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2010 Fiscal Year Final Research Report

Control of Quantum Conductions in Nonowire-Nanoparticle Connecting System

Research Project

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Project/Area Number 20350060
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionHokkaido University

Principal Investigator

AKUTAGAWA Tomoyuki  Hokkaido University, 多元物質科学研究所, 教授 (60271631)

Project Period (FY) 2008 – 2010
Keywordsナノワイヤ / ナノ粒子 / 量子伝導 / 分子超薄膜 / ネットワーク / LB膜 / 電荷移動
Research Abstract

Hybrid nanostructures between the electrical conducting one-dimensional molecular-assembly nanowires and gold nanoparticles with the diameters of 8.5 and 13nm were fabricated at the substrate surface. The electrical conducting behaviors of these hybrid systems were examined from the viewpoint of quantum conduction depending on the size of gold nanoparticles. From the temperature dependent electrical conductivities, the electrical conductions were dominated by the collective tunneling effects between the gold nanoparticles at the temperatures below 100K.

  • Research Products

    (40 results)

All 2011 2010 2009 2008 Other

All Journal Article (18 results) (of which Peer Reviewed: 18 results) Presentation (14 results) Book (7 results) Remarks (1 results)

  • [Journal Article] Exploring the thermochromism of sulfite-embedded polyoxometalate capsules2011

    • Author(s)
      R.Tsunashima, D.Long, T.Endo, S.Noro, T.Akutagawa, T.Nakamura, R.Q.Cabrera, P.F.McMillan, P.Kogerler, L.Cronin
    • Journal Title

      Phys.Chem.Chem.Phys.

      Pages: 7295-7297

    • Peer Reviewed
  • [Journal Article] Ferromagnetic coupling of [Ni(dmit)_2]^- anions in (m-fluoroanilinium)(dicyclohexano[18]crown-6)[Ni(dmit)_2]2010

    • Author(s)
      T.Akutagawa, D.Sato, Q.Ye, S.Noro, T.Nakamura
    • Journal Title

      Dalton Transactions 39

      Pages: 2191-2193

    • Peer Reviewed
  • [Journal Article] Conformational Polymorph of o-Aminoanilinium (dibenzo[18]crown-6) Supramolecules in [Ni(dmit)_2]^- Salts2010

    • Author(s)
      T.Akutagawa, H.Koshinaka, Q.Ye, S.Noro, J.Kawamata, H.Yamaki, T.Nakamura
    • Journal Title

      Chemistry An Asian Journal 5

      Pages: 520-529

    • Peer Reviewed
  • [Journal Article] [18]crown-6 Rotator in Spin-Ladder Compound of m-Aminoanilinium ([18]crown-6)[Ni(dmit)_2]^-2010

    • Author(s)
      T.Akutagawa, D.Sato, Q.Ye, T.Endo, S.Noro, S.Takeda, T.Nakamura
    • Journal Title

      Dalton Transactions 39

      Pages: 8219-8227

    • Peer Reviewed
  • [Journal Article] Asymmetrical [Ni(dmit)_2]^- Arrangements Induced by (1R,2R)-Cyclohexane diammonium - Crown Ether Supramolecules2010

    • Author(s)
      Q.Ye, T.Akutagawa, T.Endo, S.Noro, T.Nakamura, R.Xiong
    • Journal Title

      Inorganic Chemistry 49

      Pages: 8591-8600

    • Peer Reviewed
  • [Journal Article] Highly Polar 7,7-Bis(N,N-dimethyl piperazinium)-8,8-dicyanoquinodimethane in [Ni(dmit)_2]^- Salt ; Crystal Structure and Magnetic Properties2010

    • Author(s)
      S.Jayanty, T.Akutagawa, T.Nakamura
    • Journal Title

      CrystEngComm. 12

      Pages: 4087-4090

    • Peer Reviewed
  • [Journal Article] Polymorphism and Magnetism of cis-Cyclohexane-1, 4-diammonium(Dicyclo hexano [18]crown-6)_2[Ni(dmit)_2]_2 Salts2010

    • Author(s)
      Q.Ye, T.Akutagawa, S.Noro, T.Nakamura, R.Xiong
    • Journal Title

      Cryst.Growth & Des. 10

      Pages: 4856-4860

    • Peer Reviewed
  • [Journal Article] Electron transport in a gold nanoparticle assembly structure stabilized by a physisorbed porphyrin derivative2010

    • Author(s)
      Y.Noda, S.Noro, T.Akutagawa, T.Nakamura
    • Journal Title

      Phys.Rev.B. 83

      Pages: 205420-1,205420-6

    • Peer Reviewed
  • [Journal Article] Ferroelectricity and polarity control in solid state flip-flop supramolecular rotators2009

    • Author(s)
      T.Akutagawa, H.Koshinaka, D.Sato, S.Takeda, S.Noro, H.Takahasi, R.Kumai, Y.Tokura, T.Nakamura
    • Journal Title

      Nature Materials 8

      Pages: 342-347

    • Peer Reviewed
  • [Journal Article] Ferromagnetic and Antiferromagnetic Coupling of [Ni(dmit)_2]^- Anion Layers Induced by Cs^+_2(benzo[18]crown-6)_3 Supramolecule2009

    • Author(s)
      T.Akutagawa, K.Shitagami, M.Aonuma, S.Noro, T.Nakamura
    • Journal Title

      Inorg. Chem. 48

      Pages: 4454-4461

    • Peer Reviewed
  • [Journal Article] Langmuir-Blodgett Films of Charge-Transfer Complexes : Ethylenedithio-Substituted Amphiphilic Bis-TTF Macrocycle and F_4TCNQ or Br_2TCNQ2009

    • Author(s)
      T.Endo, T.Akutagawa, T.Kajiwara, K.Kakiuchi, Y.Tatewaki, S.Noro, T.Nakamura
    • Journal Title

      Bull.Chem.Soc.Jpn. 82

      Pages: 968-974

    • Peer Reviewed
  • [Journal Article] Supramolecular Silver Polyoxometalate Architectures Direct the Growth of Composite Semiconducting Nanostructures2009

    • Author(s)
      C.Streb, R.Tsunashima, D.A.MacLaren, T.McGlone, T.Akutagawa, T.Nakamura, A.Scandurra, B.Pignataro, N.Gadegaard, L.Cronin
    • Journal Title

      Angew.Chem.Int.Ed. 48

      Pages: 6490-6493

    • Peer Reviewed
  • [Journal Article] Molecular-Assemblies of Amphiphilic Gigantic {Mo_<154>}-Ring : (Dimethydioctadecylammonium)_20 [Mo_<154>O_<462>H^+_8 (H_2O)_<90>]2008

    • Author(s)
      T.Akutagawa, R.Jin, R.Tunashima, S.Noro, L.Cronin, T.Nakamura
    • Journal Title

      Langmuir 24

      Pages: 231-238

    • Peer Reviewed
  • [Journal Article] A Solid State Supramolecular Rotator Assembled from a Cs-Crown Ether Polyoxometalate-Hybrid : (Cs^+)_3([18]crown-6)_3(H^+)_2 [PMo_<12>O_<40>].2008

    • Author(s)
      T.Akutagawa, D.Endo, F.Kudo, S.Noro, S.Takeda, L.Cronin, T.Nakamura
    • Journal Title

      Crystal Growth & Design 8

      Pages: 812-816

    • Peer Reviewed
  • [Journal Article] Solid State Molecular Rotators of Anilinium and Adamantylammonium in [Ni(dmit)_)2]^- Salts with Diverse Magnetic Properties2008

    • Author(s)
      T.Akutagawa, D.Sato, H.Koshinaka, M.Aonuma, S.Noro, S.Takeda, T.Nakamura
    • Journal Title

      Inorg.Chem. 47

      Pages: 5951-5962

    • Peer Reviewed
  • [Journal Article] Fullerene Nanowires : Self-Assembly Structures of a Low-Molecular-Weight Organogelator Fabricated by the Langmuir-Blodgett Method2008

    • Author(s)
      R.Tsunashima, S.Noro, T.Akutagawa, T.Nakamura, H.Kawakami, K.Toma
    • Journal Title

      Chem.Eur.J. 14

      Pages: 8169-8176

    • Peer Reviewed
  • [Journal Article] Supramolecular approach for solid state Brownian rotators2008

    • Author(s)
      T.Akutagawa, T.Nakamura
    • Journal Title

      Dalton Transaction

      Pages: 6335-6345

    • Peer Reviewed
  • [Journal Article] Electrical Resistivity of Individual Molecular-assembly Nanowires of Amphiphilic bis-tetrathiafulvalene/2,3,5,6-tetrafluoro-7,7,8,8-tetracyano-p-quinodimethane Charge Transfer Complex by PCI-AFM2008

    • Author(s)
      R.Tsunashima, Y.Noda, Y.Tatewaki, S.Noro, T.Akutagawa, T.Nakamura, T.Matsumoto, T.Kawai
    • Journal Title

      Appl.Phys.Lett. 93

      Pages: 173102

    • Peer Reviewed
  • [Presentation] Molecular Fluctuation and Dielectric Response in Flexible Supramolecular Complexes2010

    • Author(s)
      芥川智行
    • Organizer
      International Symposium on Advanced Soft Materials
    • Place of Presentation
      Kumamoto
    • Year and Date
      20101124-20101126
  • [Presentation] Fabrication of Gold Nanoparticle Assemblies Connected by Double-decker Phthalocyanine Complex via van der Waals Interactions2010

    • Author(s)
      野田祐樹, 野呂真一郎, 芥川智行, 中村貴義
    • Organizer
      International Conference on Nanoscopic Colloid and Surface Science (NCSS2010)
    • Place of Presentation
      Tuskuba
    • Year and Date
      20100919-20100920
  • [Presentation] フタロシアニンダブルデッカー-金ナノ粒子集積体の量子伝導挙動2010

    • Author(s)
      野田祐樹, 野呂真一郎, 芥川智行, 中村貴義
    • Organizer
      分子科学討論会2010
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      20100914-20100917
  • [Presentation] 電子活性な分子集合体の設計から機能性材料の開拓2010

    • Author(s)
      芥川智行
    • Organizer
      山口大学大学院理学研究科講演会
    • Place of Presentation
      山口大学
    • Year and Date
      2010-10-05
  • [Presentation] イミン部位の相互作用を利用したポルフィリン-金ナノ粒子集積体の作製と電気伝導2009

    • Author(s)
      野田祐樹, 芥川智行, 野呂真一郎, 中村貴義
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      名古屋大学
    • Year and Date
      20090921-20090924
  • [Presentation] ポルフィリン誘導体-金ナノ粒子複合構造の作製2009

    • Author(s)
      野田祐樹, 野呂真一郎, 芥川智行, 中村貴義
    • Organizer
      第62回コロイドおよび界面化学討論会
    • Place of Presentation
      岡山理科大学
    • Year and Date
      20090917-20090919
  • [Presentation] TTF誘導体-金ナノ粒子複合LB膜の量子伝導に与える金ナノ粒子サイズの影響2009

    • Author(s)
      福原克朗, 野田祐樹, 野呂真一郎, 芥川智行, 中村貴義
    • Organizer
      第62回コロイドおよび界面化学討論会
    • Place of Presentation
      岡山理科大学
    • Year and Date
      20090917-20090919
  • [Presentation] 金ナノ粒子-ポルフィリン誘導体からなる集積体の電気伝導挙動2009

    • Author(s)
      野田祐樹, 芥川智行, 野呂真一郎, 中村貴義
    • Organizer
      日本物理学会2009年秋季大会
    • Place of Presentation
      熊本大学
    • Year and Date
      20090910-20090913
  • [Presentation] マクロサイクリックTTF-金ナノ粒子複合LB膜の電気伝導性に及ぼす金ナノ粒子のサイズ効果2009

    • Author(s)
      福原克郎・野田祐樹・帯刀陽子・野呂真一郎・芥川智行・中村貴義
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部舟橋キャンパス
    • Year and Date
      20090327-20090330
  • [Presentation] Charge Transport Behavior of Hybrid Structures between Gold Nanoparticles and TTF Derivatives2009

    • Author(s)
      Y.Noda, Y.Tatewaki, T.Akutagawa, T.Nakamura
    • Organizer
      Fifth International Conference on Molecular Electronics and Bioelectronics (M&BE5)
    • Place of Presentation
      Miyazaki International Conference Hall
    • Year and Date
      20090315-20090318
  • [Presentation] Langmuir-Blodgett Films of Charge-Transfer Complexes : Ethylenedithio-Substituted Amphiphilic Bis-TTF Macrocycle and F4TCNQ or Br2TCNQ2008

    • Author(s)
      T.Endo, T.Akutagawa, T.Kajiwara, K.Kakiuchi, Y.Tatewaki, S.Noroa, T.Nakamura
    • Organizer
      8th International Conference on Nano-Molecular Electronics (ICNME 2008)
    • Place of Presentation
      Kobe Portopia Hotel, Japan
    • Year and Date
      20081216-20081218
  • [Presentation] 新規超薄膜のナノ物性評価2008

    • Author(s)
      福原克郎, 野田祐樹, 帯刀陽子, 野呂真一郎, 芥川智行, 中村貴義, Jan BECHER
    • Organizer
      第61回コロイドおよび界面化学討論会
    • Place of Presentation
      九州大学
    • Year and Date
      20080907-20080909
  • [Presentation] Quantum Conducting Behaviour of Gold Nanoparticles - Molecular Nanowires Hybrids2008

    • Author(s)
      T.Akutagawa, Y.Noda, Y.Tatewaki, T.Nakamura
    • Organizer
      International Conference on Science and Technology of Synthetic Metals 2008
    • Place of Presentation
      Porto de Galinhas, Brazil
    • Year and Date
      20080706-20080711
  • [Presentation] Protonic, Ionic, and Molecular Motions in Organic Solid for Conducting and Ferroelectric Materials2008

    • Author(s)
      芥川智行
    • Organizer
      Special Lecture in Nanjing University in China.
    • Place of Presentation
      Nanjing, China
    • Year and Date
      2008-11-06
  • [Book] 現代界面コロイド科学の辞典(日本化学会編)2010

    • Author(s)
      芥川智行, 中村貴義
    • Total Pages
      162-163
    • Publisher
      丸善
  • [Book] 化学と工業(有機強誘電体の新展開)(62(9))2009

    • Author(s)
      芥川智行
    • Total Pages
      986-987
  • [Book] 配位空間の化学-最新技術と応用-:誘電物性(北川進編著)2009

    • Author(s)
      芥川智行, 中村貴義
    • Total Pages
      290-297
    • Publisher
      シエムシー出版
  • [Book] 分子性導体デバイス(超分子サイエンス&テクノロジー)(監修国武豊喜)2009

    • Author(s)
      芥川智行, 中村貴義
    • Total Pages
      618-627
    • Publisher
      NTS出版
  • [Book] 化学と工業(有機強誘電体の新展開)(62(9))2009

    • Author(s)
      芥川智行
    • Total Pages
      986-987
  • [Book] 遷移金属錯体の固体物性化学(山下正廣、小島憲道編著)(錯体化学会選書3)2008

    • Author(s)
      芥川智行, 中村貴義
    • Total Pages
      375-390
    • Publisher
      三共出版
  • [Book] ケイ・ディー・ネオブック(分子エレクトロニクスの話)(斉藤軍治編著5章)2008

    • Author(s)
      芥川智行
    • Total Pages
      90-102
    • Publisher
      化学同人
  • [Remarks] ホームページ等

    • URL

      http://www.tagen.tohoku.ac.jp/labo/akutagawa/Homepage2010/index-j.html

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Published: 2012-01-26   Modified: 2016-04-21  

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