Synthesis of new functional materials by assembly of lantern-type dinuclear complexes

2010 Fiscal Year Final Research Report

• Project/Area Number: 20550066
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Inorganic chemistry
• Research Institution: Shimane University
• Principal Investigator: HANDA Makoto Shimane University, 総合理工学部, 教授 (70208700)
• Co-Investigator(Kenkyū-buntansha): IKEUE Takahisa 島根大学, 総合理工学部, 准教授 (00379033)
• Project Period (FY): 2008 – 2010
• Keywords: 二核錯体 / 集積化 / 磁性 / 液晶 / 置換反応

Research Abstract

Assembled complexes of lantern-type dinuclear complxes composed of two metal ions and four bidentate ligands such as carboxylate ions were synthesized and characterized. Chlorido and cyanato-bridged polymers of ruthenium (II, III) carboxylate dimers with long alkyl chains have shown intra-dimer antiferromagnetisms and liquid crystalline properties. New types of assembled complexes of the lantern-type dimers were also obtained by using formamidinato and carboxylato ligands for supporting the dinuclear skeletons.

Research Products

• [Journal Article] Crystal Structure of Rhodium(II) Formamidinate Dimer with an Axial Acetonitrile Molecule (2011)
  • Author(s): Makoto Handa, Motoi Yasuda, Daisuke Yoshioka, Takahisa Ikeue, Masahiro Mikuriya
  • Journal Title: X-ray Structure Analysis Online 27 Pages: 15-16
  • Peer Reviewed
• [Journal Article] Preparation and crystal structure of tetrakis(m-pivalato-O,O')bis [(pivalic acid-O)rhodium(II)] (2011)
  • Author(s): Masahiro Mikuriya, Jinya Yamamoto, Hideaki Ishida, Daisuke Yoshioka, Makoto Handa
  • Journal Title: X-ray Structure Analysis Online 27 Pages: 7-8
  • Peer Reviewed
• [Journal Article] Luminescence of tetraphenylporphyrin by an energy transfer from phtotexcited ZnO nanaparticle Chem. (2011)
  • Author(s): Ichiro Hiromitsu, Ayana Kawami, Senku Tanaka, Shigekazu Morito, Ryo Sasai, Takahisa Ikeue, Yasuhisa Fujita, Makoto Handa
  • Journal Title: Phys.Lett. 501 Pages: 385-389
  • Peer Reviewed
• [Journal Article] Synthesis, crystal structure, and ^1H NMR spectra of a chloride-bridged chain complex of dinuclear ruthenium(II,III) 3,4,5-tri(ethoxy-d5)benzoate (2010)
  • Author(s): Hideaki Ishida, Makoto Handa, Takahisa Ikeue, Jun Taguchi, Masahiro Mikuriya
  • Journal Title: Chem.Papers 64 Pages: 767-775
  • Peer Reviewed
• [Journal Article] Annulated dinuclear palladium(II) phthalocyanine complex as an effective photo-oxidation catalyst for near-infrared region light (2010)
  • Author(s): Takahisa Ikeue, Makoto Sonoda, Satoshi Kurahashi, Haruaki Tachibana, Daichi Teraoka, Tamotsu Sugimori, Kuninobu Kasuga, Makoto Handa
  • Journal Title: Inorg.Chem.Commun. 13 Pages: 1170-1172
  • Peer Reviewed
• [Journal Article] A Polymer Complex [Cu(O_2CC_6F_5)_2(pyz)]_n Formed from Copper(II) Pentafluorobenzoate and Pyrazine (2009)
  • Author(s): Makoto Handa, Yoshiyuki Ishitobi, Taku Yakuwa, Daisuke Yoshioka, Hideaki Ishida, Masahiro Mikuriya, Ichiro Hiromitsu, Hidekazu Tanaka, Takahisa Ikeue
  • Journal Title: Bull.Chem.Soc.Jpn. 82 Pages: 1277-1279
  • Peer Reviewed
• [Journal Article] Synthesis, Magnetic and Spectral Properties, and Crystal Structure of Mixed-Valence Ruthenium(II,III) 3,4,5-Tributanoxy benzotate, in "Insights into Coordination, Bioinorganic and Applied Inorganic Chemistry," "ed by M.Melnik, J.Sigla, and M.Tatarko (2009)
  • Author(s): Hideaki Ishida, Makoto Handa, Ichiro Hiromitsu, Masahiro Mikuriya
  • Journal Title: Slovak Technical University Press, Bratislava Pages: 197-203
  • Peer Reviewed
• [Journal Article] Synthesis, Crystal Structure, and Spectral and Magnetic Properties of Chloro-Bridged Chain Complex of Dinucler Ruthenium(II,III) 3,4,5-Triethoxybenzoate (2009)
  • Author(s): Hideaki Ishida, Makoto Handa, Ichiro Hiromitsu, Masahiro Mikuriya
  • Journal Title: Chem.J.Mordova 4 Pages: 90-96
  • Peer Reviewed
• [Journal Article] Photoinduced energy transfer in ZnO-tetraphenylporphyrin systems (2009)
  • Author(s): Ichiro Hiromitsu, Takahisa Ikeue, Kazuhiro Karino, Takatsugu Ohno, Senku Tanaka, Hideo Shiratori, Shigekazu Morito, Yasuhisa Fujita, Makoto Handa
  • Journal Title: Chem.Phys.Lett. 474 Pages: 315-319
  • Peer Reviewed
• [Journal Article] Electronic Structure of five- and six-coordinate iron(III) tetraazaporphyrin complex : pyrrole-Cα chemical shift as a useful probe (2008)
  • Author(s): Takahisa Ikeue, Satoshi Kurahashi, Makoto Handa, Tamotsu Sugimori, Mikio Nakamura
  • Journal Title: J.Porphyrins Phthalocyanines 12 Pages: 1041-1049
  • Peer Reviewed
• [Journal Article] Synthesis and magnetic properties of polymeric complexes containing ruthenium(II)-ruthenium(III) tetracarboxylato units linked by cyanato, thiocyanato, and selenocyanato ligands (2008)
  • Author(s): Makoto Handa, Hideaki Ishida, Kayoko Ito, Toshihiro Adachi, Takahisa Ikeue, Ichiro Hiromitsu, Masahiro Mikuriya, Kuninobu Kasuga
  • Journal Title: Chem.Pap. 62 Pages: 410-416
  • Peer Reviewed
• [Presentation] Synthesis, One-dimensional Polymer Complexes of Rhodium(II) Carboxylates and N,N'-Bidentate Ligands (2011)
  • Author(s): Masahiro Mikuriya, Junya Yamamoto, Kazuya Ouchi, Yasutaka Nakanishi, Daisuke Yoshioka, Hidekazu Tanaka, Makoto Handa
  • Organizer: Second International Conference on Multifunctional, Hybrid & Nanomaterials
  • Place of Presentation: Strasbourg, France
  • Year and Date: 2011-03-07
• [Presentation] Lantern-type Dirhodium(II) Complexes with Formamidinato and Carboxylato Bridges (2010)
  • Author(s): 半田真, 池上崇久, 吉岡大輔, 御厨正博
  • Organizer: XVIIth International Winter School on Coordination Chemistry
  • Place of Presentation: Karpacz, Poland
  • Year and Date: 2010-12-08
• [Presentation] Paddlewheel-type dirhodium(II) complexes with formamidinato and carboxylato bridges (2010)
  • Author(s): 半田真
  • Organizer: The Polish-Japan Symposium Chemistry of Modern Materials
  • Place of Presentation: Torun, Poland
  • Year and Date: 2010-12-03
• [Presentation] ホルムアミジナートイオンとカルボン酸イオンを分子内架橋配位子とするランタン型ロジウム(II)二核錯体の合成と性質 (2010)
  • Author(s): 半田真, 池上崇久, 井上麻美, 竹原正大, 井上涼子, 杉森保, 吉岡大輔, 御厨正博
  • Organizer: 2010年日本化学会西日本大会
  • Place of Presentation: 熊本
  • Year and Date: 2010-11-06
• [Presentation] ホルムアミジナートイオンとカルボン酸イオンを架橋配位子とするランタン型ロジウム(II)錯体 (2010)
  • Author(s): 半田真, 池上崇久, 吉岡大輔, 御厨正博
  • Organizer: 2010年錯体分子素子研究センターシンポジウム
  • Place of Presentation: 三田
  • Year and Date: 2010-10-02
• [Presentation] 3,4,5-トリ(エトキシ-d_5)安息香酸ルテニウム(II,III)二核のクロリド架橋鎖状錯体の結晶構造および磁気的性質 (2010)
  • Author(s): 石田英晃, 半田真, 広光一郎, 御厨正博
  • Organizer: 2010年錯体分子素子研究センターシンポジウム
  • Place of Presentation: 三田
  • Year and Date: 2010-10-02
• [Presentation] 酢酸ロジウム(II)及び安息香酸ロジウム(II)二核の鎖状錯体の結晶構造と窒素吸着性質 (2010)
  • Author(s): 御厨正博, 山本淳也, 大内和也, 中西康貴, 吉岡大輔, 田中秀和, 半田真
  • Organizer: 2010年錯体分子素子研究センターシンポジウム
  • Place of Presentation: 三田
  • Year and Date: 2010-10-02
• [Presentation] Rhodium(II) Dinuclear Complexes with Formamidinato and Carboxylato Bridges (2010)
  • Author(s): 半田真, 池上崇久, 井上麻美, 竹原正大, 井上涼子, 杉森保, 吉岡大輔, 御厨正博
  • Organizer: 60th Anniversary Conference on Coordination Chemistry in OSAKA
  • Place of Presentation: Japan, Osaka, Japan
  • Year and Date: 2010-09-28
• [Presentation] Synthesis, Crystal Structures, and Adsorption Properties of Chain Complexes of Rhodium(II) Acerate and Rhodium(II) Benzoate with N,N'-Bidentate Ligands (2010)
  • Author(s): Masahiro Mikuriya, Junya Yamamoto, Kazuya Ouchi, Yasutaka Nakanishi, Daisuke Yoshioka, Hidekazu Tanaka, Makoto Handa
  • Organizer: IVth International Conference on Molecular Materials MOLMAT 2010
  • Place of Presentation: Montpellier, France
  • Year and Date: 2010-07-06
• [Presentation] Polymer Complexes Formed from Copper(II) and Rhodium(II) Benzoates and Bidentate Bridging Ligands with Nitrogen Donors (2009)
  • Author(s): M.Handa, Y.Ishitobi, D.Yoshioka, M.Mikuriya,I.Hiromitsu, H.Tanaka, T.Ikeue
  • Organizer: XVIth Winter School on Coordination Chemistry
  • Place of Presentation: Karpacz, Poland
  • Year and Date: 2009-12-09
• [Presentation] 3,4,5-トリアルコキシ安息香酸混合原子価ルテニウム二核のクロロ架橋鎖状錯体の結晶構造 (2009)
  • Author(s): 石田英晃, 半田真, 御厨正博
  • Organizer: 日本結晶学会2009年度年会
  • Place of Presentation: 関西学院大学(西宮市)
  • Year and Date: 2009-12-06
• [Presentation] ホルムアミジンとフェロセンカルボン酸を分子内架橋配位子に用いたルテニウム(II,III)二核錯体の合成と性質 (2009)
  • Author(s): 池上崇久, 狩野和弘, 木村祐子, 杉森保, 吉岡大輔, 御厨正博, 半田真
  • Organizer: 2009年日本化学会西日本大会
  • Place of Presentation: 愛媛大学(松山市)
  • Year and Date: 2009-11-07
• [Presentation] クロロ架橋3,4,5-トリアルコキシ安息香酸ルテニウム錯体の溶液挙動 (2009)
  • Author(s): 石田英晃, 田口潤, 半田真, 池上崇久, 御厨正博
  • Organizer: 2009年日本化学会西日本大会
  • Place of Presentation: 愛媛大学(松山市)
  • Year and Date: 2009-11-07
• [Presentation] 安息香酸ロジウム(II)と二座架橋配位子からなる鎖状錯体の結晶構造と吸着特性 (2009)
  • Author(s): 御厨正博, 山本淳也, 大内和也, 中西康貴, 吉岡大輔, 田中秀和, 半田真
  • Organizer: 2009年日本化学会西日本大会
  • Place of Presentation: 愛媛大学(松山市)
  • Year and Date: 2009-11-07
• [Presentation] 3-カルボキシ-PROXYLを用いた二核銅(II)錯体の合成と磁気的性質 (2009)
  • Author(s): 御厨正博, 松原静香, 中村知端, 横田和幸, 福崎雅文, 吉岡大輔, 半田真
  • Organizer: 2009年日本化学会西日本大会
  • Place of Presentation: 愛媛大学(松山市)
  • Year and Date: 2009-11-07
• [Presentation] New Magnetic Materials Based on Dinuclear Ruthenium Carboxylates (2009)
  • Author(s): Masahiro Mikuriya, Daisuke Yoshioka, Ana Borta, Dominique Luneau, Dariusz Matoga, Janusz Szklarzewicz, Makoto Handa
  • Organizer: European Conference on Molecular Magnetism ECMM 2009
  • Place of Presentation: Wroclaw, Poland
  • Year and Date: 2009-10-07
• [Presentation] ジフェニルホルムアミジナートイオンを架橋配位子とするランタン型ルテニウム(II,III)二核錯体の合成と性質 (2009)
  • Author(s): 木村祐子, 池上崇久, 吉岡大輔, 石田英晃, 杉森保, 御厨正博, 半田真
  • Organizer: 第59回錯体化学討論会
  • Place of Presentation: 長崎大学(長崎市)
  • Year and Date: 2009-09-25
• [Presentation] Syntheses, Magnetic and Spectral Properties, and Crystal Structure of Mixed-valence (2009)
  • Author(s): 石田英晃, 半田真, 広光一郎, 御厨正博
  • Organizer: XXII. International Conference on Coordination and Bioinorganic Chemistry
  • Place of Presentation: Smolenice, Slovakia
  • Year and Date: 2009-06-09
• [Presentation] One-dimensional Chloro-bridged Chain Complexes of Dinuclear Ruthenium(II,III) 3,4,5-Trialkoxybenzoates (2009)
  • Author(s): 石田英晃, 半田真, 広光一郎, 御厨正博
  • Organizer: The International Conference dedicated to the 50th anniversary from the foundation of the Institute of Chemistry of the Moldavian Academy of Sciences
  • Place of Presentation: Chisinau, Moldova
  • Year and Date: 2009-05-26
• [Presentation] カルボン酸とジフェニルホルムアミジンからなるランタン型ルテニウム(II,III)二核錯体の合成と性質 (2009)
  • Author(s): 木村祐子, 池上崇久, 石田英晃, 杉森保, 御厨正博, 半田真
  • Organizer: 第89回日本化学会春季年会
  • Place of Presentation: 日本大学(船橋市)
  • Year and Date: 2009-03-28
• [Presentation] ホルムアミジナートイオンを分子内架橋配位子に用いたランタン型ロジウム(II)二核錯体およびその四量体の合成と性質 (2008)
  • Author(s): 井上麻美, 吉岡大輔, 池上崇久, 杉森保, 御厨正博, 半田真
  • Organizer: 2008年日本化学会西日本大会
  • Place of Presentation: 長崎大学(長崎市)
  • Year and Date: 2008-11-15
• [Presentation] 環周辺にニトロ基を有するポルフィリン鉄(III)錯体の合成と性質 (2008)
  • Author(s): 池上崇久, 山本健一, 中村幹夫, 杉森保, 半田真
  • Organizer: 2008年日本化学会西日本大会
  • Place of Presentation: 長崎大学(長崎市)
  • Year and Date: 2008-11-15
• [Presentation] 酢酸ロジウムと二座架橋配位子からなる鎖状錯体の結晶構造と吸着特性 (2008)
  • Author(s): 御厨正博, 山本淳也, 大内和也, 吉岡大輔, 田中秀和, 半田真
  • Organizer: 2008年日本化学会西日本大会
  • Place of Presentation: 長崎大学(長崎市)
  • Year and Date: 2008-11-15
• [Presentation] チオオキザミド金属錯体の合成と性質 (2008)
  • Author(s): 新田展大, 東浦大二郎, 末次裕太, 池上崇久, 石田英晃, 御厨正博, 半田真
  • Organizer: 2008年日本化学会西日本大会
  • Place of Presentation: 長崎大学(長崎市)
  • Year and Date: 2008-11-15
• [Presentation] トリス長鎖アルキルオキシ安息香酸ルテニウム二核錯体の磁気的性質及び液晶的性質 (2008)
  • Author(s): 石田英晃, 半田真, 池上崇久, 広光一郎, 氏家誠司, 御厨正博
  • Organizer: 2008年日本化学会西日本大会
  • Place of Presentation: 長崎大学(長崎市)
  • Year and Date: 2008-11-15
• [Presentation] カルボン酸架橋ランタン型ルテニム(II,III)錯体の溶液中に於ける磁気的挙動 (2008)
  • Author(s): 真野貴行, 池上崇久, 石田英晃, 御厨正博, 半田真
  • Organizer: 2008年日本化学会西日本大会
  • Place of Presentation: 長崎大学(長崎市)
  • Year and Date: 2008-11-15
• [Presentation] 4-?カルボキシ-TEMPO二核銅(II)の鎖状錯体の合成と磁気的性質 (2008)
  • Author(s): 御厨正博, 松原静香, 中村知端, 橋戸里江子, 横田和幸, 渡辺武士, 吉岡大輔, 半田真
  • Organizer: 2008年日本化学会西日本大会
  • Place of Presentation: 長崎大学(長崎市)
  • Year and Date: 2008-11-14
• [Presentation] 種々の置換基を導入したホルムアミジナートイオンを架橋配位子とするルテニウム(II,III)二核錯体の合成と性質 (2008)
  • Author(s): 池上崇久, 狩野和弘, 木村祐子, 今岡剛, 杉森保, 半田真
  • Organizer: 第58回錯体化学討論会
  • Place of Presentation: 金沢大学(金沢市)
  • Year and Date: 2008-09-21
• [Presentation] ジフェニルホルムアミジナートイオンを分子内架橋配位子に含むルテニウム(II,III)二核錯体の合成と性質 (2008)
  • Author(s): 木村祐子, 池上崇久, 石田英晃, 杉森保, 御厨正博, 半田真
  • Organizer: 第58回錯体化学討論会
  • Place of Presentation: 金沢大学(金沢市)
  • Year and Date: 2008-09-20
• [Presentation] 3,4,5-トリアルコキシ安息香酸ルテニウム(II,III)二核錯体の合成,磁気的性質及び液晶性 (2008)
  • Author(s): 石田英晃, 半田真, 池上崇久, 広光一郎, 氏家誠司, 御厨正博
  • Organizer: 第58回錯体化学討論会
  • Place of Presentation: 金沢大学(金沢市)
  • Year and Date: 2008-09-20
• [Presentation] Magnetic and Mesomorphic Properties of Chain Complexes of Dinuclear Ruthenium(II,III) 3,4,5-Trialkoxybenzoates (2008)
  • Author(s): 石田英晃, 半田真, 広光一郎, 氏家誠司, 御厨正博
  • Organizer: 3rd International Symposium on Molecular Materials MOLMAT 2008
  • Place of Presentation: Toulouse, France
  • Year and Date: 2008-07-08
• [Presentation] Syntheses and Properties of Chain Complexes of Dinuclear Ruthenium(II,III) 3,4,5-Triethoxybenzoate with Chloro and Cyanato Bridging Ligands (2008)
  • Author(s): 石田英晃, 半田真, 広光一郎, 御厨正博
  • Organizer: 3rd International Symposium on Molecular Materials MOLMAT 2008
  • Place of Presentation: Toulouse, France
  • Year and Date: 2008-07-08
• [Presentation] 3,4,5-トリオクタデカノキシ安息香酸ルテニウム(II,III)二核カチオンと種々のアニオンを組み合わせた錯体の合成と性質 (2008)
  • Author(s): 石田英晃, 半田真, 広光一郎, 氏家誠司, 御厨正博
  • Organizer: 錯体分子素子研究センターシンポジウム
  • Place of Presentation: 関西学院大学(三田市)
  • Year and Date: 2008-04-19
• [Presentation] 安息香酸ロジウム(II)およびピバル酸ロジウム(II)とピリミジンからなる新規錯体の合成と結晶構造及び吸着特性 (2008)
  • Author(s): 山本淳也, 吉岡大輔, 御厨正博, 半田真, 田中秀和
  • Organizer: 錯体分子素子研究センターシンポジウム
  • Place of Presentation: 三田市
  • Year and Date: 2008-04-19
• [Presentation] ホルムアミジナートロジウム(II)二核を架橋二座配位子で連結したポリマー錯体の構造と性質 (2008)
  • Author(s): 半田真, 佐仲綾, 井上麻美, 田中秀和, 池上崇久, 吉岡大輔, 御厨正博
  • Organizer: 錯体分子素子研究センターシンポジウム
  • Place of Presentation: 関西学院大学(三田市)
  • Year and Date: 2008-04-19
• [Remarks] ホームページ等