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2011 Fiscal Year Final Research Report

Development of Single-component Molecular Metals with New Electronic Functions

Research Project

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Project/Area Number 20350069
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionNihon University

Principal Investigator

KOBAYASHI Akiko  日本大学, 文理学部, 教授 (50011705)

Co-Investigator(Kenkyū-buntansha) ZHOU Biao  日本大学, 文理学部, 助教 (80434067)
Project Period (FY) 2008 – 2011
Keywords単一分子性金属 / π-d相互作用 / 反強磁性相転移 / 分子性伝導体
Research Abstract

The aims of this research are developing new functional materials and clarifying their physical properties. Based on molecular design by selecting the central metal atoms and modifying ligands new electronic materials of single-component molecular conductors are developed.

  • Research Products

    (31 results)

All 2012 2011 2010 2009

All Journal Article (11 results) (of which Peer Reviewed: 10 results) Presentation (20 results)

  • [Journal Article] Charge Ordering and Carrier Generation by Air Oxidation of a Nickel Complex with Selenium-Containing Extended-Tetrathia fulvalenedithiolate Ligands2012

    • Author(s)
      H. Yajima, B. Zhou, E. Fujiwara, A. Kobayashi, H. Kobayashi
    • Journal Title

      Inorg. Chem.

      Volume: 51 Pages: 2731-2733

    • DOI

      DOI:10.1021/ic2026768

    • Peer Reviewed
  • [Journal Article] Molecular Alloy with Dilited Magnetic Moments. Molecular Kondo System2012

    • Author(s)
      Y. Idobata, B. Zhou, A. Kobayashi, H. Kobayashi
    • Journal Title

      J. Amer. Chem. Soc.

      Volume: 134 Pages: 871-874

    • DOI

      DOI:10.1021/ja210019y

    • Peer Reviewed
  • [Journal Article] Single-component Layered Molecular Conductor, [Au(ptdt)_2]2011

    • Author(s)
      B. Zhou, H. Yajima, Y. Idobata, A. Kobayashi, T. Kobayashi, E. Nishibori, H. Sawa, H. Kobayashi
    • Journal Title

      Chem. Lett.

      Volume: 41 Pages: 154-156

    • DOI

      DOI:10.1246/cl.2012.154

    • Peer Reviewed
  • [Journal Article] Magnetic Single-Component Molecular Conductors Exhibiting Strongπ-d Interactions2011

    • Author(s)
      A. Kobayashi, B. Zhou, H. Kobayashi
    • Journal Title

      Polyhedron

      Volume: 30 Pages: 3298

    • DOI

      DOI:10.1016/j.poly.2011.07.027

  • [Journal Article] Studies on Molecular Conductors-From Organic Semiconductors to Molecular Metals and Superconductors2011

    • Author(s)
      H. Kobayashi, A. Kobayashi and H. Tajima
    • Journal Title

      Chemistry-An Asian Journal

      Volume: 6 Pages: 1688-1704

    • DOI

      DOI:10.1002/asia.201100061

    • Peer Reviewed
  • [Journal Article] The First BETS Radical Cation Salts with Dicyanamide Anion : Crystal Growth, Structure and Conductivity Study2011

    • Author(s)
      N. D. Kushch, ; L. I. Buravov, A. N. Chekhlov, N. G. Spitsina, P. P Kushch, E. B. Yagubskii, E. Herdtweck, A. Kobayashi
    • Journal Title

      J. Solid. State. Chem.

      Volume: 184 Pages: 3074

    • DOI

      10.1016/j.jssc.2011.09.001

    • Peer Reviewed
  • [Journal Article] Single-Component Molecular Conductor [Cu(tmdt)_2] Containing an Antiferromagnetic Heisenberg Chain2010

    • Author(s)
      B. Zhou, H. Yajima, A. Kobayashi, Y. Okano, H. Tanaka, T. Kumashiro, E. Nishibori, H. Sawa and H. Kobayashi
    • Journal Title

      Inorg. Chem.

      Volume: 49 Pages: 6740-6747

    • DOI

      DOI:10.1021/ic100845f

    • Peer Reviewed
  • [Journal Article] High-Pressure(up to 10.7 GPa) Crystal Structure of Single-Component Molecular Metal [Au(tmdt)_2]2009

    • Author(s)
      Y. Okano, B. Zhou, H. Tanaka, T. Adachi, Y. Oishi, M. Takata, S. Aoyagi, E. Nishibori, M. Sakata, A. Kobayashi, and H. Kobayashi
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 131 Pages: 7169-7174

    • DOI

      DOI:10.1021/ja9010018

    • Peer Reviewed
  • [Journal Article] Single-component Molecular Conductor [Pt(tmdt)_2](tmdt=trimethylenetetrathia fulvalenedithiolate)-An Advanced Molecular Metal Exhibiting High Metallicity2009

    • Author(s)
      B. Zhou, A. Kobayashi, Y. Okano, T. Nakashima, S. Aoyagi, E. Nishibori, M. Sakata, M. Tokumoto, and H. Kobayashi
    • Journal Title

      Adv. Mater

      Volume: 21 Pages: 3596-3600

    • DOI

      DOI:10.1002/adma.200803116

    • Peer Reviewed
  • [Journal Article] Metallization of the single component molecular semiconductor [Ni(ptdt)_2] under very high pressure2009

    • Author(s)
      H. Cui, J. S. Brooks, A. Kobayashi, H. Kobayashi
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 131 Pages: 6358-6359

    • DOI

      DOI:10.1021/ja901553z

    • Peer Reviewed
  • [Journal Article] Structural Anomalies Associated with Antiferromagnetic Transition of Single-Component Molecular Metal [Au(tmdt)_2]2009

    • Author(s)
      B. Zhou, A. Kobayashi, Y. Okano, H. Cui, D. Graf, J. S. Brooks, T. Nakashima, S. Aoyagi, M. Sakata and H. Kobayashi
    • Journal Title

      Inorg. Chem

      Volume: 48 Pages: 10151-10157

    • DOI

      DOI:10.1102/ic9001172u

    • Peer Reviewed
  • [Presentation] 層状構造を持つ単一成分分子性伝導体-[Au(ptdt)_2]の合成と物性2012

    • Author(s)
      周彪, 矢島寛之, 井戸端裕樹, 小林昭子, 小林速男
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学
    • Year and Date
      20120325-28
  • [Presentation] セレン原子を導入した拡張TTF型ジチオラトニッケル錯体の合成および物性2012

    • Author(s)
      矢島寛之, 周彪, 小林昭子, 小林速男
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学,日吉
    • Year and Date
      20120325-28
  • [Presentation] 稀薄な磁気モーメントを持つ分子性合金.分子性近藤系2012

    • Author(s)
      井戸端裕樹, 周彪, 小林昭子, 小林速男
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学,日吉
    • Year and Date
      20120325-28
  • [Presentation] 新規な電子機能性を示す分子物質の開発.分子性稀薄磁性合金と巨大な誘電異常を示す有機ペロブスカイト2012

    • Author(s)
      小林昭子, 周彪, 小林速男
    • Organizer
      新学術領域研究"分子自由度が拓く新物質科学"第6回領域会議
    • Place of Presentation
      仙台
    • Year and Date
      20120105-07
  • [Presentation] 銅原子を含む単一分子性伝導体の構造と物性2011

    • Author(s)
      小林昭子, 周彪, 小林速男
    • Organizer
      分子アンサンブル2011
    • Place of Presentation
      理研
    • Year and Date
      20111110-12
  • [Presentation] 金属錯体ポリマー結晶を用いた新しい誘電体の開発2011

    • Author(s)
      周彪, 小林昭子, 小林速男
    • Organizer
      分子アンサンブル2011
    • Place of Presentation
      理研
    • Year and Date
      20111110-12
  • [Presentation] Single-component Multifrontierπ-d System, [Cu(dmdt)_2] with Twisted Molecular Structure and Magnetic Phase Transition around 100 K2011

    • Author(s)
      A. Kobayashi, Y. Idobata, B. Zhou, and H. Kobayashi
    • Organizer
      The 9th International Symposium on Crystalline Organic Metals, Superconductors and Ferromagnets(ISCOM2011)
    • Place of Presentation
      Pozna., Poland
    • Year and Date
      20110925-30
  • [Presentation] Vortex Dynamics in Superconducting State forλ-(BETS)_2GaCl_42011

    • Author(s)
      S. Uji, T. Terashima, A. Harada, S. Tsuchiya, N. Kurita, K. Kodama, K. Sugii, B. Zhou, H. Kobayashi and A. Kobayashi
    • Organizer
      The 9th International Symposium on Crystalline Organic Metals, Superconductors and Ferromagnets(ISCOM2011)
    • Place of Presentation
      Pozna., Poland
    • Year and Date
      20110925-30
  • [Presentation] Magnetic Field Effect on Antifferomagnetic Insulating State ofλ-(BETS)_2FeCl_42011

    • Author(s)
      H. Akiba, K. Nobori, K. Shimada, Y. Nishio, K. Kajita, R. Kato, B. Zhou, A. Kobayashi and H. Kobayashi
    • Organizer
      The 9th International Symposium on Crystalline Organic Metals, Superconductors and Ferromagnets(ISCOM2011)
    • Place of Presentation
      Pozna., Poland
    • Year and Date
      20110925-30
  • [Presentation] Heat Capacity Measurements of magnetic conductorκ-(BETS)_2FeX_42011

    • Author(s)
      S. Fukuoka, T. Yamamoto, Y. Nakazawa, A. Kobayashi, and H. Kobayashi
    • Organizer
      The 9th International Symposium on Crystalline Organic Metals, Superconductors and Ferromagnets(ISCOM2011)
    • Place of Presentation
      Pozna., Poland
    • Year and Date
      20110925-30
  • [Presentation] Exchange interaction between conduction π and localized d spins in the field induced superconductor,λ-(BETS)_2Fe_<1-x> Ga_xCl_42011

    • Author(s)
      K. Hiraki, T. Takahashi, H. Akiba, Y. Nishio, B. Zhou, A. Kobayashi and H. Kobayashi
    • Organizer
      The 9th International Symposium on Crystalline Organic Metals, Superconductors and Ferromagnets(ISCOM2011)
    • Place of Presentation
      Pozna., Poland
    • Year and Date
      20110925-30
  • [Presentation] Peculiarities of BETS electrocrystallization in the presence of transition metal dicyanamides. The first BETS radical cation salts with dicyanamide anion : crystal growing, structure and conductivity study2011

    • Author(s)
      D. Kushch, L. I. Buravov, A. N. Chekhlov, N. G. Spitsina, P.P. Kushch, E. B. Yagubskii, E. Herdtweck, A. Kobayashi, and H. Kobayashi
    • Organizer
      The 9th International Symposium on Crystalline Organic Metals, Superconductors and Ferromagnets(ISCOM2011)
    • Place of Presentation
      Pozna., Poland
    • Year and Date
      20110925-30
  • [Presentation] Diverse Magnetic Properties of [M(tmdt)_2](M=Au, Cu) Studied by^IH-NMR2011

    • Author(s)
      R. Takagi, K. Miyagawa, K. Kanoda, B. Zhou, A. Kobayashi, and H. Kobayashi
    • Organizer
      The 9th International Symposium on Crystalline Organic Metals, Superconductors and Ferromagnets(ISCOM2011)
    • Place of Presentation
      Pozna., Poland
    • Year and Date
      20110925-30
  • [Presentation] Development of Molecular Materials with Electronic and/or Magnetic Functions2011

    • Author(s)
      H. Kobayashi, B. Zhou, A. Kobayashi
    • Organizer
      The XXII Congress and General Assembly of the International Union of Crystallography
    • Place of Presentation
      Madrid, Spain
    • Year and Date
      20110822-30
  • [Presentation] Magnetic Single-Component Molecular Conductors Exhibiting Strongπ-d Interactions2010

    • Author(s)
      A. Kobayashi, B. Zhou and H. Kobayashi
    • Organizer
      The 12^<th> International Conference on Molecule-Based Magnets
    • Place of Presentation
      Beijing, China
    • Year and Date
      20101008-12
  • [Presentation] Single-component Molecular Conductors-New Multi-frontierπ-d System2010

    • Author(s)
      A. Kobayashi, B. Zhou and H. Kobayashi
    • Organizer
      Kyoto International Conference Center
    • Place of Presentation
      Japan, September
    • Year and Date
      20100904-09
  • [Presentation] Single-component Molecular Conductors [M(tmdt)_2]: Newπ-d System with Strong Three-dimensionality2009

    • Author(s)
      A. Kobayashi, B. Zhou, H. Kobayashi
    • Organizer
      Schegolev Memorial Conference Low-Dimensional Metallic and Superconducting Systems, Russian Academy of Science, Institute of Solid State Physics
    • Place of Presentation
      Chernogolovka, Moscow
    • Year and Date
      20091011-16
  • [Presentation] Possibilities of Pressure-induced Metallization of Molecular Crystals, TMTTeN and [Ni(ptdt)_2] and Anomalous Phase Transitions of Molecular Conductors Based on Transition Metal Complex Molecules with Extended-TTF Ligands2009

    • Author(s)
      H. Kobayashi, B. Zhou, A. Kobayashi, H. B. Cui, J. S. Brooks I. F
    • Organizer
      Schegolev Memorial Conference Low-Dimensional Metallic and Superconducting Systems, Russian Academy of Science, Institute of Solid State Physics
    • Place of Presentation
      Chernogolovka, Moscow
    • Year and Date
      20091011-16
  • [Presentation] A New Single-component Magnetic Molecular Conductor [Cu(tmdt)_2]2009

    • Author(s)
      A. Kobayashi, B. Zhou, H. Kobayashi, H. Tanaka, E. Nishibori, H. Sawa
    • Organizer
      ISCOM2009
    • Place of Presentation
      Hokkaido Niseko
    • Year and Date
      20090912-17
  • [Presentation] Structural Studies on [Au(tmdt)_2] and Metallization of [Ni(ptdt) 2] at High Pressure2009

    • Author(s)
      H. Kobayashi, B. Zhou, A. Kobayashi, H. Tanaka, Y. Okano, E. Nishibori, M. Sakata, H. Cui, J. Brooks
    • Organizer
      ISCOM2009
    • Place of Presentation
      Hokkaido Niseko
    • Year and Date
      20090912-17

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Published: 2013-07-31  

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