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2010 Fiscal Year Final Research Report

Development of photo-responsive actuators and their application to intelligent micropump

Research Project

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Project/Area Number 20360112
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Intelligent mechanics/Mechanical systems
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

WATANABE Toshiyuki  東京農工大学, 大学院・工学研究院, 教授 (10210923)

Co-Investigator(Kenkyū-buntansha) TOTANI Kenro  東京農工大学, 工学府, 技術職員 (50397014)
Project Period (FY) 2008 – 2010
Keywordsアクチュエーター / アゾベンゼン / 高分子ゲル / 二光子励起重合 / 光応答性 / マイクロポンプ / 末端架橋法
Research Abstract

Poly(amide acid) gels containing photosensitive azobenzene groups in the main chain have been synthesized. It was found that 405 nm light induced a decrease of local volume due to trans-cis isomerization and 532 nm light irradiation increases a volume of gel.
The gel works as a photosensitive pump that discharge solvent by blue laser irradiation and aspirate solvent under visible light irradiation. The discharge amount of solvent under one pulsating is estimated to be 1×10^<-10> m^3. The discharge amount of solvent from polymer gels synthesized with tetrafunctional crosslinker is 20% larger than that of polymer gels synthesized by use of trifunctional crosslinker.

  • Research Products

    (20 results)

All 2011 2010 2009 2008 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (7 results) Book (4 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Generation of dielectric barrier discharge plasma in supercritical argon2010

    • Author(s)
      Y. Suga, T. Nakajima, T. Watanabe
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 49(7) Pages: 076002/1-076002/4

    • Peer Reviewed
  • [Journal Article] Investigation of quenching mechanism in thermoreversible fluorescence recording materials using thermo-chromic fluorescence resonance energy transfer(tc-FRET)2010

    • Author(s)
      S. Hirata, M. Vach, T. Watanabe
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 49(5) Pages: 052501/1-052501/10

    • Peer Reviewed
  • [Journal Article] 高分子フォトニクスナノ構造制御材料のフォトニクスデバイスへの展開2010

    • Author(s)
      渡辺敏行
    • Volume
      59(5)
    • Pages
      321-324
    • Peer Reviewed
  • [Journal Article] Plasma optical emission spectrometry in supercritical fluid for material synthesis process2010

    • Author(s)
      Y. Suga, T. Watanabe
    • Journal Title

      Trans. Mater. Res. Soc. Jpn

      Volume: 35(1) Pages: 15-17

    • Peer Reviewed
  • [Journal Article] A Simple Fabrication Method for Three-Dimensional Gold Nanoparticle Electrodes and Their Application to the Study of the Direct Electrochemistry of Cytochrome c2010

    • Author(s)
      K. Murata, K. Kajiya, M. Nukaga, Y. Suga, T. Watanabe, N. Nakamura, H. Ohno
    • Journal Title

      Electroanalysis

      Volume: 22(2) Pages: 185-190

    • Peer Reviewed
  • [Journal Article] Scattering-type polarizers consisting of fiber/matrix and method to enhance polarization property2009

    • Author(s)
      K. Totani, H. Hayashi, T. Watanabe
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 48(8) Pages: 082403/1-082403/8

    • Peer Reviewed
  • [Journal Article] Reversible fluorescent on-off recording in a highly transparent polymeric material utilizing fluorescent resonance energy transfer(FRET) induced by heat treatment2008

    • Author(s)
      S. Hirata, T. Watanabe, KS. Lee
    • Journal Title

      Adv. Func. Mater

      Volume: 8(19) Pages: 2869-2879

    • Peer Reviewed
  • [Presentation] 光照射によって屈曲挙動を示す高分子ゲル2011

    • Author(s)
      草野大地、吉原直希、村上義彦、渡辺敏行
    • Organizer
      第20回インテリジェント材料/材料システムシンポジウム
    • Place of Presentation
      東京女子医大
    • Year and Date
      2011-01-16
  • [Presentation] Reversible Fluorescent On-Off Recording in a Highly Transparent Polymeric Material Utilizing Fluorescence Energy Transfer for Multilayer Recording System2010

    • Author(s)
      T. Watanabe, S. Hirata, K. Totani
    • Organizer
      Pacific Chem
    • Place of Presentation
      Hawai, USA
    • Year and Date
      2010-12-16
  • [Presentation] 立体的に対称な四官能架橋剤を用いた末端架橋型剛直性高分子ゲルの物性2010

    • Author(s)
      吉原直希,草野大地,渡辺敏行,野本祐作,柴山充弘,酒井崇匡
    • Organizer
      第59回高分子学会討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-16
  • [Presentation] Synthesis and mechanical properties of novel rigid polymer gels by using hinge-liked cross-linker2009

    • Author(s)
      N. Yoshihara, N. Hosono, T. Sakai and T. Watanabe
    • Organizer
      Gel Sympo 2009
    • Place of Presentation
      Kwansei Gakuin Univ
    • Year and Date
      2009-12-03
  • [Presentation] 新規ヒンジ型架橋高分子ゲルの力学物性2009

    • Author(s)
      吉原直希,細野暢彦,渡辺敏行
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-17
  • [Presentation] ヒンジ型架橋剤を利用した新規剛直性高分子ゲルの合成と評価2009

    • Author(s)
      吉原直希,細野暢彦,渡辺敏行、細野暢彦
    • Organizer
      平成21年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2009-06-11
  • [Presentation] ヒンジ型架橋剤を利用した新規剛直性高分子ゲルの合成2009

    • Author(s)
      吉原直希,細野暢彦,渡辺敏行
    • Organizer
      第58回高分子年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2009-05-27
  • [Book] 高効率二光子吸収材料2011

    • Author(s)
      渡辺敏行
    • Total Pages
      200
    • Publisher
      シーエムシー出版
  • [Book] 光学材料の屈折率制御技術2009

    • Author(s)
      渡辺敏行、魚津吉弘
    • Total Pages
      326
    • Publisher
      シーエムシー出版
  • [Book] 光学材料の屈折率制御技術2009

    • Author(s)
      渡辺敏行
    • Total Pages
      31-41
    • Publisher
      シーエムシー出版
  • [Book] 次世代医療のための高分子材料工学2008

    • Author(s)
      渡辺敏行、中広貴
    • Total Pages
      42-54
    • Publisher
      シーエムシー出版
  • [Remarks]

    • URL

      http://www.tuat.ac.jp/~watanabe

  • [Patent(Industrial Property Rights)] 新規グアナミン化合物、その誘導体及びそれらの製造方法2010

    • Inventor(s)
      大石哲也、渡辺敏行、藤田弘幸、秋山三郎、豊田昭徳
    • Industrial Property Rights Holder
      大石哲也、東京農工大学
    • Industrial Property Number
      特許、特願2010-100674
    • Filing Date
      2010-04-26

URL: 

Published: 2013-07-31  

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