2010 Fiscal Year Final Research Report
Living radical polymerization of fluorine vinyl monomer using long-term radicals in solid state and application of fuel cell membrane.
| Project/Area Number |
20550117
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Japan Atomic Energy Agency |
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Principal Investigator |
HASEGAWA Shin Japan Atomic Energy Agency, 量子ビーム応用研究部門, 研究員 (60354940)
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| Co-Investigator(Kenkyū-buntansha) |
MAEKAWA Yasunari 独立行政法人日本原子力研究開発機構, 量子ビーム応用研究部門, 研究主幹 (30354939)
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| Project Period (FY) |
2008 – 2010
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| Keywords | 機能性高分子 |
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| Research Abstract |
For synthesis of polymer electrolyte membrane (PEM) that can be applied to fuel cells for mobile electricity in vehicles, as well as a domestic co-generation system, radiation-induced graft polymerization is a convenient method to introduce directly graft chains with proton conductivity into fluorine polymer. A superior durable PEM which introduced fluorine vinyl monomer into polymer films can be obtained by using both long-term radicals by irradiation for graft polymerization and stable radicals for living radical polymerization.
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