Breakthrough of Organic Electrosynthesis Using Tiny Space

2010 Fiscal Year Self-evaluation Report

• Project/Area Number: 20350046
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Synthetic chemistry
• Research Institution: Yokohama National University (2010-2011); Tokyo Institute of Technology (2008-2009)
• Principal Investigator: ATOBE Mahito Tokyo Institute of Technology, 環境情報研究院, 教授 (90291351)
• Project Period (FY): 2008 – 2011
• Keywords: 反応場 / 有機電解合成

Research Abstract

本研究は反応場が微小空間であるマイクロリアクターの特徴を活用した全く新しい電解合成反応や電解システムの構築を目指すものであり、具体的には以下の4つのテーマを展開する。
1)支持電解質を必要としない環境調和型電解合成システムの開発
2)液-液平行流を活用した求核剤の電位に影響されない陽極置換反応システムの開発
3)微小空間を活用した電解発生活種同士のカップリング反応
4)両極での反応を活用するラセミアルコールのデラセミ化反応の創製

Research Products

• [Journal Article] Chemoselective Reaction System Using a Two Inlets Micro-flow Reactor : Application to Reductive Carbonyl Allylation (2010)
  • Author(s): Fumihiro AMEMIYA, Keishi FUSE, Toshio FUCHIGAMI, Mahito ATOBE,
  • Journal Title: Chem.Commun. 46 Pages: 2730-2732
  • Peer Reviewed
• [Journal Article] Liquid | Liquid Biphasic Electrochemistry in Ultra-turrax Dispersed Acetonitrile | Aqueous Electrolyte Systems, (2010)
  • Author(s): John D.WATKINS, Fumihiro AMEMIYA, Mahito ATOBE, Philip C.BULMAN-PAGE, Frank MARKEN
  • Journal Title: Electrochim.Acta 55 Pages: 8808-8814
  • Peer Reviewed
• [Journal Article] A New Approach to Size-Controlled Synthesis of Conducting Polymer Microspheres Using Pulsed Sonoelectrochemical Polymerization (2009)
  • Author(s): Mahito ATOBE, Kengo ISHIKAWA, Ryosuke ASAMI, Toshio FUCHIGAMI,
  • Journal Title: Angew.Chem.Int.Ed. 48 Pages: 6069-6072
  • Peer Reviewed
• [Journal Article] A Novel Electrosynthetic System for Anodic Substitution Reactions Using Parallel Laminar Flow in a Micro-Flow Reactor, (2008)
  • Author(s): Daisuke HORII, Fumihiro AMEMIYA, Toshio FUCHIGAMI, Mahito ATOBE
  • Journal Title: Chem.Eur.J. 14 Pages: 10382-10387
  • Peer Reviewed
• [Journal Article] Self-supported Paired Electrosynthesis Using a Micro-flow Reactor without Intentionally Added Electrolyte (2008)
  • Author(s): Fumihiro AMEMIYA, Daisuke HORII, Toshio FUCHIGAMI, Mahito ATOBE
  • Journal Title: J.Electrochem.Soc 155 Pages: E162-E165
  • Peer Reviewed
• [Presentation] Electrosynthetic Processes Using Unique Fields and Methods (2010)
  • Author(s): Mahito ATOBE
  • Organizer: 1st German-Japanese Symposium on Electrosynthesis.
  • Place of Presentation: Bonn, Germany.
  • Year and Date: 2010-10-02
• [Presentation] A Novel Electrosynthetic System Using Parallel Laminar Flow in a Micro-Flow Reactor (2010)
  • Author(s): Mahito ATOBE, Fumihiro AMEMIYA, Daisuke HORII, Toshio FUCHIGAMI,
  • Organizer: The 61st Annual Meet.of Inter.Soc.Electrochem.,
  • Place of Presentation: Nice, France.
  • Year and Date: 2010-09-30
• [Presentation] Environmental-Friendly Emulsion Electrosyntheses Using Acoustic Emulsification (2010)
  • Author(s): Mahito ATOBE, Shintaro IKARI, Fumihiro AMEMIYA, Ryosuke ASAMI, Toshio FUCHIGAMI
  • Organizer: 217th Electrochem.Soc.Meet.
  • Place of Presentation: Vancouver, Canada.
  • Year and Date: 2010-04-26
• [Presentation] Development of Chemoselective Microflow Reactor : Application to Regioselective Cathodic Carbonyl Allylation, (2009)
  • Author(s): Fumihiro AMEMIYA, Toshio FUCHIGAMI, Mahito ATOBE
  • Organizer: 215th Electrochem.Soc.Meet
  • Place of Presentation: Viena, Austria.
  • Year and Date: 2009-10-04
• [Presentation] Development of a Self-Supported Paired Electrosynthetic System using a Micro-flow Reactor (2008)
  • Author(s): Fumihiro AMEMIYA, Daisuke HORII, Toshio FUCHIGAMI, Mahito ATOBE
  • Organizer: 214th Electrochem.Soc.Meet.
  • Place of Presentation: Honolulu, USA.
  • Year and Date: 2008-10-13
• [Book] みみずく書房 (2009)
  • Author(s): 跡部真人、逢坂哲弥、加納健司、桑畑進、立間徹、門間聰之、
  • Total Pages: 1-208
  • Publisher: で理解する電気化学測定法
• [Book] カーク・オスマー化学技術・環境ハンドブック(イオン液体(第10章))(第1巻) (2009)
  • Author(s): 跡部真人
  • Total Pages: 221-272
  • Publisher: 丸善
• [Remarks] 研究室ホームページ
  • URL: http://www.atobe-lab.ynu.ac.jp
• [Remarks] Highlights in Chemical Science 誌に論文 が紹介 (Highlights in Chemical Science, April 2010, Volume 7, Issue 4) Chemoselective Reaction System Using a Two Inlet Micro-flow Reactor : Application to Carbonyl Allylation Amemiya, F. ; Fuse, K .; Fuchigami, T. ; Atobe, M.Chem.Commun.2010, 46, 2730-2732.