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2010 Fiscal Year Final Research Report

Dominant factors influencing dielectric properties in several biodegradable polymers

Research Project

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Project/Area Number 20360146
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionWaseda University

Principal Investigator

OHKI Yoshimichi  Waseda University, 理工学術院, 教授 (70103611)

Co-Investigator(Kenkyū-buntansha) TANAKA Toshikatsu  早稲田大学, 情報生産システム研究科, 教授 (50253539)
SOTA Takayuki  早稲田大学, 理工学術院, 教授 (90171371)
HIRAI Naoshi  早稲田大学, 理工学術院, 講師 (30329122)
Project Period (FY) 2008 – 2010
Keywords生分解性高分子 / テラヘルツ分光 / 誘電特性 / 電気絶縁 / ポリ乳酸 / 絶縁材料 / フォトルミネセンス
Research Abstract

For typical biodegradable polymers, namely, polyethylene terephthalate succinate, polybutylene succinate, polycaprolactone, polybutylene succinate adipate, polybutylene adipate terephthalate, starch ester, and poly-L-lactic acid, effects of the crystal structure on their dielectric properties were examined by conducting advanced measurements such as photoluminescence using synchrotron radiation, terahertz time domain spectroscopy, and numerical calculations using density functional theory. As a result, much knowledge was obtained on the dominant factors influencing the dielectric properties of biodegradable polymers. This will greatly contribute to the development of eco-friendly dielectric materials.

  • Research Products

    (20 results)

All 2011 2010 2009 2008

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (12 results) Book (1 results)

  • [Journal Article] 原子力発電所における絶縁劣化診断の重要性およびケミルミネセンスによる酸化状態の把握2011

    • Author(s)
      大木義路,平井直志
    • Journal Title

      マテリアルライフ学会誌 Vol.23, No.1

      Pages: 1-9

    • Peer Reviewed
  • [Journal Article] Observation and Analysis of Molecular Vibration Modes in Poly Lactide at Terahertz Frequencies2010

    • Author(s)
      N.Fuse, R.Sato, M.Mizuno, K.Fukunaga, K.Itoh, Y.Ohki
    • Journal Title

      Japan Journal of Applied Physics Vol.49, No.10

      Pages: 102402-1-102402-4

    • Peer Reviewed
  • [Journal Article] 2層誘電体構成の空間電荷分布が示すLDPE/MgOナノコンポジットの良好な絶縁性2010

    • Author(s)
      鐘ヶ江越,石本和之,田中祀捷,大木義路,関口洋逸,村田義直,C.C.Reddy
    • Journal Title

      電気学会論文誌基礎・材料・共通部門誌 Vol.130-A, No.4

      Pages: 349-354

    • Peer Reviewed
  • [Journal Article] Electrical Conduction and Dielectric Relaxation in Polyethylene Terephthalate Succinate2010

    • Author(s)
      F.Kato, Y.Ohki
    • Journal Title

      Electrical Engineering in Japan Vol.170, No.4

      Pages: 1-8

    • Peer Reviewed
  • [Journal Article] L型ポリ乳酸の結晶化度が誘電特性に与える影響2009

    • Author(s)
      彦坂早紀,石川裕人,大木義路
    • Journal Title

      電気学会論文誌A Vol.129, No.4

      Pages: 217-222

    • Peer Reviewed
  • [Journal Article] Temperature Dependence of Complex Permittivity in Biodegradable Polybutylene Succinate2008

    • Author(s)
      H.Ishikawa, Y.Ohki
    • Journal Title

      IEEJ Trans.FM Vol.128, No.10

      Pages: 647-651

    • Peer Reviewed
  • [Journal Article] ポリエチレンテレフタレートサクシネートにおける電気伝導と誘電緩和2008

    • Author(s)
      加藤福太郎,大木義路
    • Journal Title

      電学論A 128, 7

      Pages: 490-496(3)

    • Peer Reviewed
  • [Presentation] Band Gap Energies of Several Insulating Polymers Estimated by Optical Absorption Measurements2010

    • Author(s)
      Y.Ohki, N.Fuse, T.Arai
    • Organizer
      the Conference on Electrical Insulation and Dielectric Phenomena
    • Place of Presentation
      West Lafayette.
    • Year and Date
      2010-10-18
  • [Presentation] Observation of Water Trees Using Terahertz Imaging and Time-domain Spectroscopy2010

    • Author(s)
      R.Sato, N.Fuse, Y.Nakamichi, G.Morita, T.Konishi, M.Mizuno, K.Fukunaga, M.Tanimoto, Y.Ohki
    • Organizer
      the 2010 International Conference on Condition Monitoring and Diagnosis
    • Place of Presentation
      Tokyo.
    • Year and Date
      2010-09-08
  • [Presentation] Effects of Gamma-ray Irradiation and Thermal Aging on the Chemiluminescence in Flame-Retardant Ethylene-Propylene Rubber2010

    • Author(s)
      N.Hirai, Y.Ohki
    • Organizer
      the 2010 International Conference on Condition Monitoring and Diagnosis
    • Place of Presentation
      Tokyo.
    • Year and Date
      2010-09-08
  • [Presentation] Experimental Research on the Feasibility of Biodegradable Polymeric Insulating Materials2010

    • Author(s)
      Y.Ohki, N.Hirai, S.Kaneko, S.Okabe
    • Organizer
      CIGRE (Paris 2010 Aug.23-27) Session 43
    • Place of Presentation
      Paris.
    • Year and Date
      2010-08-25
  • [Presentation] Detection of Electrochemical Migration Growth along the Thickness Direction in a Paper/phenol-resin Composite2010

    • Author(s)
      H.Asakawa, M.Natsui, T.Tanaka, Y.Ohki, T.Maeno, K.Okamoto
    • Organizer
      IEEE 2010 International Conference on Solid Dielectrics
    • Place of Presentation
      Potsdam, Germany.
    • Year and Date
      2010-07-06
  • [Presentation] Space Charge Behavior in Multi-layered Dielectrics with LDPE and LDPE/MgO Nanocomposites2010

    • Author(s)
      E.Kanegae, T.Tanaka, Y.Ohki, Y.Sekiguchi, Y.Murata, C.C.Reddy
    • Organizer
      IEEE 2010 International Conference on Solid Dielectrics
    • Place of Presentation
      Potsdam, Germany.
    • Year and Date
      2010-07-06
  • [Presentation] Experimental and Numerical Analyses of Molecular Vibrations in Amorphous and Crystalline Polylactide at Terahertz Frequencies2010

    • Author(s)
      N.Fuse, R.Sato, M.Mizuno, K.Fukunaga, K.Itoh, Y.Ohki
    • Organizer
      IEEE 2010 International Conference on Solid Dielectrics
    • Place of Presentation
      Potsdam, Germany.
    • Year and Date
      2010-07-06
  • [Presentation] Broadband Dielectric Spectroscopy as a Tool for Polymer Analysis2009

    • Author(s)
      Y.Ohki, N.Fuse, M.Mizuno, K.Fukunaga
    • Organizer
      2nd International Workshop on Terahertz Technology
    • Place of Presentation
      Osaka.
    • Year and Date
      2009-12-01
  • [Presentation] Effect of Crystallinity on the Partial Discharge Resistance of Poly-L-Lactide2009

    • Author(s)
      Y.Ohki, K.Miyata
    • Organizer
      IEEE 2009 Annual Report Conference on Electrical Insulation and Dielectric Phenomena
    • Place of Presentation
      Virginia Beach.
    • Year and Date
      2009-10-21
  • [Presentation] Complex Permittivity Spectra of Several Insulating Polymers at Electrical and THz Frequencies2009

    • Author(s)
      Y.Ohki, N.Fuse, S.Hikosaka, Y.Takemura, M.Mizuno, K.Fukunaga
    • Organizer
      IEEE 2009 Annual Report Conference on Electrical Insulation and Dielectric Phenomena
    • Place of Presentation
      Virginia Beach.
    • Year and Date
      2009-10-19
  • [Presentation] Effects of Blending Various Biodegradable Polymer Plasticizers on the Conduction Current and AC Breakdown Strength in Starch Ester2009

    • Author(s)
      Y.Nemoto, F.Kato, N.Hirai, Y.Ohki, S.Kaneko, S.Okabe
    • Organizer
      Proceedings of the 2008 International Symposium on Electrical Insulating Materials
    • Place of Presentation
      Yokkaichi.
    • Year and Date
      2009-09-10
  • [Presentation] Effects of Crystallinity on Thermally Stimulated Current and Complex Permittivity of Poly(L-lactide)2008

    • Author(s)
      S.Hikosaka, H.Ishikawa, Y.Ohki
    • Organizer
      2008 Annual Report of Conference on Electrical Insulation and Dielectric Phenomena
    • Place of Presentation
      Quebec City.
    • Year and Date
      2008-10-28
  • [Book] 高分子絶縁材料技術とその実例・評価2010

    • Author(s)
      大木義路監修
    • Total Pages
      462
    • Publisher
      サイエンス&テクノロジー

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Published: 2012-01-26   Modified: 2016-04-21  

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