2010 Fiscal Year Final Research Report
Development of catalysts devices for selective oxidation of hydrocabons with O_2
| Project/Area Number |
20360367
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Kanagawa University |
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Principal Investigator |
HIKICHI Shiro Kanagawa University, 工学部, 教授 (10282857)
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| Co-Investigator(Renkei-kenkyūsha) |
NAKAZAWA Jun 神奈川大学, 工学部, 特別助手 (70550888)
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| Project Period (FY) |
2008 – 2010
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| Keywords | 酸化反応 / 錯体触媒 / 固定化錯体触媒 / 酸素活性化 / 過酸化物 / ニッケル / 鉄 |
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| Research Abstract |
Novel homogeneous and heterogeneous catalysts for biomimetic hydrocarbon oxidation process have been developed. Tuning the electronic property of the ligand of the nickel complex catalyst leads to achieve selective hydroxylation of alkane with organic peroxide. A thiophenolate complex of nickel(II) activates 02 through intramolecular electron transfer from sulfer donor ligand to the nickel center. Also, novel immobilized metallocomplex catalysts based on the ligand mimicking the metal-supporting motifs found in the active site of the enzymes have been developed. The iron complex-immobilized catalysts exhibit the catalysis for hydrocarbon oxygenation with aqueous H202 at ambient temperature.
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[Journal Article]2010
Author(s)
Shiro Hikichi, Koyu Fujita, Yoshitaka Manabe, Munetaka Akita, Jun Nakazawa, Hidehito Komatsuzaki
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Journal Title
Eur.J.Inorg.Chem.
Pages: 5529-5537
Peer Reviewed
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