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2010 Fiscal Year Final Research Report

Study of polymer thin films for processing of metal thin films in thermal nanoimprint lithography

Research Project

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Project/Area Number 20350103
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionTohoku University

Principal Investigator

NAKAGAWA Masaru  東北大学, 多元物質科学研究所, 教授 (10293052)

Co-Investigator(Renkei-kenkyūsha) MATSUI Shinji  兵庫県立大学, 高度産業科学技術研究所, 教授 (00312306)
Research Collaborator KUBO Shoichi  東北大学, 多元物質科学研究所, 助教 (20514863)
Project Period (FY) 2008 – 2010
Keywords高分子構造・物性 / 微細加工 / ナノ材料
Research Abstract

Thermoplastic polymer thin films showing resist property suitable for wet processing of metal thin films on substrates were studied for scientific understanding of reactive-monolayer-assisted thermal nanoimprint lithography using photoreactive adsorbed monolayers which form chemical covalent bonds at resist polymer and metal interface. We demonstrated the kind of thermoplastic polymers effectively grafted to photoreactive groups, the kind of thermoplastic polymer and its optimum molecular weight suitable for metal wet etching and electrodeposition, molecular-weight-dependent permeation behavior of etching aqueous solution through resist polymer thin film, and usefulness of fluorescent resist to visualize patterned shapes of resist thin films by thermal nanoimprinting.

  • Research Products

    (18 results)

All 2011 2010 2009 2008 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (6 results) Remarks (1 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article]2011

    • Author(s)
      Shoichi Kubo, Yuko Sato, Yoshihiko Hirai, Masaru Nakagawa
    • Journal Title

      J. Appl. Phys.

      Volume: (in press)

    • Peer Reviewed
  • [Journal Article] Reactive-monolayer-assisted thermal nanoimprint lithography with benzo-phenone-containing trimethoxysilane derivative for patterning thin chromium and copper films2010

    • Author(s)
      Shoichi Kubo, Tomoyuki Ohtake, Eui-Chul Kang, Masaru Nakagawa
    • Journal Title

      J. Photopolym. Sci. Technol.

      Volume: 23 Pages: 83-86

    • Peer Reviewed
  • [Journal Article] Resist properties of thin poly(methyl methacrylate)and poly(styrene)films patterned by thermal nanoimprint lithography2010

    • Author(s)
      Koichi Nagase, Shoichi Kubo, Masaru Nakagawa
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 49 Pages: 06GL05-1-06GL05-5

    • Peer Reviewed
  • [Journal Article] ポリ(メタクリル酸メチル)へのベンゾフェノン誘導体の光グラフト反応2009

    • Author(s)
      大嶽知之, 高岡利明, 中川勝
    • Journal Title

      高分子論文集

      Volume: 66 Pages: 111-117

    • Peer Reviewed
  • [Journal Article] Thermal nanoimprint of a poly(styrene)and poly(4-vinylpyridine)double-layer thin film and visualization determination of its internal structure by transmission electron microscopy2009

    • Author(s)
      Masaru Nakagawa, Noriyoshi Kamata, Tomokazu Iyoda, Shinji Matsui
    • Journal Title

      Jpn. J. Appy. Phys.

      Volume: 48 Pages: 06FH12-1-06FH12-6

    • Peer Reviewed
  • [Journal Article] Photo-reactive chemisorbed monolayer suppressing polymer dewetting in thermal nanoimprint lithography2009

    • Author(s)
      Hirokazu Oda, Tomoyuki Ohtake, Toshiaki Takaoka, Masaru Nakagawa
    • Journal Title

      Langmuir

      Volume: 25 Pages: 6604-6606

    • Peer Reviewed
  • [Journal Article] Photo-induced graft reactions of 4-methoxybenzophenone with thermoplastic polymers designed for reactive monolayer-assisted thermal nanoimprint lithography2009

    • Author(s)
      Tomoyuki Ohtake, Hirokazu Oda, Toshiaki Takaoka, Masaru Nakagawa
    • Journal Title

      J. Photopolym. Sci. Technol.

      Volume: 22 Pages: 205-211

    • Peer Reviewed
  • [Journal Article] Optical monitoring of a poly(styrene)residual layer on a photocrosslinkable monolayer in thermal nanoimprint2009

    • Author(s)
      Koichi Nagase, Shoichi Kubo, Tomoyuki Ohtake, Toshiaki Takaoka, Masaru Nakagawa
    • Journal Title

      J. Photopolym. Sci. Technol

      Volume: 22 Pages: 200-204

    • Peer Reviewed
  • [Presentation] Reactive-monolayer-assisted thermal nanoimprint lithography for fine metal patterning2010

    • Author(s)
      Shoichi Kubo, 他2名
    • Organizer
      The 9th International Conference on Nanoimprint and Nanoprint Technology (NNT 2010)
    • Place of Presentation
      Oresund & Copenhagen(デンマーク)
    • Year and Date
      2010-10-14
  • [Presentation] 界面化学結合型熱ナノインプリントリソグラフィによる高分子薄膜の成型と金属薄膜の微細加工2010

    • Author(s)
      中川勝
    • Organizer
      第18回ポリマー材料フォーラム
    • Place of Presentation
      三井化学グループ横浜研究センター(神奈川県)
    • Year and Date
      2010-06-20
  • [Presentation] 界面化学結合型熱ナノインプリントリソグラフィ(IV)-金の電解析出に対するレジストライン幅の影響-2010

    • Author(s)
      永瀬康一, 他4名
    • Organizer
      第59回高分子年次大会
    • Place of Presentation
      パシフィコ横浜(神奈川県)
    • Year and Date
      2010-05-28
  • [Presentation] 界面化学結合型熱ナノインプリントリソグラフィによる高分子薄膜の成型と金属薄膜の微細加工2009

    • Author(s)
      中川勝
    • Organizer
      第18回ポリマー材料フォーラム
    • Place of Presentation
      船堀(東京都)
    • Year and Date
      2009-11-26
  • [Presentation] 熱ナノインプリント-電解めっき法によるマイクロ金バンプの作製2009

    • Author(s)
      永瀬康一, 他3名
    • Organizer
      第56回応用物理学関係連合講演会
    • Place of Presentation
      筑波大学(茨城県)
    • Year and Date
      2009-03-30
  • [Presentation] Photo-induced chemisorption of poly(styrene)resist suppressing partial filling in thermal nanoimprint lithography2008

    • Author(s)
      Hirokazu Oda, 他3名
    • Organizer
      7th International Conference on Nanoimprint and Nanoprint Technology (NNT08)
    • Place of Presentation
      京都国際会議場(京都府)
    • Year and Date
      2008-10-14
  • [Remarks]

    • URL

      http://www.tagen.tohoku.ac.jp/labo/nakagawa/index-j.html

  • [Patent(Industrial Property Rights)] 透明導電基板の製造方法、及び透明導電基板2009

    • Inventor(s)
      川島政彦, 中川勝, 永瀬康一, 大嶽知之, 高岡利明
    • Industrial Property Rights Holder
      旭化成イーマテリアルズ株式会社, 国立大学法人東北大学, 日油株式会社
    • Industrial Property Number
      特許権、特願2009-200724
    • Acquisition Date
      2009-08-31
  • [Patent(Industrial Property Rights)] 蛍光レジスト組成物および、その用途2009

    • Inventor(s)
      大嶽知之, 中川勝, 川島政彦, 高岡利明, 久保祥一
    • Industrial Property Rights Holder
      日油株式会社, 国立大学法人東北大学, 旭化成イーマテリアルズ株式会社
    • Industrial Property Number
      特許権、特願2009-200307
    • Acquisition Date
      2009-08-31
  • [Patent(Industrial Property Rights)] 金属配線基板、およびその製法2009

    • Inventor(s)
      中川勝, 永瀬康一, 大嶽知之, 高岡利明
    • Industrial Property Rights Holder
      日油株式会社, 国立大学法人東北大学
    • Industrial Property Number
      特許権、特願2009-026938
    • Acquisition Date
      2009-02-09

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Published: 2013-07-31  

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