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2010 Fiscal Year Final Research Report

Control of spin structures by using program molecules

Research Project

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Project/Area Number 20550127
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionHiroshima University (2010)
Osaka Prefecture University (2008-2009)

Principal Investigator

NISHIHARA Sadafumi  広島大学, 大学院・理学研究科, 准教授 (00405341)

Co-Investigator(Renkei-kenkyūsha) HOSOKOSHI Yuko  大阪府立大学, 大学院・理学系研究科, 教授 (50290903)
Project Period (FY) 2008 – 2010
Keywordsプログラム分子 / 配列制御 / 磁性 / 結晶構造 / 磁気構造
Research Abstract

We have been studying on the controlling molecular arrangements of organic radicals by hydrogen and metal-organic coordination bonds. In order to achieve the purpose, the program molecule having hydrogen bonding and metal coordination sites are introduced to radical compounds. As the results, we succeeded in the preparation of novel compounds and the determination of the magnetic structures of these compounds.

  • Research Products

    (48 results)

All 2011 2010 2009 2008 Other

All Journal Article (24 results) (of which Peer Reviewed: 24 results) Presentation (22 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Construction of two metal coordination polymers based on 1, 4-terephthalate and 1, 4-bis(1, 2, 4-triazol-1-ylmethyl) benzene2011

    • Author(s)
      G. X. Liu, X. L. Xu, Y. Y. Xu, S. Nishihara, X. M. Ren
    • Journal Title

      Russ. J. Coord. Chem

      Volume: 37(3) Pages: 202-210

    • Peer Reviewed
  • [Journal Article] A New Chiral Cu(II) Complex Consisting of Achiral Flexible Tripodal Ligand of Benzene-1, 3, 5-Triacetate Acid with Phenan throline2011

    • Author(s)
      G. X. Liu, X. C. Zha, Y. Wang, S. Nishihara, X. M. Ren
    • Journal Title

      J. Inorg. Organomet. Polymer Mater

      Volume: 21(1) Pages: 201-206

    • Peer Reviewed
  • [Journal Article] A chiral copper(II) inverse-9-metalla-crown-3 complex : Synthesis, crystal structure, ferroelectric and magnetic properties2011

    • Author(s)
      G. X. Liu, W. Guo, S. Nishihara, X. M. Ren
    • Journal Title

      Inorg. Chim. Acta

      Volume: 368(1) Pages: 165-169

    • Peer Reviewed
  • [Journal Article] Three new nickel(III) compounds based on 2-thioxo-1, 3-dithiole-4, 5-dithiolate : Syntheses, structures, magnetic properties and theoretical analyses2010

    • Author(s)
      G. X. Liu, H. Yang, W. Guo, Y. Liu, R. Y. Huang, S. Nishihara
    • Journal Title

      X. M. Ren, Polyhedron

      Volume: 29(15) Pages: 2916-2923

    • Peer Reviewed
  • [Journal Article] New Photoluminescent Coordination Polymers Constructed from Dicarboxylate and 1, 2-Bis(imidazol-1-ylmethyl) benzene2010

    • Author(s)
      G. X. Liu, Y. Y. Xu, S. Nishihara, X. M. Ren
    • Journal Title

      Russ. J. Coord. Chem.

      Volume: 36(10) Pages: 739-745

    • Peer Reviewed
  • [Journal Article] Self-assembly of 3-D 4d-4f coordination frameworks based on pyridine-3, 5-dicarboxylic acid : Syntheses, crystal structures and luminescence2010

    • Author(s)
      G. X. Liu, Y. Y. Xu, X. M. Ren, S. Nishihara, R. Y. Huang
    • Journal Title

      Inorg. Chem. Acta

      Volume: 363(14) Pages: 3727-3732

    • Peer Reviewed
  • [Journal Article] Three zinc(II) complexes constructed from aromatic dicarboxylate and 1, 4-bis((2-(pyridin-2-yl)-1H-imidazol-1-yl) methyl) benzene : Syntheses, crystal structures and luminescent properties2010

    • Author(s)
      G. X. Liu, Y. Y. Xu, Y. Wang, S. Nishihara, X. M. Ren
    • Journal Title

      Inorg. Chem. Acta

      Volume: 363(14) Pages: 3932-3938

    • Peer Reviewed
  • [Journal Article] Stationary Behavior in Effective Magnetic Moment and Magnetization of 2, 3, 6-Trifluorophenyl Nitronyl Nitroxide Radical Crystals2010

    • Author(s)
      T. Kanzawa, S. Nishihara, H. Nojiri, Y. Hosokoshi
    • Journal Title

      Bull. Chem. Soc. Jpn

      Volume: 83(12) Pages: 1447-1454

    • Peer Reviewed
  • [Journal Article] Synthesis, Crystal Structure, and Magnetic Property of a New Nickel(III) Complex Constructed from 1, 2-Benezedithiolate2010

    • Author(s)
      G. X. Liu, Y. Lui, S. Nishihara, X. M. Ren
    • Journal Title

      Synth. React. Inprg. Met. Org. Chem.

      Volume: 40(6) Pages: 416-420

    • Peer Reviewed
  • [Journal Article] A Trinuclear Cu(II) Complex from the Use of Phenyl 2-Pyridyl Ketoxime : Structure and Magnetic Behavior2010

    • Author(s)
      G. X. Liu, H. Yang, S. Nishihara, X. M. Ren
    • Journal Title

      Synth. React. Inprg. Met. Org. Chem.

      Volume: 40(6) Pages: 421-424

    • Peer Reviewed
  • [Journal Article] Hydrothermal Synthesis, Crystal Structure and Magnetic Properties of Lithium Manganese Complex of Benzene-Hexacarboxylic Acid(Mellitic Acid)2010

    • Author(s)
      G. X. Liu, H. Xu, S. Nishihara, X. M. Ren
    • Journal Title

      J. Inorg. Organomet. Polymer Mat.

      Volume: 20(3) Pages: 564-569

    • Peer Reviewed
  • [Journal Article] Synthesis, characterization, and crystal structures of two novel ion-pair complexes based on benzene-1, 2-dithiolate ligand2010

    • Author(s)
      G. X. Liu, Y. Liu, S. Nishihara, X. M. Ren
    • Journal Title

      Russ. J. Coord. Chem.

      Volume: 36(3) Pages: 226-231

    • Peer Reviewed
  • [Journal Article] Appearance of Magnetization Jumps in Magnetic Hysteresis Curves in Spinel Oxide FeV2O42010

    • Author(s)
      S. Nishihara, W. Doi, H. Ishibashi, Y. Hosokoshi, X. M. Ren
    • Journal Title

      S. Mori, J. Appl. Phy.

      Volume: 107 Pages: 09A504-1-3

    • Peer Reviewed
  • [Journal Article] Five 3D metal-organic frameworks constructed from V-shaped polycarboxylate acids and flexible imidazole-based ligands2010

    • Author(s)
      G. X. Liu, K. Zhu, H. M. Xu, S. Nishihara, R. Y. Huang, X. M. Ren
    • Journal Title

      CrystEngComm

      Volume: 12(4) Pages: 1175-1185

    • Peer Reviewed
  • [Journal Article] Syntheses and Characterizations of Three Cu(II) Complexes with 2, 2'-Bipyridine-3, 3'-dicarboxylate and N-Donor Ancillary Ligands2010

    • Author(s)
      H. Y. Xia, G. X. Liu, S. Nishihara, Y. Wang
    • Journal Title

      J. Inorg. Organometa. Polym. Mater.

      Volume: 20(1) Pages: 110-117

    • Peer Reviewed
  • [Journal Article] Synthesis, Structure and Magnetic Properties of a Novel Anion-Radical Salt Based on TCNQ2010

    • Author(s)
      Y. Liu, Y. Y. Xu, G. X. Liu, S. Nishihara, X. M. Ren
    • Journal Title

      J. Inorg. Organometa. Polym. Mater.

      Volume: 20(1) Pages: 177-181

    • Peer Reviewed
  • [Journal Article] Construction of hybrid d10 metal-organic frameworks by flexible aromatic dicarboxylate and N-donor ligands : syntheses, structures and physical properties2009

    • Author(s)
      G. X. Liu, K. Zhu, H. M. Xu, S. Nishihara, R. Y. Huang, X. M. Ren
    • Journal Title

      CrystEngComm

      Volume: 11(12) Pages: 2784-2796

    • Peer Reviewed
  • [Journal Article] Syntheses, structures and photoluminescent properties of two zinc(II) coordination polymers based on aromatic polycarboxylate and 1, 4-bis(imidazol-1-ylmethyl) benzene2009

    • Author(s)
      G. X. Liu, K. Zhu, S. Nishihara, R. Y. Huang, X. M. Ren
    • Journal Title

      Inorg. Chim. Acta

      Volume: 362(14) Pages: 5103-5108

    • Peer Reviewed
  • [Journal Article] A 3D Gd-Ag coordination polymer constructed from pyridine-3, 5-dicarboxylic acid : Synthesis, crystal structure and magnetic properties2009

    • Author(s)
      G. X. Liu, X. M. Ren, H. Xu, S. Nishihara, R. Y. Huang
    • Journal Title

      Inorg. Chem. Commun.

      Volume: 12(9) Pages: 895-897

    • Peer Reviewed
  • [Journal Article] Cobalt(II) coordination polymers assembled from polycarboxylate and benzotriazole : Syntheses, structures and physical properties2009

    • Author(s)
      K. Zhu, H. Chen, S. Nishihara, G. X. Liu, X. M. Ren
    • Journal Title

      Inorg. Chim. Acta

      Volume: 262(13) Pages: 4780-4784

    • Peer Reviewed
  • [Journal Article] Ferroelectrics2009

    • Author(s)
      T. Ozaki, S. Kitagawa, S. Nishihara, Y. Hosokoshi, M. Suzuki, Y. Noguchi, M. Miyayama, S. Mori
    • Journal Title

      Ferroelectric Properties and Nano-Scaled Domain Structures in(1-x) BiFeO3-xBaTiO3(0. 33<x<0. 50)

      Volume: 385 Pages: 155-161

    • Peer Reviewed
  • [Journal Article] Two d10 coordination polymers based on 4, 4′-(hexafluoroisopropylidene) diphthalic acid : Syntheses, structures and physical properties2009

    • Author(s)
      G. X. Liu, H. Xu, X. M. Ren, S. Nishihara, Y. Wang
    • Journal Title

      Inorg. Chem. Commun.

      Volume: 12(6) Pages: 498-501

    • Peer Reviewed
  • [Journal Article] Impurity effect of an S=1/ 2 two leg spin ladder antiferromagnet[ Ph(NH3)]([ 18] crown-6)[ Ni(dmit) 2] studied by ESR2009

    • Author(s)
      M. Fujisawa, A. Asakura, S. Okubo, H. Ohta, S. Nishihara, T. Akutagawa, T. Nakamura, Y. Hosokoshi
    • Journal Title

      J. Phys.: Conf. Ser.

      Volume: 150 Pages: 042034

    • Peer Reviewed
  • [Journal Article] Microstructures related to the ferroelectric properties in BiFeO3-BaTiO3", S. Kitagawa2008

    • Author(s)
      S. Kitagawa, Y. Horibe, K. Yoshii, M. Suzuki, Y. Noguchi, S. Nishihara, Y. Hosokoshi, S. Mori
    • Journal Title

      Trans. MRS-J.

      Volume: 33(1) Pages: 27-30

    • Peer Reviewed
  • [Presentation] スピンラダー構造を有する[ Ph(NH3)]([ 18] crown-6)[ Ni(dmit) 2]塩へのキャリアドーピングと電気物性評価2011

    • Author(s)
      國塩和久、西原禎文、芥川智行、中村貴義、秋田素子、井上克也
    • Organizer
      日本化学会第91回春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2011-03-26
  • [Presentation] 水熱法によるコバルト-アミノ酸錯体の合成、構造と物性2011

    • Author(s)
      能美耕太郎、秋田素子、西原禎文、井上克也
    • Organizer
      日本化学会第91回春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2011-03-26
  • [Presentation] メトキシ置換フェニルニトロニルニトロキシド-遷移金属錯体の合成、構造及び磁気的性質2011

    • Author(s)
      北尾大樹、秋田素子、西原禎文、井上克也
    • Organizer
      日本化学会第91回春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2011-03-26
  • [Presentation] イオンチャネル構造を有するLi2([ 18] crown-6) 3[ Ni(dmit) 2] 2(H2O) 4の構造と物性2011

    • Author(s)
      今野大輔、西原禎文、秋田素子、井上克也、芥川智行、中村貴義
    • Organizer
      日本化学会第91回春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2011-03-26
  • [Presentation] 水素結合性分子磁性体(TMA)(NITPBAH)の作製と磁気物性2011

    • Author(s)
      中野佑紀、西原禎文、秋田素子、井上克也
    • Organizer
      日本化学会第91回春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2011-03-26
  • [Presentation] 低次元分子磁性体への化学ドーピングと物性評価2011

    • Author(s)
      西原禎文
    • Organizer
      日本化学会中国四国支部山口地区化学講演会
    • Place of Presentation
      山口
    • Year and Date
      2011-01-21
  • [Presentation] 動的分子・イオン場構築による新規機能開拓2010

    • Author(s)
      西原禎文
    • Organizer
      青山学院大学物理学科コロキウム
    • Place of Presentation
      相模原
    • Year and Date
      2010-12-10
  • [Presentation] EFFECTS OF CARRIER DOPING INTO A MOLECULAR SPIN LADDER2010

    • Author(s)
      Sadafumi Nishihara, Kazuhisa Kunishio, Xiao-Ming Ren, Tomoyuki Akutagawa, Takayoshi Nakamura, Motoko Akita, and Katsuya Inoue
    • Organizer
      The 12th Intenational Comference on Moledular-Based Magnets
    • Place of Presentation
      Beijing, China
    • Year and Date
      2010-10-10
  • [Presentation] SYNTHESYS, CRYSTAL STRUVTURE AND MAGNETIC PEOPERTIES OF TRANSITION METAL COMPLEXES WITH METOXY-SUBSTITUTED PHENYLNITRONYL NITOROXISW RADICALS2010

    • Author(s)
      Motoko Akita, Shoya Sato, Hiroki Kitao, Chikako Suzuki, Sadafumi Nishihara, and Katsuya Inoue
    • Organizer
      The 12th Intenational Comference on Moledular-Based Magnets
    • Place of Presentation
      Beijing, China
    • Year and Date
      2010-10-10
  • [Presentation] 動的分子空間構築による新規誘電・磁性材料の開発2010

    • Author(s)
      西原禎文
    • Organizer
      フューチャー・フェロエレクトリック~第2回・誘電体若手夏の学校~
    • Place of Presentation
      相模原
    • Year and Date
      2010-08-08
  • [Presentation] 反強磁性ボンド交替鎖有機磁性体F5PNNの磁場中構造相転移2010

    • Author(s)
      原田太陽, 松下琢, 和田信雄, 西原禎文, 細越裕子
    • Organizer
      日本物理学会春季大会
    • Place of Presentation
      岡山
    • Year and Date
      2010-03-20
  • [Presentation] S=1/ 2スピンラダー[ Ph(NH3)]([ 18] crown-6)[ Ni(dmit) 2]のX-band ESR測定2010

    • Author(s)
      藤澤真士, 朝倉淳, 大久保晋, 太田仁, 西原禎文, 芥川智行, 中村貴義, 細越裕子
    • Organizer
      日本物理学会春季大会
    • Place of Presentation
      岡山
    • Year and Date
      2010-03-20
  • [Presentation] 有機ビラジカルBIP-V2の磁気相互作用2010

    • Author(s)
      多田晶美, 西原禎文, 細越裕子, 野尻浩之
    • Organizer
      日本物理学会春季大会
    • Place of Presentation
      岡山
    • Year and Date
      2010-03-20
  • [Presentation] Low-temperature Magnetic Properties of spinel oxide FeV2O42010

    • Author(s)
      S. Nishihara, W. Doi, H. Ishibashi, Y. Hosokoshi, S. Mori
    • Place of Presentation
      Washinton, USA
    • Year and Date
      2010-01-18
  • [Presentation] スピネル化合物(FeV2O4)における低温での磁気ヒステリシス異常2009

    • Author(s)
      西原禎文
    • Organizer
      大阪府立大学物理科学談話会
    • Place of Presentation
      大阪
    • Year and Date
      2009-09-30
  • [Presentation] 1次元反強磁性ボンド交替鎖有機磁性体F5PNNの磁場中磁気秩序2009

    • Author(s)
      原田太陽, 松下琢, 檜枝光憲, 和田信雄, 細越裕子, 西原禎文
    • Organizer
      日本物理学会春季大会
    • Place of Presentation
      神戸
    • Year and Date
      2009-09-10
  • [Presentation] フェルダジル系有機ビラジカルBIP-V2の構造と磁性2009

    • Author(s)
      多田晶美, 西原禎文, 細越裕子
    • Organizer
      日本物理学会春季大会
    • Place of Presentation
      神戸
    • Year and Date
      2009-09-10
  • [Presentation] スピネル型化合物FeV2O4の単結晶作製と磁性2009

    • Author(s)
      西原禎文, 土井渉, 石橋広記, 細越裕子, 森茂生
    • Organizer
      日本物理学会春季大会
    • Place of Presentation
      神戸
    • Year and Date
      2009-09-10
  • [Presentation] (1-x) BiFeO3-xBaTiO3における微細構造と磁気特性・誘電特性の相関2009

    • Author(s)
      尾崎友厚, 西原禎文, 細越裕子, 野口祐二, 宮山勝, 徳永将史, 吉井賢資, 森茂生
    • Organizer
      日本物理学会春季大会
    • Place of Presentation
      神戸
    • Year and Date
      2009-09-10
  • [Presentation] 反強磁性三角格子磁性体TNN系有機ラジカルの磁性2009

    • Author(s)
      細越裕子, 中治光晶, 西原禎文, 野尻浩之
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      東京
    • Year and Date
      2009-03-27
  • [Presentation] S=l/ 2分子性スピンラダー物質Ni(dmit) 2の非磁性不純物による微細構造2009

    • Author(s)
      朝倉淳, 藤澤真士, 大久保晋, 太田仁, 西原禎文, 芥川智行, 中村貴義, 細越裕子
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      東京
    • Year and Date
      2009-03-27
  • [Presentation] (1-x) BiFeO3-xBaTiO3における磁気・誘電特性とドメイン構造(4)2009

    • Author(s)
      尾崎友厚, 西原禎文, 細越裕子, 寺西俊輔, 野口祐二, 吉井賢資, 森茂生
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      東京
    • Year and Date
      2009-03-27
  • [Remarks]

    • URL

      http://home.hiroshima-u.ac.jp/snishi/index.html

  • [Patent(Industrial Property Rights)] イオン伝導性結晶およびそれを用いた固体電解質,電池用セパレータ,電池2011

    • Inventor(s)
      西原禎文、井上克也、今野大輔
    • Industrial Property Rights Holder
      広島大学
    • Industrial Property Number
      特許2011-045176
    • Filing Date
      2011-03-02

URL: 

Published: 2013-07-31   Modified: 2013-11-20  

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