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2010 Fiscal Year Final Research Report

Development of light-transmitting heat-insulation materials using novel hybrid gels

Research Project

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Project/Area Number 20350094
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionKyoto University

Principal Investigator

NAKANISHI Kazuki  Kyoto University, 大学院・理学研究科, 准教授 (00188989)

Co-Investigator(Kenkyū-buntansha) KANAMORI Kazuyoshi  京都大学, 大学院・理学研究科, 助教 (60452265)
Project Period (FY) 2008 – 2010
Keywords多孔体 / 低密度固体 / 有機無機ハイブリッド / 熱伝導率
Research Abstract

Light-transmitting, low-density organic-inorganic hybrid solid materials suitable for heat-insulation were obtained in the methylsilsesquioxane system via one-step synthesis using surfactants and urea as additives followed by either super-critical or ambient evaporation drying of the solvent. Gels with hierarchiall macro-and mesopores have also been synthesized by careful tuning ofthe compositions and reaction conditions. The relation between gas pressure and thermal conductivity of the above materials have been investigated in relation to their pore structures.

  • Research Products

    (21 results)

All 2011 2010 2009 2008

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (12 results) Book (1 results)

  • [Journal Article] Organic-inorganic hybrid aerogels with high mechanical properties via organotrialkoxysilane-derived sol-gel process2011

    • Author(s)
      K.Kanamori
    • Journal Title

      Journal of the Ceramic Society of Japan vol.119

      Pages: 16-22

    • Peer Reviewed
  • [Journal Article] Controlled pore formation in organotrialkoxy- silane-derived hybrids : From aerogels to hierarchically porous monoliths2011

    • Author(s)
      K.Kanamori, K.Nakanishi
    • Journal Title

      Chemical Society Reviews vol.40

      Pages: 754-770

    • Peer Reviewed
  • [Journal Article] Organosiloxane transparent aerogels and hierarchically porous monoliths2010

    • Author(s)
      Y.Kodera, G.Hayase, K.Kanamori, K.Nakanishi, T.Hanada
    • Journal Title

      Materials Research Society Symposium Proceedings vol.1306

      Pages: BB10-05

    • Peer Reviewed
  • [Journal Article] A new route to monolithic macroporous SiC/C composites from biphenylene-bridged polysilsesquioxane gels2010

    • Author(s)
      G.Hasegawa, K.Kanamori, K.Nakanishi, T.Hanada
    • Journal Title

      Chemistry of Materials vol.22

      Pages: 2541-2547

    • Peer Reviewed
  • [Journal Article] Sol-gel synthesis, porous structure, and mechanical property of polymethyl-silsesquioxane aerogels2009

    • Author(s)
      K.Kanamori, K.Nakanishi, T.Hanada
    • Journal Title

      Journal of the Ceramics Society of Japan vol.117

      Pages: 1333-1338

    • Peer Reviewed
  • [Journal Article] Spinodal decomposition in siloxane sol-gel systems in macroporous media2009

    • Author(s)
      K.Kanamori, K.Nakanishi, T.Hanada
    • Journal Title

      Soft Matter vol.5

      Pages: 3106-3113

    • Peer Reviewed
  • [Journal Article] Elastic aerogels and xerogels synthesized from methyltrimethoxysilane (MTMS)2009

    • Author(s)
      K.Kanamori, K.Nakanishi, T.Hanada
    • Journal Title

      Materials Research Society Symposium Proceedings vol.1134

      Pages: BB07-06

    • Peer Reviewed
  • [Journal Article] Elastic organic-inorganic hybrid aerogels and xerogels2008

    • Author(s)
      K.Kanamori, M.Aizawa, K.Nakanishi, T.Hanada
    • Journal Title

      Journal of Sol-Gel Science and Technology vol.48

      Pages: 172-181

    • Peer Reviewed
  • [Presentation] Porous Materials Prepared in Methylsilsesquioxane Sol-Gel Systems2010

    • Author(s)
      K.Kanamori, Y.Kodera, K.Nakanishi, T.Hanada
    • Organizer
      3rd International Congress on Ceramics
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      20101114-20101118
  • [Presentation] Synthesis and characterization of organic-inorganic hybrid aerogel2010

    • Author(s)
      早瀬元, 金森主祥, 中西和樹, 花田禎一
    • Organizer
      MRS 2010 Spring Meeting
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      20100405-20100409
  • [Presentation] Hierarchically Porous Monoliths : from Oxides to Hybrids, Polymers and Carbon Materials2010

    • Author(s)
      中西和樹
    • Organizer
      2nd Japan-Korea Joint Forum on Sol-Gel Science and Technology
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      20100126-20100129
  • [Presentation] 新規有機-無機ハイブリッドエアロゲルの細孔構造と力学特性2009

    • Author(s)
      金森主祥, 中西和樹, 花田禎一
    • Organizer
      第50回ガラスおよびフォトニクス材料討論会
    • Place of Presentation
      京都大学(桂キャンパス)
    • Year and Date
      20091029-20091030
  • [Presentation] Facile synthesis of elastic aerogels and xerogels from methyltrimethoxysilane (MTMS)2009

    • Author(s)
      金森主祥, 中西和樹, 花田禎一
    • Organizer
      The XVth International Sol-Gel Conference
    • Place of Presentation
      Porto de Galinhas, Brazil
    • Year and Date
      20090823-20090827
  • [Presentation] 有機-無機ハイブリッドエアロゲルの合成と物性評価2009

    • Author(s)
      早瀬元, 金森主祥, 中西和樹, 花田禎一
    • Organizer
      第7回日本ゾル-ゲル学会討論会
    • Place of Presentation
      メルパルク京都
    • Year and Date
      20090728-20090729
  • [Presentation] 有機-無機ハイブリッドエアロゲルの細孔構造と力学特性2009

    • Author(s)
      金森主祥, 中西和樹, 花田禎一
    • Organizer
      日本セラミックス協会 第22回秋季シンポジウム
    • Place of Presentation
      愛媛大学
    • Year and Date
      20090616-20090918
  • [Presentation] Hierarchically porous monoliths applied to separation science, First International Conference on Multifunctional2009

    • Author(s)
      金森主祥
    • Organizer
      Hybrid and Nanomaterials (Hybrid Materials 2009)
    • Place of Presentation
      Tours, France(invited)
    • Year and Date
      20090315-20090319
  • [Presentation] Phase separation in silica sol-gel system containing polyoxyethylene alkyl ether2009

    • Author(s)
      Y.Kodera, K.Kanamori, K.Nakanishi, T.Hanada
    • Organizer
      First International Conference on Multifunctional, Hybrid and Nanomaterials (Hybrid Materials 2009)
    • Place of Presentation
      Tours, France
    • Year and Date
      20090315-20090319
  • [Presentation] 有機-無機ハイブリッド透明多孔性物質の液相合成2009

    • Author(s)
      金森主祥, 中西和樹, 花田禎一
    • Organizer
      第4回日本セラミックス協会関西支部学術講演会
    • Place of Presentation
      関西大学
    • Year and Date
      2009-07-16
  • [Presentation] Facile synthesis of elastic aerogels and xerogels from methyltrimethoxysilane (MTMS)2008

    • Author(s)
      金森主祥, 中西和樹, 花田禎一
    • Organizer
      The IUMRS International Conference in Asia 2008
    • Place of Presentation
      Nagoya, Japan
    • Year and Date
      20081209-20081213
  • [Presentation] Facile synthesis of elastic aerogels and xerogels from methyltrimethoxysilane (MTMS)2008

    • Author(s)
      金森主祥, 中西和樹, 花田禎一
    • Organizer
      MRS 2008 Fall Meeting
    • Place of Presentation
      Boston, USA
    • Year and Date
      20081201-20081205
  • [Book] Monolithic Silicas in Separation Science(Chapters 2 & 5)2011

    • Author(s)
      K.Nakanishi, K.Kanamori
    • Publisher
      Wiley-VCH

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Published: 2012-01-26   Modified: 2016-04-21  

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