Development of Single-component Molecular Metals with New Electronic Functions.

2010 Fiscal Year Self-evaluation Report

• Project/Area Number: 20350069
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Functional materials chemistry
• Research Institution: Nihon University
• Principal Investigator: KOBAYASHI Akiko Nihon University, 文理学部, 教授 (50011705)
• Project Period (FY): 2008 – 2011
• Keywords: 分子性固体 / 分子性金属

Research Abstract

本研究は分子の電子状態制御により新たな機能性分子物質の開発を目指すとともに、その物理化学的特性を解明し、新たな分子物質の開発に寄与することが目的である。主として中心金属選択や配位子修飾による分子軌道設計に基づき、単一分子性伝導体における多軌道起源の新電子相を探索する。

Research Products

• [Journal Article] Anomalous Dielectric Behavior and Thermal Motion of Water Molecules Confined in Channels of Porous Coordination Polymer Crystals (2011)
  • Author(s): B.Zhou, A.Kobayashi, H.Cui, L.Long, H.Fujimori, H.Kobayashi
  • Journal Title: J.Amer.Chem.Soc. 133 Pages: 5736-5739
  • Peer Reviewed
• [Journal Article] Single-Component Molecular Conductor [Cu(tmdt)_2] Containing an Antiferromagnetic Heisenberg Chain (2010)
  • Author(s): B.Zhou, H.Yajima, A.Kobayashi, Y.Okano, H.Tanaka, T.Kumashiro, E.Nishibori, H.Sawa, H.Kobayashi
  • Journal Title: Inorg. Chem. 49 Pages: 6740-6747
  • Peer Reviewed
• [Journal Article] High-Pressure (up to 10.7 GPa) Crystal Structure of Single-Component Molecular Metal [Au(tmdt)_2] (2009)
  • Author(s): Y.Okano, B.Zhou, H.Tanaka, T.Adachi, Y.Oishi, M.Takata, S.Aoyagi, E.Nishibori, M.Sakata, A.Kobayashi, H.Kobayashi
  • Journal Title: J.Am.Chem.Soc. 131 Pages: 7169-7174
  • Peer Reviewed
• [Journal Article] Single-component Molecular Conductor [Pt(tmdt)_2](tmdt=trimethylenetetrathiafulvalenedithiolate)-An Advanced Molecular Metal Exhibiting High Metallicity (2009)
  • Author(s): B.Zhou, A.Kobayashi, Y.Okano, T.Nakashima, S.Aoyagi, E.Nishibori, M.Sakata, M.Tokumoto, H.Kobayashi
  • Journal Title: Adv.Mater. 21 Pages: 3596-3600
  • Peer Reviewed
• [Journal Article] Metallization of the single component molecular semiconductor [Ni(ptdt)_2] under very high pressure (2009)
  • Author(s): H.Cui, J.S.Brooks, A.Kobayashi, H.Kobayashi
  • Journal Title: J.Am.Chem.Soc. 131 Pages: 6358-6359
  • Peer Reviewed
• [Journal Article] Structural Anomalies Associated with Antiferromagnetic Transition of Single-Component Molecular Metal [Au(tmdt)_2] (2009)
  • Author(s): B.Zhou, A.Kobayashi, Y.Okano, H.Cui, D.Graf, J.S.Brooks, T.Nakashima, S.Aoyagi, M.Sakata, H.Kobayashi
  • Journal Title: Inorg. Chem. 48 Pages: 10151-10157
  • Peer Reviewed
• [Journal Article] Studies on Molecular Conductors-From Organic Semiconductors to Molecular Metals and Superconductors
  • Author(s): H.Kobayashi, A.Kobayashi, H.Tajima
  • Journal Title: Chemistry-An Asian Journal in press
  • Peer Reviewed
• [Presentation] Magnetic Single-Component Molecular Conductors Exhibiting Strong π-d Interactions (2010)
  • Author(s): A.Kobayashi, B.Zhou, H.Kobayashi
  • Organizer: The 12^<th> International Conference on Molecule-Based Magnets
  • Place of Presentation: Beijing, China
  • Year and Date: 20101008-20101012
• [Presentation] Single-component Molecular Conductors-New Multi-frontier π-d System (2010)
  • Author(s): A.Kobayashi, B.Zhou, H.Kobayashi
  • Organizer: Kyoto International Conference Center
  • Place of Presentation: Kyoto, Japan
  • Year and Date: 20100904-20100909
• [Presentation] A New Single-component Magnetic Molecular Conductor [Cu(tmdt)_2] (tmdt=trimethylenetetrathiafulvalenedithiolate) (2009)
  • Author(s): A.Kobayashi, B.Zhou, H.Kobayashi, H.Tanaka, E.Nishibori, H.Sawa
  • Organizer: ISCOM2009
  • Place of Presentation: Hokkaido Niseko
  • Year and Date: 20090912-20090917
• [Presentation] Development of Single-Component Molecular Metals-Metallic Crystals Consisting of Single Kind of Molecules (2009)
  • Author(s): A.Kobayashi
  • Organizer: L'OREAL-UNESCO Awards "For Women in Science"
  • Place of Presentation: French Academy of Science, Paris
  • Year and Date: 2009-03-04
• [Presentation] A Single-Component Molecular Metals (2008)
  • Author(s): A.Kobayashi
  • Organizer: IUCr2008
  • Place of Presentation: Osaka
  • Year and Date: 20080823-20080830