2010 Fiscal Year Final Research Report
Synthetic Method for Non-planar Polyaromatic Hydorocarbon Based on Carbon-Hydrogen Bond Cleavage Reaction
Project/Area Number |
20550048
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Organic chemistry
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Research Institution | Osaka Prefecture University |
Principal Investigator |
KEN Kamikawa Osaka Prefecture University, 理学系研究科, 准教授 (40316021)
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Project Period (FY) |
2008 – 2010
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Keywords | 反応有機化学 |
Research Abstract |
We have succeeded synthesis of non-planar polyaromatic hydrocarbon such as helicene and benzoacenaphthylene by utilizing palladium catalyzed direct C-H arylation reactions. These synthetic methodologies gave short steps synthesis without any preactivation of the substrate. The studies of fluorecene in acenaphtylene derivatives were also achieved.
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Research Products
(19 results)
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[Journal Article]
Author(s)
Ogasawara, M.; Wu, W.-Y.; Arae, S.; Morita, T.; Watanabe, S.; Takahashi, T.; Kamikawa, K.J.
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Journal Title
Peer Reviewed
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