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2010 Fiscal Year Final Research Report

Solventless synthesis of bismuth-free and lead-free low-melting glasses

Research Project

  • PDF
Project/Area Number 20613007
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Element strategy
Research InstitutionKyoto University

Principal Investigator

YOKO Toshinobu  Kyoto University, 化学研究所, 教授 (90158353)

Co-Investigator(Kenkyū-buntansha) TAKAHASHI Masahide  大阪府立大学, 大学院・工学研究科, 教授 (20288559)
TOKUDA Yomei  京都大学, 化学研究所, 准教授 (30372551)
Project Period (FY) 2008 – 2010
Keywords有機-無機ハイブリッド / 低融点 / プロトン伝導
Research Abstract

We have recently developed the low-melting organic-inorganic hybrid silicophosphate glasses, which are prepared by mixing orthophosphoric acid with organically-modified chlorosilane at low temperature (<300℃). These glasses are capable of dissolving both rare earth ions and organic molecules, suggesting that they may be good host material candidates for optical devices. Because of the low water resistance in the atmosphere, the purpose of this study is to improve the water resistance of glasses. We proposed the hydrolytic reaction mechanism of the glasses using quantum chemical calculations. Based on this result, we concluded that the hydrolysis is assisted by acid derived from phosphoric acid and/or hydrochloric acid generated during the glass formation reaction. We also developed HCl-free reaction using orthophosphoric acid and organically-modified alkoxysilane as starting reagents to prepare the water-durable low-melting glasses.
Additionally, we have also prepared an organic-inorganic hybrid phosphosilicate membrane with a lot of uniformly-dispersed phosphoric groups based on this method. Thermogravimetric and AC impedance spectroscopy have revealed that the present membrane is a potential candidate for the proton-conducting membrane.

  • Research Products

    (10 results)

All 2011 2010 2009 2008 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (7 results) Remarks (1 results)

  • [Journal Article] Structure manufacturing of proton-conducting organic-inorganic hybrid silicophosphilte membranes by solventless synthesis2011

    • Author(s)
      Tokuda Y, Oku S, Yamada T, Takahashi M, Yoko T, Kitagawa H, Ueda Y
    • Journal Title

      J.Mater.Res. 26

      Pages: 796-803

    • Peer Reviewed
  • [Journal Article] Silicophosphate/silicophosphite hybrid materials prepared by solventless ethanol condensation2009

    • Author(s)
      Tokuda Y, Tanaka Y, Takahashi M, Ihara R, Yoko T
    • Journal Title

      J.Ceram.Soc.Japan 117

      Pages: 842-846

    • Peer Reviewed
  • [Presentation] チタノリン酸塩系有機-無機ハイブリッド材料の中低温・無加湿条件下でのプロトン伝導特性2011

    • Author(s)
      徳田陽明, 西岡聡, 正井博和, 上田義勝, 高橋雅英, 古屋仲秀樹, 横尾俊信
    • Place of Presentation
      神奈川県
    • Year and Date
      2011-03-30
  • [Presentation] 有機-無機ハイブリッド低融点ホウリン酸塩系ガラスの無溶媒合成2011

    • Author(s)
      山本泰河・徳田陽明・正井博和・横尾俊信
    • Organizer
      2011年日本セラミックス協会年会
    • Place of Presentation
      静岡県
    • Year and Date
      2011-03-16
  • [Presentation] チタノリン酸塩系有機-無機ハイブリッド膜の作製とプロトン伝導性2011

    • Author(s)
      西岡聡史、徳田陽明、高橋雅英、上田義勝、横尾俊信
    • Organizer
      日本セラミックス協会第49回セラミックス基礎科学討論会
    • Place of Presentation
      岡山県
    • Year and Date
      2011-01-11
  • [Presentation] 有機-無機ハイブリッドポリシロキサンガラスの軟化特性制御に関する研究2010

    • Author(s)
      品川正志、徳田陽明、高橋雅英、横尾俊信
    • Organizer
      日本セラミックス協会2010年年会
    • Place of Presentation
      東京都
    • Year and Date
      2010-03-22
  • [Presentation] ケイリン酸塩系有機無機ハイブリッド薄膜の無溶媒合成とその応用2009

    • Author(s)
      奥聡志、徳田陽明、高橋雅英、横尾俊信
    • Organizer
      日本セラミックス協会第47回セラミックス基礎科学討論会
    • Place of Presentation
      大阪府
    • Year and Date
      2009-01-08
  • [Presentation] 無溶媒縮合法による有機修飾酸化物交互共重合体の合成と応用2008

    • Author(s)
      徳田陽明、高橋雅英、横尾俊信
    • Organizer
      第49回ガラスおよびフォトニクス材料討論会
    • Place of Presentation
      宮城県
    • Year and Date
      2008-11-27
  • [Presentation] 有機無機ハイブリッドケイリン酸塩膜の無溶媒合成およびプロトン伝導特性の評価2008

    • Author(s)
      奥聡志、徳田陽明、高橋雅英、横尾俊信
    • Organizer
      粉体粉末冶金平成20年度春期大会
    • Place of Presentation
      東京都
    • Year and Date
      2008-05-27
  • [Remarks] ウェブサイト

    • URL

      http://noncry.kuicr.kyoto-u.ac.jp/

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Published: 2012-01-26   Modified: 2016-04-21  

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