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2010 Fiscal Year Final Research Report

Crystallographic study of superfine step coverage in Supercritical Cu nanoplating

Research Project

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Project/Area Number 20360325
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/treatments
Research InstitutionTokyo Institute of Technology

Principal Investigator

SONE Masato  Tokyo Institute of Technology, 精密工学研究所, 准教授 (30323752)

Co-Investigator(Kenkyū-buntansha) HIGO Yakichi  東京工業大学, 精密工学研究所, 教授 (30016802)
ISHIYAMA Chiemi  東京工業大学, 精密工学研究所, 助教 (00311663)
SHIBATA Akinobu  京都大学, 工学研究科, 助教 (60451994)
Project Period (FY) 2008 – 2010
Keywords精密造形プロセス
Research Abstract

We developed a new electroplating technology, "Supercritical Nanoplating (SNP)" that combines the merits of traditional electroplating and supercritical CO_2 techniques and can provide high uniform metal films. Moreover, we applied nanoparticle technology into SNP in order to conduct integrated circuit wiring, and denoted it as modified-SNP (M-SNP). The aim of this project is to clarify these elemental phenomena and extend crystallographic study of superfine step coverage of integrated circuit wiring. In this project, we succeeded in wiring Cu into ・60nm hole with high aspect ratio, and found that the wired Cu formed single crystal without void.

  • Research Products

    (40 results)

All 2010 2009 2008 Other

All Journal Article (17 results) (of which Peer Reviewed: 17 results) Presentation (18 results) Book (4 results) Remarks (1 results)

  • [Journal Article] Impregnation of Ni-P Metal into Polymer Substrate via Catalyzation in Sc-CO2 and Electroless Plating in Sc-CO2 Emulsion2010

    • Author(s)
      B.H.Woo, M.Sone, A.Shibata, C.Ishiyama,Susumu Edo, M.shi Tokita, Junji Watanabe, Y.Higo
    • Journal Title

      Surface & Coatings Technology Vol.204

      Pages: 1785-1792

    • Peer Reviewed
  • [Journal Article] Effects of CO2 on Ni-P Electroless Plating in an Emulsion of Supercritical CO22010

    • Author(s)
      H.Uchiyama, A.Shibata, M.Sone, Y.Higo
    • Journal Title

      Journal of The Electrochemical Society Vol.157, No.10

      Pages: D550-D552

    • Peer Reviewed
  • [Journal Article] Microstructural development of an electrodeposited Ni layer formed from an additive-free Watts2010

    • Author(s)
      A.Shibata, H.Noda, M.Sone, Y.Higo
    • Journal Title

      Thin Solid Films Vol.518

      Pages: 121-126

    • Peer Reviewed
  • [Journal Article] Evaluation of the block boundary and sub-block boundary strengths of ferrous lath martensite2010

    • Author(s)
      A.Shibata, T.Nagoshi, M.Sone, S.Morito, Y.Higo
    • Journal Title

      Materials Science and Engineering A Vol.527

      Pages: 7538-7544

    • Peer Reviewed
  • [Journal Article] Hydrogen Permeability and Membrane Durability of Novel Pd/.-alumina Graded Membrane2010

    • Author(s)
      M.Seshimo, Minoru Ozawa, M.Sone, M.Sakurai, Hideo Kameyama
    • Journal Title

      Journal of Chemical Engineering of Japan Vol.43, No.11

      Pages: 932-937

    • Peer Reviewed
  • [Journal Article] Bright nickel film deposited by supercritical carbon dioxide emulsion using an additive-free Watt2010

    • Author(s)
      Mark Chang, M.Sone, A.Shibata, C.Ishiyama, Y.Higo
    • Journal Title

      Electrochimica Acta Vol.55

      Pages: 6469-6475

    • Peer Reviewed
  • [Journal Article] Electrochemical Nanoplating Using Supercritical Carbon Dioxide2010

    • Author(s)
      M.Sone
    • Journal Title

      Journal of The Surface Finishing Society of Japan Vol.61, No.8

      Pages: 561-565

    • Peer Reviewed
  • [Journal Article] Effects of Aspect Ratio of Photoresist Patterns on Adhesive Strength between Microsized SU-8 Columns and Silicon Substrate under Bend Loading Condition2010

    • Author(s)
      C.Ishiyama, A.Shibata, M.Sone, Y.Higo
    • Journal Title

      Japanese Journal of Applied Physics Vol.49

      Pages: 06GN14-1-06GN14-5

    • Peer Reviewed
  • [Journal Article] Impregnation of Ni-P Metal into Polymer Substrate via Catalyzation in Sc-CO2 and Electroless Plating in Sc-CO2 Emulsion2010

    • Author(s)
      B.H.Woo, M.Sone, A.Shibata, C.Ishiyama, S.Edo, M.shi Tokita, Junji Watanabe, Y.Higo
    • Journal Title

      Surface & Coating Technology, ELSEVIER Vol.204

      Pages: 1785-1792

    • Peer Reviewed
  • [Journal Article] Microstructural development of an electrodeposited Ni layer formed from an additive-free Watts bath2010

    • Author(s)
      A.Shibata, H.Noda, M.Sone, Y.Higo
    • Journal Title

      Thin Solid Films Volume 518, Issue 18

      Pages: 5153-5158

    • Peer Reviewed
  • [Journal Article] Metallization on polymer via quantitatively controlled catalyzation in Sc- CO2 and electroless plating with Sc-CO2 emulsion for micro and nano device2009

    • Author(s)
      B.H.Woo, M.Sone, A.Shibata, C.Ishiyama, K.Masuda, M.Yamagat, Y.Higo
    • Journal Title

      Microelectronics Engineering. 86

      Pages: 1179-1182

    • Peer Reviewed
  • [Journal Article] Effects of Sc-CO_2_Catalyzation in Metallization on Polymer by Electroless Plating2009

    • Author(s)
      B.H.Woo, M.Sone, A.Shibata, C.Ishiyama, K.Masuda, M.Yamagata, Y.Higo
    • Journal Title

      Surface & Coating Technology 203

      Pages: 1971-1978

    • Peer Reviewed
  • [Journal Article] Functionally graded Pd/g-alumina composite membrane fabricated by electroless plating with emulsion of supercritical CO22009

    • Author(s)
      M.Seshimo, T.Hirai, Md.Mizanur Rahman, Minoru Ozawa, M.Sone, M.Sakurai, Y.Higo, Hideo Kameyama,
    • Journal Title

      Journal of Membrane Science Vol.324

      Pages: 321-326

    • Peer Reviewed
  • [Journal Article] Direct Observation of the Change in Microstructure with Deformation in Ferrous Lath Martensite by Using Micro-Sized Specimen2009

    • Author(s)
      A.Shibata, Y.Ogawa, M.Sone, Y.Higo
    • Journal Title

      Material Science Forum vol.638-642

      Pages: 3514-3519

    • Peer Reviewed
  • [Journal Article] Pd-Ni-P metallic glass film fabricated by electroless alloy plating2009

    • Author(s)
      A.Shibata, Y.Imamura, M.Sone, C.Ishiyama, Y.Higo
    • Journal Title

      Thin Solid Films 517

      Pages: 1935-1938

    • Peer Reviewed
  • [Journal Article] Metallization on Polymer by Catalyzation in Supercritical CO2 and Electroless Plating in Dense CO2 Emulsion2008

    • Author(s)
      B.H.Woo, M.Sone, A.Shibata, C.Ishiyama, K.Masuda, M.Yamagata, Tatsuro Endo, Takeshi Hatsuzawa, Y.Higo
    • Journal Title

      Surface & Coating Technology 202/16

      Pages: 3921-3926

    • Peer Reviewed
  • [Journal Article] Fabrication of a Novel Pd/γ-Alumina Graded Membrane by Electroless Plating on Nanoporous γ-Alumina2008

    • Author(s)
      M.Seshimo, Minoru Ozawa, M.Sone, M.Sakurai, Hideo Kameyama
    • Journal Title

      Journal of Membrane Science 324

      Pages: 181-187

    • Peer Reviewed
  • [Presentation] Metallization for Integrated Circuits via Electroplating in Sc-CO2 Emulsion (Invited Lecture)2010

    • Author(s)
      曽根正人
    • Organizer
      Advanced Metallization Conference 2010(62-63)
    • Year and Date
      20101019-20101022
  • [Presentation] Self-annealing at room temperature of Copper electroplating by additive free bath2010

    • Author(s)
      E.Shinada, Mark Chang, A.Shibata, M.Sone
    • Organizer
      Advanced Metallization Conference 2010(94-95)
    • Year and Date
      20101019-20101022
  • [Presentation] Electrodeposition using Supercritical Carbon Dioxide Emulsion (Invited Lecture)2010

    • Author(s)
      曽根正人
    • Organizer
      13th Asia Pacific Confederation of Chemical Engineering Congress (APCChE 2010)(Vol.205)
    • Year and Date
      20101005-20101008
  • [Presentation] Electroplating of Nickel in Supercritical Carbon Dioxide Emulsion Using Additive-Free Watts Bath2010

    • Author(s)
      Mark Chang, C.Ishiyama, M.Sone
    • Organizer
      13th Asia Pacific Confederation of Chemical Engineering Congress (APCChE 2010)(160)
    • Year and Date
      20101005-20101008
  • [Presentation] Void-free nickel pattern electroplated with supercritical carbon dioxide emulsions2010

    • Author(s)
      Mark Chang, T.Tasaki, C.Ishiyama, M.Sone
    • Organizer
      MNE 2010(P-MEMS-9)
    • Year and Date
      20100919-20100922
  • [Presentation] Pd-Ni-P metallic glass pattern with controllable microstructure fabricated by electroless alloy plating2010

    • Author(s)
      Nobuyuki Yoshida, T.Tasaki, Mark Chang, A.Shibata, C.Ishiyama, M.Sone
    • Organizer
      MNE 2010(P-MEMS-12)
    • Year and Date
      20100919-20100922
  • [Presentation] Characterization of local deformation behavior of martensitic steel using a micro-sized cantilever-beam specimen2010

    • Author(s)
      A.Shibata, T.Nagoshi, M.Sone, S.Morito, Y.Higo
    • Organizer
      31st Risoe International Symposium on Materials Science
    • Year and Date
      20100919-20100922
  • [Presentation] Mark Chang, 曽根正人, Effects of supercritical carbon dioxide treatment on bending properties of microsized SU-9 specimens2010

    • Author(s)
      C.Ishiyama
    • Organizer
      MNE 2010(P-LITH-59)
    • Year and Date
      20100919-20100922
  • [Presentation] Characterization of the Elastic Properties of SU-8 Microposts and Their Adhesion Strength to Silicon Substrates2009

    • Author(s)
      Joao Gasper, C.Ishiyama, M.Sone, Y.Higo, Oliver Paul
    • Organizer
      Proceedings of MRS fall meeting 2009
    • Year and Date
      20091130-20091204
  • [Presentation] 超臨界CO2を利用しためっき技術2009

    • Author(s)
      曽根正人
    • Organizer
      表面技術協会第119回講演大会(招待講演)
    • Place of Presentation
      山梨大学
    • Year and Date
      20090316-20090318
  • [Presentation] 超臨界流体を用いた電気めっき技術,表面技術協会めっき部会2009

    • Author(s)
      曽根正人
    • Organizer
      銀座ブロッサム中央会館(招待講演)
    • Year and Date
      2009-07-24
  • [Presentation] Characterization of texture and microstructure of electrodeposited Ni layer, MRS2008 Fall Meeting2008

    • Author(s)
      H.Noda, C.Ishiyama, A.Shibata, M.Sone, Y.Higo
    • Organizer
      Hynes Convention Center & Sheraton Boston Hotel Boston, MA
    • Year and Date
      20081201-20081205
  • [Presentation] Microstructure of Pd-Ni-P metallic glass film fabricated by electroless alloy plating2008

    • Author(s)
      A.Shibata, Y.Imamura, C.Ishiyama, M.Sone, Y.Higo
    • Organizer
      MRS2008 Fall Meeting, Hynes Convention Center & Sheraton Boston Hotel Boston, MA
    • Year and Date
      20081201-20081205
  • [Presentation] Effects of Aspect Ratio of Micro-sized Photoresist Patterns on Bond Strength between the Photoresist and Si Substrate2008

    • Author(s)
      C.Ishiyama, A.Shibata, M.Sone, Y.Higo
    • Organizer
      MRS2008 Fall Meeting, Dec1-Dec5 (2008) Hynes Convention Center & Sheraton Boston Hotel Boston, MA
    • Year and Date
      20081201-20081205
  • [Presentation] Metallization on polymer via quantitatively controlled catalyzation in Sc-CO2 and electroless plating with Sc-CO2 emulsion for micro and nano device2008

    • Author(s)
      B.H.Woo, M.Sone, A.Shibata, C.Ishiyama,M.Yamagata, K.Masuda, Y.Higo
    • Organizer
      34th International Micro-Nano Engineering Conference (MNE 2008)
    • Place of Presentation
      Athens, Greece
    • Year and Date
      20080915-20080918
  • [Presentation] Improvement of Bond strength between Micro-sized photoresist components and silicon substrate usingsupercritical carbon dioxide cleaning2008

    • Author(s)
      C.Ishiyama, A.Shibata, M.Sone, Y.Higo
    • Organizer
      34th International Micro-Nano Engineering Conference (MNE 2008)
    • Place of Presentation
      Athens.Greece
    • Year and Date
      20080915-20080918
  • [Presentation] Hybrid Technology of Supercritical Fluid Catalyzation and CO2 Emulsion Electroless Plating for Metallization on Polymer2008

    • Author(s)
      B.H.Woo, M.Sone, A.Shibata, K.Masuda, M.Yanagida, C.Ishiyama, Y.Higo
    • Organizer
      The 1st International Symposium on Supercritical Fluid in Fiber and Textile Science 2008(ISSF2008)Tower Hoall Funahori
    • Place of Presentation
      Japan
    • Year and Date
      20080617-20080618
  • [Presentation] Uniform Metal-Film Fabricated by Novel Electroless Plating Method with an Emulsion of Supercritical Carbon Dioxide2008

    • Author(s)
      H.Uchiyama, M.Sone, A.Shibata, Y.Higo
    • Organizer
      The 1st International Symposium on Supercritical Fluid in Fiber and Textile Science 2008(ISSF2008), Tower Hoall Funahori
    • Place of Presentation
      Japan
    • Year and Date
      20080617-20080618
  • [Book] 化学工学会・超臨界流体部会活動成果集2009(ワーキンググループ活動報告書no.6)2009

    • Author(s)
      曽根正人(分担)
    • Total Pages
      178-187
    • Publisher
      (社)化学工学会、超臨界流体部会
  • [Book] 超臨界流体入門(7章7.9ナノプレーティング)2008

    • Author(s)
      曽根正人
    • Total Pages
      196-204
    • Publisher
      丸善株式会社
  • [Book] 超臨界流体技術の開発と応用(第3章6)2008

    • Author(s)
      曽根正人
    • Total Pages
      124-134
    • Publisher
      (株)CMC出版
  • [Book] 鍍金の世界(超臨界流体技術を用いたナノ組織金属材料の創製)2008

    • Author(s)
      曽根正人
    • Total Pages
      30-34
  • [Remarks] ホームページ等

    • URL

      http://www.ames.pi.titech.ac.jp/index.html

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Published: 2012-01-26   Modified: 2016-04-21  

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