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2010 Fiscal Year Final Research Report

Local Electronic Structures in Molecular Interaction Systems Studied by Soft X-Ray Core Excited Spectroscopies

Research Project

  • PDF
Project/Area Number 20350014
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionInstitute for Molecular Science

Principal Investigator

KOSUGI Nobuhiro  Institute for Molecular Science, 光分子科学研究領域, 教授 (20153546)

Co-Investigator(Kenkyū-buntansha) SHIGEMASA Eiji  分子科学研究所, 極端紫外光研究施設, 准教授 (90226118)
Co-Investigator(Renkei-kenkyūsha) NAGASAKA Masanari  分子科学研究所, 光分子科学研究領域, 助教 (90455212)
YAMANE Hiroyuki  分子科学研究所, 光分子科学研究領域, 助教 (50402459)
Project Period (FY) 2008 – 2010
KeywordsX線吸収分光法 / 共鳴オージェ電子分光法 / X線発光分光法
Research Abstract

Local electronic structures of weak molecular interaction systems such as molecular clusters, liquids, and organic molecular solids were investigated by soft X-ray absorption spectroscopy and resonant Auger electron and emission spectroscopy after core excitation processes. The local structures of rare gas clusters and Kr/Xe mixed clusters were revealed by soft X-ray photoelectron spectroscopy. We developed a liquid cell for the soft X-ray absorption spectroscopy in a transmission mode, and revealed hydration structures of alkali metal cations in aqueous salt solutions. We also investigated the site-specific inter- molecular interaction in crystalline phthalocyanine films by X-ray emission spectroscopy.

  • Research Products

    (24 results)

All 2011 2010 2009 2008 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (12 results) Remarks (2 results)

  • [Journal Article] High-resolution soft X-ray photoelectron soectroscopy of liquid water2011

    • Author(s)
      K.Nishizawa, N.Kurahashi, K.Sekiguchi, T.Mizuno, Y.Ogi, T.Horio, M.Oura, N.Kosugi, T.Suzuki
    • Journal Title

      Phys.Chem.Chem.Phys. 13

      Pages: 413-417

    • Peer Reviewed
  • [Journal Article] Inner-shell spectroscopy and exchange interaction of Rydberg electrons bound by singly and doubly charged Kr and Xe atoms in small clusters2011

    • Author(s)
      M.Nagasaka, T.Hatsui, H.Setoyama, E.Ruhl, N.Kosugi
    • Journal Title

      J.Electron Spectrosc.Relat.Phenom. 183

      Pages: 29-35

    • Peer Reviewed
  • [Journal Article] Development of a liquid flow cell to measure soft X-ray absorption in transmission mode : A test for liquid water2010

    • Author(s)
      M.Nagasaka, T.Hatsui, T.Horigome, Y.Hamamura, N.Kosugi
    • Journal Title

      J.Electron Spectrosc.Relat.Phenom. 177

      Pages: 130-134

    • Peer Reviewed
  • [Journal Article] A systematic study of soft-X-ray spectra of poly(dG)-poly(dC) and poly(dA)-poly(dT) DNA duplexes2010

    • Author(s)
      W.Hua, H.Yamane, B.Gao, J.Jiang, S.Li, H.S.Kato, M.Kawai, T.Hatsui, Y.Luo, N.Kosugi, H.Agren
    • Journal Title

      J.Phys.Chem.B 114

      Pages: 7016-7021

    • Peer Reviewed
  • [Journal Article] Doppler effects in fragment autoionization following core-to-valence excitation in O_22010

    • Author(s)
      R.Guillemin, M.Simon, E.Shigemasa
    • Journal Title

      Phys.Rev.A 82

      Pages: 051401(R)(4)

    • Peer Reviewed
  • [Journal Article] Theoretical studies of angle-resolved ion yield spectra of core-to-valence transitions of acetylene2009

    • Author(s)
      V.Kimberg, N.Kosugi, F.Gel'mukhanov
    • Journal Title

      J.Chem.Phys. 130

      Pages: 114302(10)

    • Peer Reviewed
  • [Journal Article] Strong double excitation and open-shell features in the near-edge X-ray absorption fine structure spectroscopy of ferrocene and ferrocenium compounds2009

    • Author(s)
      E.Otero, N.Kosugi, S.Urquhart
    • Journal Title

      J.Chem.Phys. 131

      Pages: 114313(8)

    • Peer Reviewed
  • [Journal Article] Electronic state observation of inner organic thin films beneath electrodes2009

    • Author(s)
      H.S.Kato, R.Hirakawa, F.Yamauchi, T.Minato, M.Kawai, T.Hatsui, N.Kosugi
    • Journal Title

      J.Electron Spectrosc.Relat.Phenom. 174

      Pages: 93-99

    • Peer Reviewed
  • [Journal Article] Exchange interaction in Kr 3d excitations of small krypton clusters2008

    • Author(s)
      M.Nagasaka, T.Hatsui, N.Kosugi
    • Journal Title

      J.Electron Spectrosc.Relat.Phenom. 166-167

      Pages: 16-20

    • Peer Reviewed
  • [Journal Article] Electron dynamics in charge transfer-to-solvent states of aqueous chloride revealed by Cl^- 2p resonant Auger electron spectroscopy2008

    • Author(s)
      B.Winter, E.F.Aziz, N.Ottosson, M.Faubel, N.Kosugi, I.V.Hertel
    • Journal Title

      J.Am.Chem.Soc. 130

      Pages: 7130-7138

    • Peer Reviewed
  • [Presentation] Highly efficient soft X-ray emission spectrometer using a transmission grating2010

    • Author(s)
      H.Yamane, T.Hatsui, N.Kosugi
    • Organizer
      The International Chemical Congress of Pacific Basin Societies (Pacifichem 2010)
    • Place of Presentation
      Honolulu (USA).
    • Year and Date
      2010-12-18
  • [Presentation] 水溶液の軟X線吸収分光法:アルカリ金属イオン周辺の水の構造研究2010

    • Author(s)
      長坂将成,初井宇記,小杉信博
    • Organizer
      第4回分子科学討論会
    • Place of Presentation
      大阪大学(大阪)(優秀講演賞)
    • Year and Date
      2010-09-15
  • [Presentation] Molecular Inner-shell spectra of weakly bonding and interacting systems2010

    • Author(s)
      小杉信博
    • Organizer
      37^<th> International Conference on Vacuum Ultraviolet and X-ray Physics (VUV2010)
    • Place of Presentation
      Vancouver (Canada)(招待講演)
    • Year and Date
      2010-07-16
  • [Presentation] Structural changes of small Kr-Xe mixed clusters with different compositions studied by soft X-ray photoelectron spectroscopy2010

    • Author(s)
      M.Nagasaka, N.Kosugi, E.Ruhl
    • Organizer
      37th International Conference on Vacuum Ultraviolet and X-ray Physics (VUV2010)
    • Place of Presentation
      Vancouver (Canada).
    • Year and Date
      2010-07-16
  • [Presentation] Recent progress and future prospects of transmission-grating-based X-ray emission spectroscopy of functional materials2009

    • Author(s)
      H.Yamane, T.Hatsui, N.Kosugi
    • Organizer
      Workshop on Soft X-ray Scattering
    • Place of Presentation
      Hsinchu (Taiwan)(招待講演)
    • Year and Date
      2009-10-13
  • [Presentation] Bulk electronic structure of organic solids probed by soft X-ray emission spectroscopy using transmission-grating spectrometer2009

    • Author(s)
      H.Yamane, T.Hatsui, N.Kosugi
    • Organizer
      11th International Conference on Electronic Spectroscopy and Structure (ICESS2009)
    • Place of Presentation
      Nara (Japan).
    • Year and Date
      2009-10-07
  • [Presentation] Surface structure of Kr-Xe mixed clusters studied by soft x-ray photoelectron spectroscopy2009

    • Author(s)
      M.Nagasaka, N.Kosugi, E.Ruhl
    • Organizer
      11^<th> International Conference on Electronic Spectroscopy and Structure (ICESS2009)
    • Place of Presentation
      Nara (Japan).
    • Year and Date
      2009-10-06
  • [Presentation] Soft X-ray emission spectroscopy of organic solids2009

    • Author(s)
      H.Yamane, T.Hatsui, N.Kosugi
    • Organizer
      5th Workshop on Advanced Spectro- scopy of Organic Materials for Electronic Applications (ASOMEA-V)
    • Place of Presentation
      Krusenberg (Sweden)(招待講演)
    • Year and Date
      2009-10-02
  • [Presentation] 内殻励起から何がわかるか。その特徴と課題2009

    • Author(s)
      小杉信博
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      名古屋大学(愛知)(招待講演)
    • Year and Date
      2009-09-23
  • [Presentation] Geometry of small krypton clusters revealed by site dependent peak shifts in inner-shell spectroscopies2009

    • Author(s)
      M.Nagasaka, T.Hatsui, H.Setoyama, N.Kosugi, E.Ruhl
    • Organizer
      14^<th> International Conference on X-ray Absorption Fine Structure (XAFS14)
    • Place of Presentation
      Camerino (Italy).
    • Year and Date
      2009-07-27
  • [Presentation] Resonant Auger spectra of Kr clusters and aqueous chlorides2008

    • Author(s)
      小杉信博
    • Organizer
      21^<th> International Conference on X-ray and Inner-shell Processes (X08)
    • Place of Presentation
      Paris (France).(招待講演)
    • Year and Date
      2008-06-27
  • [Presentation] Surface site dependence of Rydberg states converging to the single Kr 3d and double Kr 4p ionizations in small Kr clusters2008

    • Author(s)
      M. Nagasaka, T.Hatsui, N. Kosugi
    • Organizer
      International Workshop on Photoionization (IWP2008)
    • Place of Presentation
      Satra Brunn (Sweden)
    • Year and Date
      2008-06-16
  • [Remarks] ホームページでの成果紹介

    • URL

      http://www.ims.ac.jp/topics/2008/090302.html

  • [Remarks]

    • URL

      http://www.ims.ac.jp/know/light/kosugi/kosugi.html

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Published: 2012-01-26   Modified: 2016-04-21  

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