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2010 Fiscal Year Final Research Report

Study on hybrid soft materials-High functionalities and their mechanisms-

Research Project

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Project/Area Number 20350109
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionKawamura Institute of Chemical Research

Principal Investigator

HARAGUCHI Kazutoshi  Kawamura Institute of Chemical Research, 理事・所長(兼室長) (10373391)

Co-Investigator(Kenkyū-buntansha) TAKADA Tetsuo  財団法人川村理化学研究所, 材料化学研究室, 席研究員 (00425670)
KATO Shinji  財団法人川村理化学研究所, 高分子化学研究室, 室長 (10415458)
TAKEHISA Toru  財団法人川村理化学研究所, 材料化学研究室, 研究主任 (70425669)
Co-Investigator(Renkei-kenkyūsha) MURATA Kazutaka  財団法人川村理化学研究所, 材料化学研究室, 客員研究員
LI Huan-Jun  財団法人川村理化学研究所, 材料化学研究室, 客員研究員
MASATOSHI Sakie  財団法人川村理化学研究所, 材料化学研究室, 派遣研究員
FUKASAWA Mieko  財団法人川村理化学研究所, 材料化学研究室, 派遣研究員
Project Period (FY) 2008 – 2010
Keywordsナノ材料 / 複合材料物性 / 表面・界面物性 / ヒドロゲル
Research Abstract

We have studied on hybrid soft materials (e.g., nanocomposite (NC) gels and soft NC (M-NCs)) with unique organic (polymer)/inorganic (clay) network structures. Novel NC gels consisting of PEG/clay system and a new synthetic procedure using photopolymerization have been developed. Also, we analyzed the network structure in detail and revealed the structure-property relationships. Further, we explored to find new functions of NC gel and M-NCs, such as pattern formation, drug delivery, abnormal swelling, cell culture and subsequent detachment, control of phase transition, etc.

  • Research Products

    (51 results)

All 2011 2010 2009 2008 Other

All Journal Article (21 results) (of which Peer Reviewed: 18 results) Presentation (23 results) Book (6 results) Remarks (1 results)

  • [Journal Article] Synthesis and Properties of soft Nanocomposite Materials with novel Organic/inorganic network structures.2011

    • Author(s)
      原口和敏
    • Journal Title

      Polym.J. Vol.43

      Pages: 223-241

    • Peer Reviewed
  • [Journal Article] Stimuli-responsive nanocomposite gels.2011

    • Author(s)
      原口和敏
    • Journal Title

      Colloid.Polym.Sci. Vol.289

      Pages: 455-473

    • Peer Reviewed
  • [Journal Article] 有機・無機ナノコンポジット機能性ゲル2011

    • Author(s)
      原口和敏
    • Journal Title

      Polyfile 2月号、Vol.49

      Pages: 36-37

  • [Journal Article] Hydrophobic Surface Characteristics of Nanocomposite Hydrogels.2010

    • Author(s)
      Kazutoshi Haraguchi, Huan-Jun Li
    • Journal Title

      Macromol.Symp. Vol.291-292

      Pages: 159-167

    • Peer Reviewed
  • [Journal Article] ナノコンポジットゲルの特性と化粧品 素材としての可能性2010

    • Author(s)
      原口和敏、武久敢
    • Journal Title

      FRAGRANCE J. Vol.38

      Pages: 58-64

  • [Journal Article] Modification of Nanocomposite Gels by Irreversible Rearrangement of Polymer/Clay Network Structure through Drying.2010

    • Author(s)
      Kazutoshi Haraguchi, Huan-Jun Li, Huai-Yin Ren, Meifang Zhu
    • Journal Title

      Macromolecules Vol.43

      Pages: 9848-9853

    • Peer Reviewed
  • [Journal Article] Gel Formation and Molecular Characteristics of Poly(N-isopropylacrylamide)Prepared by Free-Radical Redox Polymerization in Aqueous Solution.2010

    • Author(s)
      Yingjia Xu, Guang Li, Kazutoshi Haraguchi
    • Journal Title

      Macromol.Chem.Phys. Vol.211

      Pages: 977-987

    • Peer Reviewed
  • [Journal Article] Molecular Characteristics of Poly(N-isopropylacrylamide)Separated from Nanocomposite Gels by Removal of Clay from the Polymer/Clay Network.2010

    • Author(s)
      Kazutoshi Haraguchi, Yingjia Xu, Guang Li
    • Journal Title

      Macromol.Rapid Commun. Vol.31

      Pages: 718-723

    • Peer Reviewed
  • [Journal Article] Synthesis and Mechanical Properties of a Nanocomposite Gel Consisting of a Tetra-PEG/Clay Network.2010

    • Author(s)
      Mieko Fukasawa, Takamasa Sakai, Ung-il Chung, Kazutoshi Haraguchi
    • Journal Title

      Macromolecules Vol.43

      Pages: 4370-4378

    • Peer Reviewed
  • [Journal Article] Synthesis and Characteristics of Nanocomposite Gels Prepared by In Situ Photopolymerization in an Aqueous System.2010

    • Author(s)
      Kazutoshi Haraguchi, Tetsuo Takada
    • Journal Title

      Macromolecules Vol.43

      Pages: 4294-4299

    • Peer Reviewed
  • [Journal Article] ナノコンポジットゲル-有機/無機ネットワーク構築によるヒドロゲルの物性革新-2010

    • Author(s)
      原口和敏
    • Journal Title

      物性研究 Vol.93

      Pages: 558-568

    • Peer Reviewed
  • [Journal Article] The Effect of Water Content on the Ultimate Properties of Rubbery Nanocomposite Gels.2009

    • Author(s)
      Kazutoshi Haraguchi, Huan-Jun Li
    • Journal Title

      J.Polym.Sci.Part B, Polym.Phys. Vol.47

      Pages: 2328-2340

    • Peer Reviewed
  • [Journal Article] Deformation Mechanism of Nanocomposite Gels Studied by Contrast Variation Small-angle Neutron Scattering.2009

    • Author(s)
      Toshihiko Nishida, Hitoshi Endo, Noboru Osaka, Huan-Jun Li, Kazutoshi Haraguchi, Mitsuhiro Shibayama
    • Journal Title

      Phys.Rev.E Vol.80

      Pages: 030801-1-030801-4

    • Peer Reviewed
  • [Journal Article] Microphase Separation in Nanocomposite Gels.2009

    • Author(s)
      Noboru Osaka, Hitoshi Endo, Toshihiko Nishida, Takuya Suzuki, Huan-Jun Li, Kazutoshi Haraguchi, Mitsuhiro Shibayama
    • Journal Title

      Phys.Rev.E Vol.79

      Pages: 060801-1-060801-4

    • Peer Reviewed
  • [Journal Article] SANSによる高分子ゲルの架橋構造解析2009

    • Author(s)
      原口和敏
    • Journal Title

      高分子 Vol.58

      Pages: 748-749

    • Peer Reviewed
  • [Journal Article] 「ナノコンポジット型ヒドロゲル」を用いた新規医療部材の実用化研究2009

    • Author(s)
      原口和敏
    • Journal Title

      Web Journal Web増刊号 No.105

      Pages: 43-46

  • [Journal Article] ナノコンポジットゲルの機能性2008

    • Author(s)
      原口和敏
    • Journal Title

      未来材料 Vol.8

      Pages: 23-30

    • Peer Reviewed
  • [Journal Article] Unusually High Hydrophobicity and Its Changes Observes on the Newly-Created Surfaces of PNIPA/Clay Nanocomposite Hydrogels.2008

    • Author(s)
      Kazutoshi Haraguchi, Huan-Jun Li, Liyuan Song
    • Journal Title

      J.Colloid.Inter.Sci. Vol.326

      Pages: 41-50

    • Peer Reviewed
  • [Journal Article] Nanocomposite Hydrogels.2008

    • Author(s)
      原口和敏
    • Journal Title

      Curr.Opin.Solid.State.Mater.Sci. Vol.11

      Pages: 47-54

    • Peer Reviewed
  • [Journal Article] Surface-Patterning of Nanocomposite Hydrogel Film by Direct Replica Molding and Subsequent Change in Pattern Size.2008

    • Author(s)
      Liyuan SONG, Meifang ZHU, Yanmo CHEN, Kazutoshi Haraguchi
    • Journal Title

      Polym.J. Vol.40

      Pages: 800-805

    • Peer Reviewed
  • [Journal Article] ナノコンポジットゲル-その本質と多 様な機能-2008

    • Author(s)
      原口和敏
    • Journal Title

      高分子論文集 Vol.65

      Pages: 619-633

    • Peer Reviewed
  • [Presentation] Nanocomposite Gels Prepared by in-situ Photopolymerization in an Aqueous SystemConvention Center.2010

    • Author(s)
      原口和敏
    • Organizer
      International Chemical Congress of Pacific Basin Societies(PACIFICHEM 2010)(Invited)
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2010-12-17
  • [Presentation] 有機/無機複合による機能性ゲル/ソフトマテリアルの創製と展開2010

    • Author(s)
      原口和敏
    • Organizer
      第19回ポリマー材料フォーラム(高分子学会)
    • Place of Presentation
      名古屋名古屋国際会議場(招待講演)
    • Year and Date
      2010-12-03
  • [Presentation] 層状無機クレイによる高分子ゲルのハイブリッド化と機能2010

    • Author(s)
      原口和敏
    • Organizer
      第29回無機高分子研究討論会
    • Place of Presentation
      東京東京理科大学(基調講演)
    • Year and Date
      2010-11-12
  • [Presentation] PEG型ナノコンポジットゲルのネットワーク構造と生分解挙動2010

    • Author(s)
      原口和敏、深澤三惠子
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道北海道大学
    • Year and Date
      2010-09-15
  • [Presentation] ナノコンポジット型ヒドロゲル-クレイ /高分子の創るネットワーク構造のもた らす物性変化-2010

    • Author(s)
      原口和敏
    • Organizer
      第54回粘土科学討論会
    • Place of Presentation
      名古屋名古屋大学(招待講演)
    • Year and Date
      2010-09-07
  • [Presentation] Molecular Characteristics of Poly(N-isopropylacrylamide)Separated from Nanocomposite Gels by Removal of Clay from the Polymer/Clay Network.2010

    • Author(s)
      Kazutoshi Haraguchi, Yingjia Xu
    • Organizer
      20th Polymer Networks Group Meeting 2010(PNG2010)
    • Place of Presentation
      Goslar, Germany
    • Year and Date
      2010-08-30
  • [Presentation] ナノコンポジットゲルからの薬物徐放とその効果2010

    • Author(s)
      武久敢、寿典子、原口和敏
    • Organizer
      第39回医用高分子シンポジウム
    • Place of Presentation
      東京東京大学
    • Year and Date
      2010-07-27
  • [Presentation] Nanocomposite Gels : A Unique Polymer/Clay Network and Their Characteristics.2010

    • Author(s)
      原口和敏
    • Organizer
      Trilateral Meeting on Clays
    • Place of Presentation
      Madrid, Spain (Invited)
    • Year and Date
      2010-06-06
  • [Presentation] 光重合型ナノコンポジットゲルの合成 と分離材への応用2010

    • Author(s)
      高田哲生、原口和敏
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      横浜パシフィコ横浜
    • Year and Date
      2010-05-27
  • [Presentation] 有機/無機ナノコンポジットにおけるクレイモルフォロジー制御2010

    • Author(s)
      村田一高、原口和敏
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      横浜パシフィコ横浜
    • Year and Date
      2010-05-27
  • [Presentation] 有機/無機ネットワーク構造構築によるソフトナノコンポジット材料の創製と物性2010

    • Author(s)
      原口和敏
    • Organizer
      第59回高分子学会年次大会学会賞受賞講演
    • Place of Presentation
      横浜パシフィコ横浜(招待講演)
    • Year and Date
      2010-05-26
  • [Presentation] NCゲルの力の原点を探る-水で出来た ゴムへの近接2010

    • Author(s)
      原口和敏
    • Organizer
      国際高分子基盤研究センター特別シンポジウム
    • Place of Presentation
      東京東京工業大学(招待講演)
    • Year and Date
      2010-04-23
  • [Presentation] Ultra-high hydrophobicity on the surface of nanocomposite hydrogels with a poly(N-isopropylacrylamide)/clay network2009

    • Author(s)
      原口和敏
    • Organizer
      International Conference on Advanced Fibers and Polymer Materials (ICAFPM)
    • Place of Presentation
      Shanghai (Invited : Key note)
    • Year and Date
      20091021-20091023
  • [Presentation] Ultimate Tensile Properties of rubbery nanocomposite gels with different water content2009

    • Author(s)
      Kazutoshi Haraguchi, Huan-Jun Li
    • Organizer
      The 8th International Gel Symposium
    • Place of Presentation
      Kansai Univ.Osaka, Japan
    • Year and Date
      2009-12-03
  • [Presentation] Characteristics of poly (N-isopropylacrylamide)prepared by free-radical redox polymerization and PNIPA in network structure of NC Gel2009

    • Author(s)
      Yingjia Xu, Kazutoshi Haraguchi
    • Organizer
      The 8th International Gel Symposium
    • Place of Presentation
      Kansai Univ.Osaka, Japan
    • Year and Date
      2009-12-02
  • [Presentation] 有機・無機ハイブリッド材料~ネットワ構造とその基本特性2009

    • Author(s)
      原口和敏
    • Organizer
      日本化学会関東支部講演会
    • Place of Presentation
      東京日本化学会(招待講演)
    • Year and Date
      2009-07-14
  • [Presentation] Development of Nanocomposite., Hydrogels for Novel Wound Dressings ASME20092009

    • Author(s)
      Toru Takehisa, Kazutoshi Haraguchi
    • Organizer
      4th Frontiers in Biomedical Devices Conference & Exhibition
    • Place of Presentation
      CA, USA
    • Year and Date
      2009-06-08
  • [Presentation] New Advanced Polymer/Clay Nanocomposites : Gels and Transparent Soft Materials.2009

    • Author(s)
      原口和敏
    • Organizer
      49th High Polymer Research Group Conference : HPRG 2009
    • Place of Presentation
      Cheshire, UK
    • Year and Date
      2009-04-28
  • [Presentation] Fundamental Properties of Nanocomposite Hydrogel With Organic/Inorganic Network Structure.2008

    • Author(s)
      原口和敏
    • Organizer
      IUMRS-ICA2008
    • Place of Presentation
      Nagoya Congress Center, Nagoya (invited)
    • Year and Date
      2008-12-13
  • [Presentation] Nanocomposite Gels Prepared by Using Clay Minerals.2008

    • Author(s)
      原口和敏
    • Organizer
      11th International Symposium on Natural Product Chemistry
    • Place of Presentation
      Karachi University, Pakistan, (invited)
    • Year and Date
      2008-10-30
  • [Presentation] Nanocomposite Gels and Soft Nanocomposites : Unique Organic/Inorganic Network Structures with Extraordinary Optical, Mechanical and Functional Properties.2008

    • Author(s)
      原口和敏
    • Organizer
      8th World Nanocpomsoites Congress 2008
    • Place of Presentation
      Sandiego, CA, (invited)
    • Year and Date
      2008-09-15
  • [Presentation] 有機(PNIPA)/無機(クレイ)ネットワークの構築と特性2008

    • Author(s)
      原口和敏
    • Organizer
      日本ゴム協会第44回夏期講座
    • Place of Presentation
      奈良猿沢荘(招待講演)
    • Year and Date
      2008-07-10
  • [Presentation] ナノコンポジット型ヒドロゲル-クレイ/高分子の創る超高分子構造のもたらす物性変化-2008

    • Author(s)
      原口和敏
    • Organizer
      高分子同友会総合講演会
    • Place of Presentation
      東京化学会館(招待講演)
    • Year and Date
      2008-04-23
  • [Book] 機能性粘土素材の最新動向(III編第11章「高分子ゲルハイブリッド」)2010

    • Author(s)
      原口和敏
    • Total Pages
      290-298
    • Publisher
      シーエムシー出版
  • [Book] CSJ化学レビュー「驚異のソフトマテリアル-最新の機能性ゲル研究-」(第II部第3章「NCゲルの創製によるゲル物性の革新-力学物性を中心として-」)2010

    • Author(s)
      原口和敏
    • Total Pages
      64-69
    • Publisher
      化学同人
  • [Book] ゲルコントロール(第4章第1節,第5項「ナノコンポジット型ヒドロゲル」)2009

    • Author(s)
      原口和敏
    • Total Pages
      466-475
    • Publisher
      情報機構
  • [Book] 有機-無機ハイブリッド材料の新展開(中條善樹監修)(第7章「有機-無機ソフトハイブリッド材料」)2009

    • Author(s)
      原口和敏
    • Total Pages
      80-96
    • Publisher
      シーエムシー出版
  • [Book] 自己組織化ハンドブック(國武豊喜 監修)(第3章第2節「塗料技術-塗膜表面と散逸構造」)2009

    • Author(s)
      原口和敏
    • Total Pages
      657-660
    • Publisher
      エヌ・ティー・エス出版
  • [Book] フィラー大全集(第5章第4節「高クレイ含有ナノコンポジットにおける構造制御と透明性」)2008

    • Author(s)
      原口和敏
    • Total Pages
      608-618
    • Publisher
      技術情報協会
  • [Remarks] ホームページ等

    • URL

      http://www.kicr.or.jp/intro/material/index.html

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Published: 2012-01-26   Modified: 2016-04-21  

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