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2010 Fiscal Year Final Research Report

Design of Integrated Heterogeneous Catalysts for One-pot Chemical Process

Research Project

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Project/Area Number 20360364
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionOsaka University

Principal Investigator

KANEDA Kiyotomi  Osaka University, 太陽エネルギー化学研究センター, 特任教授 (90029554)

Co-Investigator(Kenkyū-buntansha) JITSUKAWA Koichiro  大阪大学, 大学院・基礎工学研究科, 教授 (50235793)
MIZUGAKI Tomoo  大阪大学, 大学院・基礎工学研究科, 准教授 (50314406)
MITSUDOME Takato  大阪大学, 大学院・基礎工学研究科, 助教 (00437360)
Project Period (FY) 2008 – 2010
Keywords金属ナノ粒子 / ワンポット反応 / 機能集積型触媒 / マクロリガンド
Research Abstract

We have developed highly functionalized heterogeneous metal catalysts based on unique characteristics of inorganic materials such as hydroxyapatite, montmorillonite, and hydrotalcite. These inorganic crystallites are used as macro ligands for active metal species, which are considered as nano-structured catalyst supports. The characteristic features of these catalysts are based on the concerto effect between active metal species and surface properties, such as acidity, basicity, and site isolation, where cooperative catalysis by several immobilized active species on the solid surface can occur. Furthermore, we developed a novel catalyst system for deoxygeneation of epoxides to olefins and one-pot multi reaction systems using these heterogeneous catalysts.

  • Research Products

    (43 results)

All 2011 2010 2009 2008 Other

All Journal Article (26 results) (of which Peer Reviewed: 26 results) Presentation (13 results) Book (3 results) Remarks (1 results)

  • [Journal Article] Selective Deoxygenation of Epoxides to Alkenes with Molecular Hydrogen Using Hydrotalcite-supported Gold Catalyst : A Concerted Effect between Basic Sites and Gold Nanoparticles2011

    • Author(s)
      Akifumi Noujima ; Takato Mitsudome ; Tomoo Mizugaki ; Koichiro Jitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Angew. Chem. Int. Ed. 50

      Pages: 2986-2989

    • Peer Reviewed
  • [Journal Article] HighlyEfficient Gold Nanoparticle-CatalyzedDeoxygenation of Amides, Sulfoxides and Pyridine N-Oxides.2011

    • Author(s)
      Yusuke Mikami ; Akifumi Noujima ; TakatoMitsudome ; Tomoo Mizugaki ; KoichiroJitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Chem. Eur. J. 17

      Pages: 1768-1772

    • Peer Reviewed
  • [Journal Article] ReversibleDehydrogenation-Hydrogenation ofTetrahydroquinoline-quinoline Using asupported Cooper Nanoparticle Catalyst.2011

    • Author(s)
      Yusuke Mikami ; Kaori Ebata ; TakatoMitsudome ; Tomoo Mizugaki ; KoichiroJitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Heterocycles 82

      Pages: 1371-1377

    • Peer Reviewed
  • [Journal Article] Supported monomericvanadium catalyst for dehydration ofamides to form nitriles.2010

    • Author(s)
      Shoichiro Sueoka ; Takato Mitsudome ; Tomoo Mizugaki ; Koichiro Jitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Chem. Commun. 46

      Pages: 8243-8245

    • Peer Reviewed
  • [Journal Article] Creation ofHigh-Valent Manganese Species onHydrotalcite and Its Application toCatalytic Aerobic Oxidation of Alcohols.2010

    • Author(s)
      Kohji Nagashima ; Takato Mitsudome ;Tomoo Mizugaki ; Koichiro Jitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Green Chem. 12

      Pages: 2142-2144

    • Peer Reviewed
  • [Journal Article] RoomTemperature Deoxygenation of Epoxideswith CO Catalyzed byHydrotalcite-supported Gold Nanoparticles in Water.2010

    • Author(s)
      Takato Mitsudome ; Akifumi Noujima ; Yusuke Mikami ; Tomoo Mizugaki ; KoichiroJitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Chem. Eur. J. 16

      Pages: 11818-11821

    • Peer Reviewed
  • [Journal Article] SupportedGold and Silver Nanoparticles for GreenCatalytic Deoxygenation of Epoxidesinto Alkenes.2010

    • Author(s)
      Takato Mitsudome ; Akifumi Noujima ; Yusuke Mikami ; Tomoo Mizugaki ; KoichiroJitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Angew. Chem. Int. Ed. 49

      Pages: 5545-5548

    • Peer Reviewed
  • [Journal Article] Wacker-Type Oxidationof Internal Olefins Using aPdCl_2/N,N-Dimethylacetamide CatalystSystem under Copper-Free ReactionConditions.2010

    • Author(s)
      Takato Mitsudome ; Keiichi Mizumoto ; Tomoo Mizugaki ; Koichiro Jitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Angew. Chem. Int. Ed. 49

      Pages: 1238-1240

    • Peer Reviewed
  • [Journal Article] Selective Deoxygenation of StyreneOxides under a CO Atmosphere UsingSilver Nanoparticle Catalyst.2010

    • Author(s)
      Yusuke Mikami ; Akifumi Noujima ; Takato Mitsudome ; Tomoo Mizugaki ; Koichiro Jitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Tetrahedron Lett. 51

      Pages: 5466-5468

    • Peer Reviewed
  • [Journal Article] Highly Chemoselective Reduction ofNitroaromatic Compounds Using aHydrotalcite-supported SilverNanoparticle Catalyst under a COAtmosphere.2010

    • Author(s)
      Yusuke Mikami ; Akifumi Noujima ; Takato Mitsudome ; Tomoo Mizugaki ; Koichiro Jitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Chem. Lett. 39

      Pages: 223-225

    • Peer Reviewed
  • [Journal Article] Development of Heterogeneous OlympicMedal Metal Nanoparticle Catalysts forEnvironmentally Benign MolecularTransformations Based on the SurfaceProperties of Hydrotalcite.2010

    • Author(s)
      Kiyotomi Kaneda ; Takato Mitsudome ; Tomoo Mizugaki ; Koichiro Jitsukawa
    • Journal Title

      Molecules 15

      Pages: 8988-9007

    • Peer Reviewed
  • [Journal Article] Creation of a Monomeric VanadateSpecies in an Apatite Framework as anActive Heterogeneous Base Catalyst forMichael Reactions in Water.2010

    • Author(s)
      Kiyotomi Kaneda ; Takayoshi Hara ; Norifumi Hashimoto ; Takato Mitsudome ; Tomoo Mizugaki ; Koichiro Jitsukawa
    • Journal Title

      Catal.Today 152

      Pages: 93-98

    • Peer Reviewed
  • [Journal Article] Fine Tuning of Pd0 NanoparticleFormation on Hydroxyapatite and ItsApplication for RegioselectiveQuinoline Hydrogenation.2010

    • Author(s)
      Norifumi Hashimoto ; YusukeTakahashi ; Takayoshi Hara ; ShogoShimazu ; Takato Mitsudome ; TomooMizugaki ; Koichiro Jitsukawa ; KiyotomiKaneda
    • Journal Title

      Chem. Lett. 39

      Pages: 832-834

    • Peer Reviewed
  • [Journal Article] CompleteHydrodechlorination of DDT and ItsDerivatives Using aHydroxyapatite-Supported PdNanoparticle Catalyst.2010

    • Author(s)
      Norifumi Hashimoto ; Takayoshi Hara ; Shogo Shimazu ; Yusuke Takahashi ; TakatoMitsudome ; Tomoo Mizugaki ; KoichiroJitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Chem. Lett. 39

      Pages: 49-51

    • Peer Reviewed
  • [Journal Article] Controlled Synthesis of PdClusters in Subnanometer Range UsingPoly(propylene imine) Dendrimers.2009

    • Author(s)
      Tomoo Mizugaki ; Takayuki Kibata ; Kazuya Ota ; Takato Mitsudome ; KohkiEbitani ; Koichiro Jitsukawa ; KiyotomiKaneda
    • Journal Title

      Chem.Lett. 38

      Pages: 1118-1119

    • Peer Reviewed
  • [Journal Article] Efficient AerobicOxidation of Alcohols using aHydrotalcite-Supported GoldNanoparticle Catalyst.2009

    • Author(s)
      Takato Mitsudome ; Akifumi Noujima ; Tomoo Mizugaki ; Koichiro Jitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Adv. Synth.Catal. 351

      Pages: 1890-1896

    • Peer Reviewed
  • [Journal Article] Supported GoldNanoparticle Catalyst for the SelectiveOxidation of Silanes to Silanols inWater Chem.2009

    • Author(s)
      Takato Mitsudome ; Akifumi Noujima ; Tomoo Mizugaki ; Koichiro Jitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Commun

      Pages: 5302-5304

    • Peer Reviewed
  • [Journal Article] Supported GoldNanoparticles as a Reusable Catalystfor Synthesis of Lactones from DiolsUsing Molecular Oxygen as an Oxidantunder Mild Conditions2009

    • Author(s)
      Takato Mitsudome ; Akifumi Noujima ; Tomoo Mizugaki ; Koichiro Jitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Green Chem. 11

      Pages: 793-797

    • Peer Reviewed
  • [Journal Article] Supported Silver NanoparticleCatalyst for Selective Hydration of Nitriles to Amides in Water.2009

    • Author(s)
      Takato Mitsudome ; Yusuke Mikami ; HaruhiiiiiiuhiruhiMori ; Shusuke Arita ; TomooMizugaki ; Koichiro Jitsukawa ; KiyotomiKaneda
    • Journal Title

      Chem.Commun.

      Pages: 3258-3260

    • Peer Reviewed
  • [Journal Article] Oxidant-Free Lactonization of Diols UsingHydrtalcite - Supported CopperCatalsyts.2009

    • Author(s)
      Yusuke Mikami ; Kaori Ebata ; TakatoMitsudome ; Tomoo Mizugaki ; KoichiroJitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Heterocycles 80

      Pages: 855-861

    • Peer Reviewed
  • [Journal Article] Development of Concerto Metal CatalystsUsing Apatite Compounds for GreenOrganic Syntheses.2009

    • Author(s)
      Kiyotomi Kaneda ; Tomoo Mizugaki
    • Journal Title

      Energy Environ. Sci. 2

      Pages: 655-673

    • Peer Reviewed
  • [Journal Article] PAMAM dendron-stabilised palladiumnanoparticles : effect of generation andperipheral groups on particle size andhydrogenation activity.2008

    • Author(s)
      Tomoo Mizugaki ; M. Murata ; S.Fukubayashi ; Takato Mitsudome ; Koichiro Jitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Chem. Commun.

      Pages: 241-243

    • Peer Reviewed
  • [Journal Article] Oxidant-free alcohol dehydrogenationusing a reusablehydrotalcite-supported silvernanoparticle catalyst.2008

    • Author(s)
      Takato Mitsudome ; Yusuke Mikami ; Hisashi Funai ; Tomoo Mizugaki ; KoichiroJitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Angew. Chem.,Int. Ed. 47

      Pages: 138-141

    • Peer Reviewed
  • [Journal Article] Coppernanoparticles on hydrotalcite as aheterogeneous catalyst foroxidant-free dehydrogenation ofalcohols.2008

    • Author(s)
      Takato Mitsudome ; Y. Mikami ; K.Ebata ; Tomoo Mizugaki ; KoichiroJitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Chem. Commun.

      Pages: 4804-4806

    • Peer Reviewed
  • [Journal Article] Supported silvernanoparticle-catalyzed highlyefficient aqueous oxidation ofphenylsilanes to silanols.2008

    • Author(s)
      Takato Mitsudome ; S. Arita ; H. Mori ; Tomoo Mizugaki ; Koichiro Jitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Angew. Chem.Int. Ed. 47

      Pages: 7938-7940

    • Peer Reviewed
  • [Journal Article] Rhodium-Grafted HydrotalciteCatalyst for Heterogeneous1,4-Addition Reaction of Organoboron Reagents to Electron Deficient Olefins

    • Author(s)
      Ken Motokura ; Norifumi Hashimoto ; Takayoshi Hara ; Takato Mitsudome ; Tomoo Mizugaki ; Koichiro Jitsukawa ; Kiyotomi Kaneda
    • Journal Title

      Green Chem in press

    • Peer Reviewed
  • [Presentation] Selective hydrogenation ofquinolines catalyzed bysize-controlled Pd nanoparticlessupported on hydroxyapatite.2010

    • Author(s)
      Yuusuke Takahashi ; NorifumiHashimoto ; Takato Mitsudome ; TomooMizugaki ; Koichiro Jitsukawa ; KiyotomiKaneda
    • Organizer
      In Pacifichem2010
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      2010-12-18
  • [Presentation] Highly efficientdehydration of amides to nitrilescatalyzed by vanadium-graftedhydrotalcite.2010

    • Author(s)
      Shoichiro Sueoka ; Takato Mitsudome ; Tomoo Mizugaki ; Koichiro Jitsukawa ; Kiyotomi Kaneda
    • Organizer
      In Pacifichem2010
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      2010-12-18
  • [Presentation] Highlyefficient deoxygenation of epoxidesinto alkenes catalyzed byhydrotalcite-supported gold and silvernanoparticles.2010

    • Author(s)
      Akifumi Noujima ; Yusuke Mikami ; TakatoMitsudome ; Tomoo Mizugaki ; KoichiroJitsukawa ; Kiyotomi Kaneda
    • Organizer
      In Pacifichem2010
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      2010-12-18
  • [Presentation] Synthesisof alkyl lactates from triose catalyzedby reusable solid acids usingmontmorillonite.2010

    • Author(s)
      Tomoo Mizugaki ; Syed MuhammadAl-Amsyar ; Takato Mitsudome ; KoichiroJitsukawa ; Kiyotomi Kaneda
    • Organizer
      In Pacifichem2010
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      2010-12-18
  • [Presentation] GoldNanoparticles for Green CatalyticDeoxygenation of Epoxides.2010

    • Author(s)
      Takato Mitsudome ; Akifumi Noujima ; Yusuke Mikami ; Tomoo Mizugaki ; KoichiroJitsukawa ; Kiyotomi Kaneda
    • Organizer
      InPacifichem2010
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      2010-12-18
  • [Presentation] Copper-free Wacker-type Oxidation ofInternal Olefins Using PdCl_2-DMACatalyst System.2010

    • Author(s)
      Takato Mitsudome ; Tomoo Mizugaki ; Koichiro Jitsukawa ; Kiyotomi Kaneda
    • Organizer
      In Pacifichem2010
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      2010-12-18
  • [Presentation] Highly Efficient Deoxygenation ofEpoxides Using Supported GoldNanoparticle Catalyst.2010

    • Author(s)
      Takato Mitsudome ; Tomoo Mizugaki ; Koichiro Jitsukawa ; Kiyotomi Kaneda
    • Organizer
      In 9th Congresson Catalysis and Fine Chemicals
    • Place of Presentation
      Zaragoza, Spain
    • Year and Date
      2010-09-15
  • [Presentation] GreenCatalytic Deoxygenation of EpoxidesUsing Hydrotalcite-supported GoldNanoparticles2010

    • Author(s)
      Akifumi Noujima ; Yusuke Mikami ; TakatoMitsudome ; Tomoo Mizugaki ; KoichiroJitsukawa ; Kiyotomi Kaneda
    • Organizer
      In 3rd International IUPAC Conference on Green Chemistry(ICGC)
    • Place of Presentation
      Canada (Ottawa)
    • Year and Date
      2010-08-16
  • [Presentation] CompletelyChemoselective Reduction ofNitroaromatics Using aHydrotalcite-Supported SilverNanoparticle Catalyst.2010

    • Author(s)
      Yusuke Mikami ; Akifumi Noujima ; TakatoMitsudome ; Tomoo Mizugaki ; KoichiroJitsukawa ; Kiyotomi Kaneda
    • Organizer
      In 3rdInternational IUPAC Conference on GreenChemistry (ICGC)
    • Place of Presentation
      Canada (Ottawa)
    • Year and Date
      2010-08-16
  • [Presentation] Development ofHydrotalcite-supported GoldNanoparticle Catalyst for AerobicOxidation of Alcohols under MildReaction Conditions.2010

    • Author(s)
      Akifumi Noujima ; Takato Mitsudome ; Tomoo Mizugaki ; Koichiro Jitsukawa ; Kiyotomi Kaneda
    • Organizer
      In TOCAT6
    • Place of Presentation
      Sapporo
    • Year and Date
      2010-07-20
  • [Presentation] Discovery ofCopper-free Wacker-type Oxidation ofInternal Olefins Using PdCl2-DMACatalyst System.2010

    • Author(s)
      Takato Mitsudome ; Keiichi Mizumoto ; Tomoo Mizugaki ; Koichiro Jitsukawa ; Kiyotomi Kaneda
    • Organizer
      In TOCAT6
    • Place of Presentation
      Sapporo
    • Year and Date
      2010-07-20
  • [Presentation] Chemoselective Reduction ofNitroaromatic Compounds Using aHydrotalcite-SupportedSilver-Nanoparticle Catalyst under a COAtmosphere.2010

    • Author(s)
      Yusuke Mikami ; Akifumi Noujima ; Takato Mitsudome ; Tomoo Mizugaki ; Koichiro Jitsukawa ; Kiyotomi Kaneda
    • Organizer
      In TOCAT6
    • Place of Presentation
      Sapporo
    • Year and Date
      2010-07-20
  • [Presentation] High Performance Catalysts UsingOlympic Metal Nanoparticles for GreenOrganic Synthesis.2010

    • Author(s)
      Kiyotomi Kaneda ; Takato Mitsudome ; Tomoo Mizugaki ; Koichiro Jitsukawa
    • Organizer
      In Frontiers ofChemistry : From Molecules to Systems
    • Place of Presentation
      Paris
    • Year and Date
      2010-05-21
  • [Book] 固定化触媒(最新グリーンケミストリー)(御園生誠;村橋俊一,Eds.)2011

    • Author(s)
      金田清臣
    • Total Pages
      131
    • Publisher
      講談社
  • [Book] リサイクル型固定化Pd 触媒の開発(クロスカップリング反応基礎と産業応用)2010

    • Author(s)
      金田清臣;森浩亮;水垣共雄;海老谷幸喜
    • Total Pages
      180-190
    • Publisher
      シーエムシー出版
  • [Book] Design of Well-Defined Active Sites onCrystalline Materials for Liquid-PhaseOxidations.(In Modern HeterogeneousOxidation Catalysis : design, reactions,and characterization)(Mizuno, N., Ed.)2009

    • Author(s)
      Kiyotomi Kaneda; Takato Mitsudome
    • Total Pages
      157-183
    • Publisher
      Wiley-VCH Verlag GmbH & Co. KGaA : Weinheim
  • [Remarks] ホームページ等

    • URL

      http://www.cheng.es.osaka-u.ac.jp/kanedalabo/GSCLabo/index-j.html6

URL: 

Published: 2012-01-26   Modified: 2016-04-21  

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