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2010 Fiscal Year Final Research Report

Novel developments in the high-resolution spectroscopic study of reactive transition metal transient species

Research Project

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Project/Area Number 20550010
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionShizuoka University

Principal Investigator

OKABAYASHI Toshiaki  Shizuoka University, 創造科学技術大学院, 教授 (70224045)

Project Period (FY) 2008 – 2010
Keywords含遷移金属活性種 / 高分解能分光 / ナノクラスター
Research Abstract

Fourier transform microwave (FTMW) spectrometer was developed for the high-resolution study of the reactive transition metal transient species. A newly designed laser-ablation system with an electronic discharge was combined with the FTMW spectrometer. Some reactive species were observed with a good S/N ratio. A good prospect is now seen in our current development to extend the high-resolution spectroscopy to more reactive transition metal species like nanoclusters.

  • Research Products

    (18 results)

All 2011 2010 2009 2008

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (13 results)

  • [Journal Article] Low-energy vibrations of the group 10 metal monocarbonyl MCO (M = Ni, Pd, and Pt) : Rotational spectroscopy and force field analysis2011

    • Author(s)
      Toshiaki Okabayashi, Takuya Yamamoto, Emi Y.Okabayashi
    • Journal Title

      Mitsutoshi Tanimoto, J.Phys.Chem. A 115(10)

      Pages: 1869-1877

    • Peer Reviewed
  • [Journal Article] Millimeter- and submillimeter-wave spectroscopy of platinum monocyanide, PtCN2010

    • Author(s)
      Emi Y.Okabayashi, Toshiaki Okabayashi, Takashi Furuya, Mitsutoshi Tanimoto
    • Journal Title

      Chem.Phys.Lett. 492(1-3)

      Pages: 25-29

    • Peer Reviewed
  • [Journal Article] Hyperfine resolved Fourier transform microwave and millimeter-wave spectroscopy of the iodomethyl radical, CH_2I (^2B_1)2010

    • Author(s)
      Stephane Bailleux, Patrik Kania, Jan Skrinsky, Toshiaki Okabayashi, Mitsutoshi Tanimoto, Satoshi Matsumoto, Hiroyuki Ozeki
    • Journal Title

      J.Phys.Chem. 114(14)

      Pages: 4776-4784

    • Peer Reviewed
  • [Journal Article] Detection of free monomeric silver (I) and gold (I) cyanides, AgCN and AuCN : microwave sectra and molecular structure2009

    • Author(s)
      Toshiaki Okabayashi, Emi Y.Okabayashi, Fumi Koto, Toshimasa Ishida, Mitsutoshi Tanimoto
    • Journal Title

      J.Amer.Chem.Soc. 131(33)

      Pages: 11712-11718

    • Peer Reviewed
  • [Journal Article] Microwave spectroscopy of the PBr radical in the X^3Σ- state2008

    • Author(s)
      Toshiaki Okabayashi, Hideaki Kawajiri, Michiaki Umeyama, Chihiro Ide, Sumio Oe, Mitsutoshi Tanimoto
    • Journal Title

      J.Chem.Phys. 129(12)

      Pages: 124301-1-8

    • Peer Reviewed
  • [Presentation] A search for interstellar carbon-chain alcohol HC_4OH in the star forming region L15272011

    • Author(s)
      Mitsutoshi Araki, Shuro Takano, Hiromichi Yamabe, Naohiro, Koshikawa, Koichi Tsukiyama, Aya Nakane, Toshiaki Okabayashi, Arisa Kunimatsu, Nobuhiko Kuze
    • Organizer
      The 66th International Symposium on Molecular Spectroscopy
    • Place of Presentation
      WF06, Columbus, Ohio
    • Year and Date
      20110620-20110624
  • [Presentation] 直線炭素鎖アルコールHC4OH:星形成領域L1527と暗黒星雲TMC-1での探査2011

    • Author(s)
      荒木光典・高野秀路・工藤沙紀・茅根彩花・梅木博也・山辺裕路・築山光一・中根綾・岡林利明・國松亜利沙・久世信彦
    • Organizer
      第11回分子分光研究会
    • Place of Presentation
      広島市立大学 広島市
    • Year and Date
      20110520-20110521
  • [Presentation] 直線炭素鎖アルコールHC_4OHのマイクロ波分光2011

    • Author(s)
      國松亜利沙・田辺沙織・小川智史・久世信彦・中根綾・岡林利明・荒木光典
    • Organizer
      第11回分子分光研究会
    • Place of Presentation
      広島市立大学 広島市
    • Year and Date
      20110520-20110521
  • [Presentation] 一塩化パラジウムPdClのマイクロ波分光2011

    • Author(s)
      岡林利明・喜瀬勇太
    • Organizer
      第11回分子分光研究会
    • Place of Presentation
      広島市立大学 広島市
    • Year and Date
      20110520-20110521
  • [Presentation] マイクロ波分光を用いたPdを含む短寿命分子種の研究2010

    • Author(s)
      喜瀬勇太・岡林恵美・岡林利明
    • Organizer
      第4回分子科学討論会2010 3P014
    • Place of Presentation
      大阪大学豊中キャンパス 大阪府豊中市
    • Year and Date
      20100914-20100917
  • [Presentation] CH_2IClのフーリエ変換マイクロ波スペクトル2010

    • Author(s)
      酒井翔平, 尾関博之, Stephane Bailleux, 岡林利明
    • Organizer
      第4回分子科学討論会2010 2P013
    • Place of Presentation
      大阪大学豊中キャンパス大阪府豊中市
    • Year and Date
      20100914-20100917
  • [Presentation] 一フッ化パラジウムPdFのマイクロ波分光2010

    • Author(s)
      喜瀬勇太・岡林恵美・岡林利明
    • Organizer
      第10回分子分光研究会
    • Place of Presentation
      東京工業大学大岡山キャンパス 東京都目黒区
    • Year and Date
      20100514-20100515
  • [Presentation] Fourier transform microwave and millimeter wave spectroscopy of the iodomethyl radical, CH_2I(X^2B_1)2009

    • Author(s)
      S.Bailleux, H.Ozeki, T.Okabayashi, M.Tanimoto, P.Kania
    • Organizer
      The 30th International Symposium on Free Radicals
    • Place of Presentation
      Savonlinna, Finland
    • Year and Date
      20090725-20090730
  • [Presentation] 一フッ化白金PtFのマイクロ波分光2009

    • Author(s)
      岡林利明・蔵原卓・岡林恵美・谷本光敏
    • Organizer
      第9回分子分光研究会
    • Place of Presentation
      富山大学五福キャンパス 富山市
    • Year and Date
      20090515-20090516
  • [Presentation] 一シアン化パラジウムPdCNのマイクロ波分光2009

    • Author(s)
      喜瀬勇太・岡林恵美・岡林利明
    • Organizer
      第9回分子分光研究会
    • Place of Presentation
      富山大学五福キャンパス 富山市
    • Year and Date
      20090515-20090516
  • [Presentation] AgSHのマイクロ波分光2008

    • Author(s)
      岡林利明・山本拓也・水口伝一朗・岡林恵美・谷本光敏
    • Organizer
      第2回分子科学討論会(2008 1D14)
    • Place of Presentation
      福岡サンパレス 福岡市
    • Year and Date
      20080924-20080927
  • [Presentation] Detection in the Gas-phase of the Iodomethyl Radical, CH_2I, by Fourier Transform Microwave Spectroscopy Combined with Submillimeter-wave Spectroscopy2008

    • Author(s)
      Hiroyuki Ozeki, Toshiaki Okabayashi, Mitsutoshi Tanimoto, Jan Skrinsky, Patrik Kania, Stephane Bailleux
    • Organizer
      The 20th International Conference on High Resolution Molecular Spectroscopy
    • Place of Presentation
      Prague, Czech Republic
    • Year and Date
      20080902-20080906
  • [Presentation] AgSのマイクロ波分光2008

    • Author(s)
      岡林利明・大矢篤志・山本拓也・水口伝一朗・岡林恵美・谷本光敏
    • Organizer
      第8回分子分光研究会
    • Place of Presentation
      神戸大学六甲キャンパス 神戸市
    • Year and Date
      20080516-20080517

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Published: 2012-01-26   Modified: 2016-04-21  

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