2010 Fiscal Year Final Research Report
Preparation of High Performance Asymmetric Catalyst Using the Regularity of the Crystalline Inorganic Solid
Project/Area Number |
20360362
|
Research Category |
Grant-in-Aid for Scientific Research (B)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Catalyst/Resource chemical process
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Research Institution | Osaka University |
Principal Investigator |
JITSUKAWA Koichiro Osaka University, 大学院・基礎工学研究科, 教授 (50235793)
|
Co-Investigator(Kenkyū-buntansha) |
MIZUGAKI Tomoo 大阪大学, 大学院・基礎工学研究科, 准教授 (50314406)
|
Co-Investigator(Renkei-kenkyūsha) |
MITSUDOME Takato 大阪大学, 大学院・基礎工学研究科, 助教 (00437360)
|
Project Period (FY) |
2008 – 2010
|
Keywords | 触媒反応 / 反応場 / 固体触媒 / 不斉反応 / マクロリガンド / 触媒設計 / 有機触媒 |
Research Abstract |
Newly designed catalyst system was developed for preparation of a practical asymmetry synthesis. For preparation of the high performance asymmetric catalyst, asymmetric sphere formed on the surface of regularity inorganic solids is important. Two kinds of the system were examined based on the characteristic of crystalline solid. One was immobilization of the organic catalyst containing the optically active amines to montmorillonite through the ion exchange ability of the solid support. Another was the coordination of the surface atoms of the solid to the active center, in which the solid acted as a macroligand.
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Research Products
(44 results)