2010 Fiscal Year Final Research Report
Exploration of Purely Organic Mole cular Metal Based on Hydrogen-Bond and Charge-Transfer Interaction
| Project/Area Number |
20550051
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Organic chemistry
|
|---|
| Research Institution | Fukui University of Technology |
|---|
Principal Investigator |
NAKASUJI Kazuhiro Fukui University of Technology, 工学部, 教授 (60028230)
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
MORITA Yasushi 大阪大学, 大学院・理学研究科, 准教授 (70230133)
|
|---|
| Project Period (FY) |
2008 – 2010
|
| Keywords | 水素結合 / 電荷移動相互作用 / 分子性金属 / プロトン-電子連動系 / 結晶構造制御 / 電子ドナー分子 / イミダゾール / 核酸塩基 |
|---|
| Research Abstract |
In order to explore purely organic molecular metals exhibiting peculiar properties and multiple functions based on the cooperation of hydrogen-bond and charge-transfer interactions, we have designed and synthesized new electron-donor molecules composed of tetrathiafulvalene analogues and hydrogen-bonding groups such as imidazole and nucleobases. These new molecules formed diverse network structures by robust hydrogen-bonds, and achieved highly conducting charge-transfer complexes with organic electron-acceptors molecules.
|
