2010 Fiscal Year Final Research Report
Study on structure-inheriting solid-state dehydration reactions under hydrothermal conditions
| Project/Area Number |
20550176
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Kobe University |
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Principal Investigator |
EDA Kazuo Kobe University, 大学院・理学研究科, 助教 (00193996)
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| Research Collaborator |
大城 優
杉谷 隆充
西田 孝昌
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| Project Period (FY) |
2008 – 2010
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| Keywords | 無機合成 / 水熱合成 / 固相反応 / 構造遺伝 / ソフトケミストリー |
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| Research Abstract |
The conversion mechanism of CoMoO_4・3/4H_2O into hp-CoMoO_4 under hydrothermal conditions was revealed. The crystal structure of NiMoO_4・nH_2O was first determined, and was revealed to be isostructural with CoMoO_4・3/4H_2O. The structural changes of isostructural NiMoO_4・nH_2O and non-isostructural MMoO_4・H_2O (M=Mg, Mn) during the hydrothermal treatments were also investigated and were discussed comparing with those of CoMoO_4・3/4H_2O. In the course of the study, new hydrates CoMo_4O_<13>・2H_2O and NiMo_4O_<13>・2H_2O were also found, and their (interesting pillared layer) structures were determined.
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Research Products
(6 results)
