2010 Fiscal Year Final Research Report
Metal-metal interaction in tri- and penta-nuclear complexes with linearly arranged d8 metal units
Project/Area Number |
20550053
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic chemistry
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Research Institution | Osaka University |
Principal Investigator |
TSUGE Kiyoshi Osaka University, 大学院・理工学研究部, 教授 (60280583)
|
Project Period (FY) |
2008 – 2010
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Keywords | 金属錯体化学 / 金属間相互作用 |
Research Abstract |
To examine the amplification of metal-metal interaction by formation of multinuclear metal ion array, syntheses of multinuclear complexes and complex ligands which enable the linear arrangement of d^8 metal units were conducted with gold (III) and platinum (II) units. A novel imido bridged gold (III) complex ligand was prepared by the reaction of aminopyrimidine and a planar gold (III) unit with bipyridine.
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