishimoto and Koichi Ohno
    • Organizer
      The 8th Asian International Seminar on Atomic and MolecularPhysics(AISAMP8)
    • Place of Presentation
      オーストラリア国パース市
    • Year and Date
      2008-11-26
  • [Presentation] Collision-energy-resolved metastable impact electron spectroscopy of molecules adsorbed on a metal surface2008

    • Author(s)
      Naoki Kishimoto
    • Organizer
      The 12th International Symposium of Stereodynamics ofChemical Reactions
    • Place of Presentation
      中国大連市
    • Year and Date
      2008-10-16
  • [Presentation] 準安定励起原子衝突2次元電子分光法による有機金属化合物超薄膜の構造と立体反応ダイナミクスの研究2008

    • Author(s)
      岸本直樹、大野公一
    • Organizer
      第2回分子科学討論会
    • Place of Presentation
      福岡
    • Year and Date
      2008-09-25
  • [Presentation] 準安定励起原子衝突2次元電子分光法による固体表面吸着系の観測:ナトリウムに誘起された複素五員環化合物の構造変化2008

    • Author(s)
      工藤翔、岸本直樹、大野公一
    • Organizer
      原子衝突研究協会第33回研究会
    • Place of Presentation
      北海道大学
    • Year and Date
      2008-08-05

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Published: 2014-08-29  

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