2010 Fiscal Year Final Research Report
Research in novel catalyses using dinuclear allyl and propargyl complexes
| Project/Area Number |
20550091
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Shizuoka University |
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Principal Investigator |
TSUKADA Naofumi Shizuoka University, 理学部, 准教授 (70292240)
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| Project Period (FY) |
2008 – 2010
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| Keywords | パラジウム / 白金 / 二核錯体 / アリル化合物 / プロパルギル化合物 |
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| Research Abstract |
Several new allyl palladium and platinum complexes having chelate bridging ligands were synthesized and utilized as catalyst for novel transformation of organic compounds. We found that the dinuclear allyl complexes exhibited different selectivity from mononuclear complexes in the cross-coupling of phenylboric acid and allyl compounds, and developed a novel method for preparation of tetrahydrofuranes from carbonyl compounds and isobutenes having two leaving groups.
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