2011 Fiscal Year Final Research Report
Environmentally Friendly Selective Electrochemical Fluorination Using Fluoride Salt Ionic Liquids and Their Polymer Derivatives
| Project/Area Number |
20350071
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Environmental chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
FUCHIGAMI Toshio 東京工業大学, 大学院・総合理工学研究科, 教授 (10016701)
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| Project Period (FY) |
2008 – 2011
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| Keywords | イオン液体 / 選択的電解フッ素化 / 脱硫フッ素化 / キサントゲン酸エステル / 間接電解 / リサイクル / ジフッ素化 / メデイエーター |
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| Research Abstract |
Ionic liquids are ideal non-aqueous electrolytic solution since they are nonvolatile, inflammable, highly conductive, and recyclable. Therefore, if ionic liquids are used as both solvent and supporting electrolyte, environmentally friendly organic electrosynthsis would be possible. In this work, a supporting electrolyte recyclable anodic fluorination system was attempted, and a solvent free anodic fluorination process was successfully developed using HF salt ionic liquids as a fluorine source and solvent.
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