2010 Fiscal Year Final Research Report
Electrochemical Formation of Nanomultilayer Structures of Manganese Oxides Intercalated with Photofunctional Molecules
| Project/Area Number |
20550180
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Yamaguchi University |
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Principal Investigator |
NAKAYAMA Masaharu Yamaguchi University, 大学院・理工学研究科, 准教授 (70274181)
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| Project Period (FY) |
2008 – 2010
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| Keywords | 層状マンガン酸化物 / ポルフィリン / ルテニウムビピリジン / メチルビオロゲン / 界面活性剤 / 電析 / 光電子移動 / 反応場 |
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| Research Abstract |
We successfully electrodeposited layered manganese oxides intercalated with photofunctional molecules (porphyrin, ruthenium bipyridine comlex), electron transfer mediator (methyl viologen), and cationic surfactants with large hydrophobic moiety. Photo irradiation to the layered manganese oxide films with photofunctional molecules did not cause a significant photocurrent. On the other hand, cationic surfactants form an organic phase which functioned as a reaction field toward catalytic oxidation of hydroquinone.
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