2010 Fiscal Year Final Research Report
The Development of octabromed porphine immobilized silica gels as a stationary phase for HPLC
| Project/Area Number |
20590035
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Physical pharmacy
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| Research Institution | Okayama University |
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Principal Investigator |
MIFUNE Masaki Okayama University, 大学院・医歯薬学総合研究科, 准教授 (00200105)
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| Project Period (FY) |
2008 – 2010
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| Keywords | 八臭素化ポルフィリン固定化シリカゲル / 多環芳香族炭化水素 / HPLC充填剤 / 無極性移動相 / 極性移動相 |
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| Research Abstract |
It was developed octabromed metal-porphine (M-OBTC) immobilized silica gels as a stationary phase for HPLC using both polar and on-polar mobile phase. Furthermore, Zn-OBTC silica gels gave highest theoretical plate numbers. It was revealed the effect of modification of non-reacted amino and silanol groups and a stationary phase modified decanoyl and tetramethylsilane groups could separate polyaromatic-hydrocarbons in short time. It was expected practical use the column developed here.
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[Journal Article] Photometric Study on the reaction between 2,3,7,8,12,13,17,18-Octabromo-5,10,15,20-tetrakis- (4-methyl-pyridyl) porphine and various metal ions2011
Author(s)
M.Mifune, A.Iwado, M.Taniguchi, S.Kamino, S.Enomoto
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Journal Title
Yakugakuzasshi 131(8),掲載決定
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