2010 Fiscal Year Final Research Report
A study on Ce (IV)-mediated radical generation from organosilicon compounds activated by fluoride ion
| Project/Area Number |
20590003
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Chemical pharmacy
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| Research Institution | Kanazawa University |
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Principal Investigator |
UCHIYAMA Masahiko Kanazawa University, 学際科学実験センター, 准教授 (40277265)
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| Project Period (FY) |
2008 – 2010
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| Keywords | ラジカル / セリウム / 一電子酸化 / フッ素アニオン / 有機ケイ素化合物 |
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| Research Abstract |
Ce(IV)-mediated radical generation from organosilicon compounds activated by fluoride ion was studied. Although the generation of radical by this method has not been obsereved to date, we observed the C-C bond formation reactions with catalytic amount of Ce(IV) or Ce(III) in aqueous media in the course of this study.
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