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2011 Fiscal Year Final Research Report

Development of function-hierarchical materials under unique reaction fields and application of their electronic and molecular functions

Research Project

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Project/Area Number 20350095
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionHiroshima University

Principal Investigator

INUMARU Kei  広島大学, 大学院・工学研究院, 教授 (80270891)

Co-Investigator(Kenkyū-buntansha) FUKUOKA Hiroshi  広島大学, 大学院・工学研究院, 助教 (00284175)
Co-Investigator(Renkei-kenkyūsha) YAMANAKA Shoji  広島大学, 大学院・工学研究院, 特任教授 (90081314)
Project Period (FY) 2008 – 2011
Keywords結晶 / 多孔体 / 触媒 / 光触媒 / 超伝導
Research Abstract

We defined" function-hierarchical material" as a system in which each level of the hierarchical structured material interplays with each other to express a novel function. We explored the function-hierarchical system by using unique reaction fields such as ultra high vacuum or high pressure conditions. We could design some function-hierarchal systems : the nanocomposite of TiO_2 or Pd particles surrounded by mesoporous silica, high pressure or thin film synthesis of superconducting or antiferromagnetic nitrides, in which surface or interfaces play an important role to realize their functions.

  • Research Products

    (24 results)

All 2011 2010 2009 2008

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (9 results) Book (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Thin film growth of boron nitride on alpha-A_2O_3(001) substrates by reactive sputtering2011

    • Author(s)
      A. Anzai, F. Nishiyama, S. Yamanaka, K. Inumaru
    • Journal Title

      Mater. Res. Bull

      Volume: 18 Pages: 455-463

    • DOI

      DOI:10.1016/j.materresbull.2011.09.006

    • Peer Reviewed
  • [Journal Article] Preparation of Pd particles coated with mesoporous silica layers2011

    • Author(s)
      K. Inumaru, K. Nakamura, K. Ooyachi, K. Mizutani, S. Akihara, S. Yamanaka
    • Journal Title

      J. Porous Mater

      Volume: 18 Pages: 455-463

    • DOI

      DOI:10.1246/bcsj.20100261

    • Peer Reviewed
  • [Journal Article] Molybdenum cluster halide compound Mo_6Cl_<12>(OH_2)_2 with six-handed linkage hydrogen bonding2011

    • Author(s)
      K. Inumaru, A. Anzai, T. Kikudome, M. Harada, H. Sakai, Y. Ide, T. Sano, S. Yamanaka
    • Journal Title

      Bull. Chem. Soc. Jpn

      Volume: 84 Pages: 379-385

    • DOI

      DOI:10.1246/bcsj.20100261

    • Peer Reviewed
  • [Journal Article] Nanocomposites of crystalline TiO_2 particles and mesoporous silica : molecular selective photocatalysis tuned by controlling pore size and structure2011

    • Author(s)
      K. Inumaru, M. Yasui, T. Kasahara, Y. Kubota, K. Yamaguchi, A. Yasuda, S. Yamanaka
    • Journal Title

      J. Mater. Chem

      Volume: 21 Pages: 12117-12125

    • DOI

      DOI:10.1039/C1JM11839K

    • Peer Reviewed
  • [Journal Article] Does Water Liquid Phase Intrude into Hydrophobic Nanospaces of Alkyl-grafted Mesoporous Silica Immersed in Water? Detection by^<13> C CP-MAS NMR2010

    • Author(s)
      K. Inumaru, S. Kakii, H. Yoshida, S. Yamanaka
    • Journal Title

      Chem. Lett.

      Volume: 39 Pages: 1215-1216

    • DOI

      DOI:10.1246/cl.2010.1215

    • Peer Reviewed
  • [Journal Article] Interstitial binary nitride ReNx phases prepared by pulsed laser deposition : Structure and superconductivity dependence on nitrogen stoichiometry2009

    • Author(s)
      M. Fuchigami, K. Inumaru, S. Yamanaka
    • Journal Title

      J. Alloys Compd

      Volume: 486 Pages: 621-627

    • DOI

      DOI:10.1016/j.jallcom.2009.07.018

    • Peer Reviewed
  • [Journal Article] High pressure synthesis of ammonium tungsten bronze superconducting phases from a molecular solid acid H_3PW_<12> O_<40>・n H_2O(n~28) in BN crucibles2009

    • Author(s)
      A. Anzai, K. Inumaru, S. Yamanaka
    • Journal Title

      J. Alloys Compd

      Volume: 470 Pages: 557-560

    • DOI

      DOI:10.1016/j.jallcom.2008.03.116

    • Peer Reviewed
  • [Journal Article] Photocatalytic decomposition of 2-propanol in air by mechanical mixtures of TiO_2 crystalline particles and silicalite adsorbent : The complete conversion of organic molecules irreversibly adsorbed within zeolitic channels2009

    • Author(s)
      K. Yamaguchi, K. Inumaru, Y. Oumi, T. Sano, S. Yamanaka
    • Journal Title

      Micropor. Mesopor. Mater

      Volume: 117 Pages: 350-355

    • DOI

      DOI:10.1016/j.micromeso.2008.07.009

    • Peer Reviewed
  • [Journal Article] Reversible emergence of a self-assembled layered structure from three-dimensional isotropic ionic crystal of a cluster compound(4-HNC_5H_4OH)_2Mo_6Cl_<14> driven by absorption of water and alcohols2008

    • Author(s)
      Inumaru, T. Kikudome, H. Fukuoka, S. Yamanaka
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 130 Pages: 10038-10039

    • DOI

      DOI:10.1021/ja802752y

    • Peer Reviewed
  • [Journal Article] Magnetoresistance of ferromagnetic Cr_xTi_1-_xN solid solution nitride2008

    • Author(s)
      K. Inumaru, Y. Miyaki, K. Tanaka, K. Koyama, and S. Yamanaka
    • Journal Title

      Phys. Rev. B.

      Volume: 78 Pages: 052406/ 1-4

    • DOI

      DOI:10.1103/PhysRevB.78.052406

    • Peer Reviewed
  • [Journal Article] Partial suppression of structural distortion in epitaxially grown BaBiO_3 thin films2008

    • Author(s)
      K. Inumaru, H. Miyata, S. Yamanaka
    • Journal Title

      Phys. Rev. B.

      Volume: 78 Pages: 132507/ 1-4

    • DOI

      DOI:10.1103/PhysRevB.78.132507

    • Peer Reviewed
  • [Journal Article] High-pressure synthesis of superconducting molybdenum nitride delta-MoN by in situ nitridation2008

    • Author(s)
      K. Inumaru, T. Nishikawa, K. Nakamura, S. Yamanaka
    • Journal Title

      Chem. Mater

      Volume: 20 Pages: 4756-4761

    • DOI

      DOI:10.1021/cm800820d

    • Peer Reviewed
  • [Presentation] 遷移金属窒化物エピタキシャル薄膜の合成と機能2011

    • Author(s)
      犬丸啓
    • Organizer
      日本セラミックス協会第24回秋季シンポジウム(招待講演)
    • Place of Presentation
      札幌市
    • Year and Date
      2011-09-07
  • [Presentation] Synthesis of composite materials between preformed TiO_2 particles and zeolites for photocatalytic applications2010

    • Author(s)
      Y. Kubota, K. Yamaguchi, H. Sakai, H. Fukuoka, K. Inumaru
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ホノルル(米国)
    • Year and Date
      2010-12-19
  • [Presentation] High-pressureand high-temperature synthesis, structures, and physical properties of binary germanides of electropositive elements2010

    • Author(s)
      H. Fukuoka, D. Saito, F. Ohtsu, M. Harada, M. Yoshikawa, K. Baba, K. Inumaru
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ホノルル(米国)
    • Year and Date
      2010-12-18
  • [Presentation] Synthesis and properties of binary ytterbium germanides prepared by high-pressure and high-temperature reactions2010

    • Author(s)
      M. Harada, H. Fukuoka, K. Inumaru
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ホノルル(米国)
    • Year and Date
      2010-12-18
  • [Presentation] Control of Electronic and Magnetic Properties of Nitride Thin Films by Doping : The Cases of Chromium Nitride and Boron Nitride2010

    • Author(s)
      K. Inumaru, A. Anzai, M. Fucjhigami, S. Izumi, K. Koyama, S. Yamanaka
    • Organizer
      3^<rd> International Congress on Ceramics
    • Place of Presentation
      大阪
    • Year and Date
      2010-11-15
  • [Presentation] Mesoporous Silica-based Nanocomposite Materials : Design of Water-Tolerant Solid Acid Catalysts and Particles-Mesoporous Silica Composites2009

    • Author(s)
      Kei Inumaru
    • Organizer
      Particles-Mesoporous Silica Composites, International Symposium on Zeolites and Microporous Crystals 2009(ZMPC2009)(Keynote Lecture)
    • Place of Presentation
      東京都
    • Year and Date
      2009-08-06
  • [Presentation] Polyoxometalate H_3PW_<12> O_<40> immobilized in hydrophobic nanospaces of organomodified mesoporous silica as a water-tolerant solid acid catalyst2008

    • Author(s)
      Kei Inumaru
    • Organizer
      14th International Congress on Catalysis
    • Place of Presentation
      ソウル(韓国)
    • Year and Date
      2008-07-14
  • [Presentation] Mesoporous silica-based composite materials as molecular selective photocatalysts for purification of water2008

    • Author(s)
      Kei Inumaru
    • Organizer
      5th International Conference Interfaces Against Pollution 2008(Keynote Lecture)
    • Place of Presentation
      京都市
    • Year and Date
      2008-06-02
  • [Presentation] TiO2 Particles Embedded inMesoporous Silica : Enhanced Photocatalytic Activity for Decomposition of Organic Compounds in Water2008

    • Author(s)
      Kei Inumaru
    • Organizer
      Nanoporous Materials-V
    • Place of Presentation
      バンクーバー(カナダ)
    • Year and Date
      2008-05-27
  • [Book] セラミックス機能化ハンドブック(分担執筆)2011

    • Author(s)
      犬丸啓
    • Total Pages
      457-463
    • Publisher
      NTS
  • [Book] 触媒調製ハンドブック(分担執筆)2011

    • Author(s)
      犬丸啓
    • Total Pages
      192-193, 278-279
    • Publisher
      NTS
  • [Patent(Industrial Property Rights)] 微粒子複合体の製造方法2009

    • Inventor(s)
      犬丸啓、窪田雄之
    • Industrial Property Rights Holder
      国立大学法人広島大学
    • Industrial Property Number
      特許、特許公開2011-62587
    • Filing Date
      2009-09-15

URL: 

Published: 2013-07-31  

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