2010 Fiscal Year Final Research Report
Construction of Specific Reaction Media Using Alternating Polymer Consisting of Hetero-Macrocyclic Host Molecules
| Project/Area Number |
20550120
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Functional materials chemistry
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| Research Institution | Kanazawa University |
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Principal Investigator |
NAKAMOTO Yoshiaki Kanazawa University, 自然科学研究科, 特別研究員 (20019772)
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| Co-Investigator(Kenkyū-buntansha) |
YAMAGISHI TadaーAki 金沢大学, 物質化学系, 教授 (90220251)
OGOSHI Tomoki 金沢大学, 物質化学系, 准教授 (00447682)
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| Project Period (FY) |
2008 – 2010
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| Keywords | 環状ホスト分子 / ホストーゲスト包接錯体 / 交互共重合 / 濁点 / 蛍光 |
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| Research Abstract |
We synthesized a novel alternating copolymer composed of calix[4]arene and calix[6]arene. Compared to the model compounds of calix[4]arene and calix[6]arene, the alternating copolymer strongly captured fluoranthene because of multipoint host-guest interactions between the calixarenes in the alternating copolymer and fluoranthene. We also synthesized novel thermo-sensitive polymer carrying two stations of decyl and viologen moieties at the side chain. The polymer was prepared by radical copolymerization of N-isopropylacrylamide and styrene derivative having decyl and viologen moieties. The decyl and viologen moieties of the polymer formed host-guest complex with α-cyclodextrin and cucurbit[7]uril, respectively.
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