2010 Fiscal Year Final Research Report
Synthesis of the Group 6 Metal Complexes Related to Hydroxylase Active Sites using Water as a Reactant and Their Catalytic Activities
| Project/Area Number |
20550067
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Osaka City University |
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Principal Investigator |
SUGIMOTO Hideki Osaka City University, 工学研究科, 准教授 (00315970)
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| Project Period (FY) |
2008 – 2010
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| Keywords | モリブデン錯体 / タングステン錯体 / オキソ錯体 / スルフィド錯体 / セレニド錯体 / 酸化反応 |
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| Research Abstract |
Molybdenum(VI)-oxo, -sulfido, and -selenido complexes were prepared. Upon oxidizing oxomolybdenum(IV) complexes electrochemically or chemically in the presence of water, six-coordinate dioxomolybdenum(VI) complexes having one oxo group derived from the water molecule were prepared. Additionally, sulfido-, and selenido-molybdenum(VI) complexes were prepared from its silanolate derivative and the hydrogensulfide or hydrogenselenide. The effects of the terminal sulfido and selenido groups on the atom transfer reactivity and electronic structures were examined.
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[Journal Article] Chalcogenidobis(ene-1,2-dithiolate)molyb denum(IV) Complexes (Chalcogenide E=S,Se) : Probing Mo≡E and Ene-1,2-dithiolate Substituent Effects on Geometric and Electronic Structure2011
Author(s)
Hideki Sugimoto, Hiroyuki Tano, Koichiro Suyama, Tomoya Kobayashi, Hiroyuki Miyake, Shinobu Itoh, Regina P.Mtei, Martin L.Kirk
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Journal Title
Dalton Trans. 40
Pages: 1119-1131
Peer Reviewed
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[Journal Article] Dioxo?Molybdenum(VI) Complexes with Ene-1,2-dithiolate Ligand : Synthesis, Spectroscopy, and Oxygen Atom Transfer Reactivity2009
Author(s)
Hideki Sugimoto, Susumu Tatemoto, Koichiro Suyama, Hiroyuki Miyake, Shinobu Itoh, Chao Dong, Jing Yang, Martin L.Kirk
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Journal Title
Inorg.Chem. 48
Pages: 10581-10590
Peer Reviewed
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