Dehalogenation of Aryl halides mediated by macrocyclic metal complex catalysts.

2010 Fiscal Year Final Research Report

• Project/Area Number: 20550139
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Environmental chemistry
• Research Institution: Yokohama City University
• Principal Investigator: MOTIDUKI Katura Yokohama City University, 生命ナノシステム科学研究科, 教授 (60150562)
• Project Period (FY): 2008 – 2010
• Keywords: 環状配位子 / 金属錯体 / 脱ハロゲン化

Research Abstract

We have synthesized some new macrocyclic metal complexes, which have been applied for the studies on metal-mediated dehalogenation of arly halides. In the course of this study, we have developed a new photochemical system for debromination of aryl bromides mediated by nickel(II) complexes with macrocyclic ligands.

Research Products

• [Journal Article] Photochemical dehalogenation mediated by macrocyclic nickel(II) complexes (2011)
  • Author(s): Mochizuki K., Suzuki M.
  • Journal Title: Inorg. Chem. Commu. in press
• [Journal Article] Synthesis of {15-benzyloxy-3,7,11,17- tetraazabicyclo[11.3.1]heptadeca-1(17),13,15-triene} nickel(II) perchlorate and its analogs, and their catalytic behavior in reductive debromination of 1-bromo-4-tert-butylbenzene (2010)
  • Author(s): Mochizuki K., Sugita T., Kuroiwa S., Yamada F., Hayano K., Ohgami Y., Suzuki M., Kato S.
  • Journal Title: Inorg. Chim. Acta 363 Pages: 3151-3157
• [Journal Article] New bis(macrocyclic) dinickel(II) complexes obtained by oxidation of bis(5,7-dimethyl- 1,4,8,11-tetraazacyclotetradeca- 4,7-dien-6- yl)dinickel(II) perchlorate (2009)
  • Author(s): Mochizuki K., Sugita T., Yamada F., Mochizuki N., Hayano K., Ohgami Y.
  • Journal Title: Inorg. Chim. Acta 362(4) Pages: 1204-1208
• [Journal Article] Synthesis and structures of zinc complexes with new binucleating ligands containing alkoxide bridges, and their activities in the hydrolysis of tris(p-nitrophenyl)phosphate (2009)
  • Author(s): Mochizuki K., Ishima Y., Hayano K.
  • Journal Title: Inorg. Chim. Acta 362 Pages: 2722-2727
• [Journal Article] Migration of 1,3-diazacyclohexane sub-rings in ring-contracted macrocyclic silver(I) complexes (2009)
  • Author(s): Mochizuki K., Ohgami Y., Mochizuki A., Hayano K.
  • Journal Title: Inorg. Chem. Commun 12 Pages: 1250-1254
• [Presentation] 大環状配位子-銅錯体の合成 (2010)
  • Author(s): (横浜市大生命ナノ)大神泰伸・望月桂
  • Organizer: 第60回錯体化学討論会,2PA-055
  • Place of Presentation: 大阪大学
  • Year and Date: 20100000
• [Presentation] ビピリジン架橋部を持つ二環状配位子とその金属錯体 (2010)
  • Author(s): (横浜市大生命ナノ)内田好子・望月桂
  • Organizer: 第60回錯体化学討論会,2PA-055
  • Place of Presentation: 大阪大学
  • Year and Date: 20100000
• [Presentation] 光受容性金属錯体を持つ環状配位子ーニッケル(II)錯体の合成 (2010)
  • Author(s): (横浜市大国際総合) 望月桂・鈴木麻菜・木下愛子
  • Organizer: 第60回錯体化学討論会,2PA-054
  • Place of Presentation: 大阪大学
  • Year and Date: 20100000
• [Presentation] べンジル基が導入された環状配位子ー銅酸素錯体 (2010)
  • Author(s): (横浜市大国際総合) 望月桂・加藤翔平・進藤朋美
  • Organizer: 第60回錯体化学討論会,1pc-001
  • Place of Presentation: 大阪大学
  • Year and Date: 20100000
• [Presentation] 1,3‐ジアザシクロヘキサンを持つ大環状配位子‐銀(I)錯体 (2009)
  • Author(s): (横浜市大国際総合・北海道教育大)望月桂・大神泰伸・早野清治
  • Organizer: 第59回錯体化学討論会,1PA-002
  • Place of Presentation: 長崎大学
  • Year and Date: 20090000
• [Presentation] ビピリジン架橋部を持つ二環状配位子の合成とその銅錯体 (2009)
  • Author(s): (横浜市大生命ナノ)内田好子・望月桂
  • Organizer: 第59回錯体化学討論会,2PA-054
  • Place of Presentation: 長崎大学
  • Year and Date: 20090000
• [Presentation] 環状トリアミンを架橋した二環状配位子の合成とその銅-酸素錯体 (2008)
  • Author(s): (横浜市大院国際総合科学)今中裕佳子・古林龍作・内田好子・望月桂
  • Organizer: 第58回錯体化学討論会,2PA-021
  • Place of Presentation: 金沢大学
  • Year and Date: 20080000
• [Presentation] 環状配位子-ニッケル錯体を用いた可視光照射によるハロゲン化アリールの脱ハロゲン化 (2008)
  • Author(s): (横浜市大院国際総合科学)鈴木麻菜・望月桂
  • Organizer: 第58回錯体化学討論会,2PF-004
  • Place of Presentation: 金沢大学
  • Year and Date: 20080000
• [Presentation] ベンジル基が導入された環状配位子の合成およびそれらの銅酸素錯体 (2008)
  • Author(s): (横浜市大院国際総合科学)加藤翔平・望月桂
  • Organizer: 第58回錯体化学討論会,2PA-060
  • Place of Presentation: 金沢大学
  • Year and Date: 20080000
• [Remarks] ホームページ等