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2010 Fiscal Year Final Research Report

Chemical state of trace elements and their chemical behavior during sedimentation and diagenesis: proxy for paleoenvironment

Research Project

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Project/Area Number 20540475
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Geochemistry/Astrochemistry
Research InstitutionHiroshima University

Principal Investigator

SHIMIZU Hiroshi  Hiroshima University, 大学院・理学研究科, 名誉教授 (60090544)

Co-Investigator(Kenkyū-buntansha) TAKAHASHI Yoshio  広島大学, 大学院・理学研究科, 教授 (10304396)
Project Period (FY) 2008 – 2010
Keywords微量元素 / 希土類元素 / 堆積過程 / 続成過程 / 化学状態 / 古環境 / 堆積物
Research Abstract

Chemical state of trace elements such as rare earth elements (REE) and their chemical behavior during sedimentation and diagenesis were studied, in order to examine trace elements in sediments on the geochemical tracer reflecting their sedimentation environments. It is shown on marine sediments that REE incorporated into Mn oxides during sedimentation were released from Mn oxide dissolution during diagenesis, but the released REE were absorbed to phosphate phase such as apatite during the diagenesis. REE patterns in sedimentary rocks are confirmed to inherit their features as a whole through sedimentation and diagenesis and to be an useful geochemical tool reflecting the depositional environment.

  • Research Products

    (10 results)

All 2010 2009 2008

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (2 results)

  • [Journal Article] Abundances of rare earth elements in crude oils and their partitions in water.2010

    • Author(s)
      R.Nakada, Y.Takahashi, G.Zheng, Y.Yamamoto, H.Shimizu
    • Journal Title

      Geochem. J. 44

      Pages: 411-418

    • Peer Reviewed
  • [Journal Article] Systematic change in relative stabilities of REE-humic complexes at various metal loading levels.2010

    • Author(s)
      Y.Yamamoto, Y.Takahashi, H.Shimizu
    • Journal Title

      Geochem. J. 44

      Pages: 39-63

    • Peer Reviewed
  • [Journal Article] EXAFS study on the cause of enrichment of heavy REEs on bacteria cell surface.2010

    • Author(s)
      Y.Talahashi, M.Yamamoto, Y.Yamamoto, K.Tanaka
    • Journal Title

      Geochim. Cosmochim. Acta 74

      Pages: 5443-5462

    • Peer Reviewed
  • [Journal Article] Speciation of iron in humic substances by X-ray absorption fine structure and its effect on the complexation between humic substances and trace metal irons.2009

    • Author(s)
      Y.Yamamoto, Y.Takahashi, H.Shimizu
    • Journal Title

      Chem. Lett. 38

      Pages: 278-279

    • Peer Reviewed
  • [Journal Article] Determination of the host phase of rare earth elements in natural carbonate using X-ray absorption near-edge structure.2009

    • Author(s)
      K.Tanaka, Y.Takahashi, H.Shimizu
    • Journal Title

      Geochem. J. 43

      Pages: 143-149

    • Peer Reviewed
  • [Journal Article] Observation of transformation of calcite to gypsum in mineral aerosols by Ca K-edge X-ray absorption near-edge structure (XANES).2008

    • Author(s)
      Y.Takahashi, T.Miyoshi, S.Yabuki, Y.Inada, H.Shimizu
    • Journal Title

      Atmospheric Environment 26

      Pages: 6535-6541

    • Peer Reviewed
  • [Journal Article] High-sensitive measurement of uranium L3-edge X-ray absorption near-edge structure (XANES) for the determination of the oxidation states of uranium in crustal materials.2008

    • Author(s)
      Y.Yamamoto, Y.Takahashi, Y.Knai, Y.Watanabe, T.Uruga, H.Tanida, Y.Terada, H.Shimizu
    • Journal Title

      Applied Geochem. 23

      Pages: 2452-2461

    • Peer Reviewed
  • [Journal Article] Local structure of Y and Ho in calcite and its relevance to Y fractionation from Ho in partitioning between calcite and aqueous solution.2008

    • Author(s)
      K.Tanaka, Y.Takahashi, H.Shimizu
    • Journal Title

      Chem Geol. 248

      Pages: 104-113

    • Peer Reviewed
  • [Presentation] 原油中の希土類元素(REE)存在度と水-原油間でのREEの分配2010

    • Author(s)
      中田亮一・高橋嘉夫・鄭国東・清水洋
    • Organizer
      日本地球化学会第57回年会
    • Place of Presentation
      立正大学熊谷キャンパス
    • Year and Date
      2010-09-09
  • [Presentation] 腐植物質-水酸化鉄共存系における希土類元素の固液分配2008

    • Author(s)
      山本祐平・高橋嘉夫・清水洋
    • Organizer
      日本地球化学会第55回年会
    • Place of Presentation
      東京大学駒場キャンパス
    • Year and Date
      2008-09-19

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Published: 2012-01-26   Modified: 2016-04-21  

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