2012 Fiscal Year Final Research Report
Development of Innovative Molecular Transformations Via Cationic Rhodacycles as Active Species
| Project/Area Number |
20675002
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| Research Category |
Grant-in-Aid for Young Scientists (S)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Tokyo University of Agriculture and Technology |
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Principal Investigator |
TANAKA Ken 東京農工大学, 大学院・工学研究院, 教授 (40359683)
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| Project Period (FY) |
2008 – 2012
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| Keywords | 有機合成 / 触媒反応 / 不斉合成 / 付加環化反応 / 芳香族化合物 |
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| Research Abstract |
In this research, the method of generating various highly reactive cationic rhodacycles was examined in detail , and many novel catalyses which involve these intermediates as active species were developed. These developed catalyses were expanded to the asymmetrical catalyses that are able to construct axial, planar, helical, and multiple central chiralities, and syntheses of functional organic materials. Thus, "chemistry of cationic rhodacycles " was established.
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