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2012 Fiscal Year Final Research Report

Development of the smart deposition process of amorphous carbon films due to the control of plasma process

Research Project

  • PDF
Project/Area Number 20684027
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Plasma science
Research InstitutionNagasaki University

Principal Investigator

SHINOHARA Masanori  長崎大学, 工学研究科, 助教 (80346931)

Project Period (FY) 2008 – 2012
Keywords反応性プラズマ / プロセス診断 / プラズマ-固体表面相互作用 / プラズマプロセス制御 / アモルファス炭素膜
Research Abstract

We investigated plasma enhanced chemical vapor deposition (PECVD) mechanism of an amorphous carbon film with infrared spectroscopy in multiple internal reflection geometry (MIR-IRAS). If methane plasma is used, sp^-hydrocarbon species, such as CH_2CH_3, are main precursors, contributed to film deposition. In the deposition process the relases of hydrogen from the precursors is needed to film growth. On the other hand, sp-hydrocarbon species, such as C_2H are the main precursors if acethylene plasma used. The species can be deposited through addition reaction without the relase of hydrogen. Then, the film deposition rate is higher with acethylene plasma than with methane plasma.

  • Research Products

    (9 results)

All 2012 2011 2010 2009

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (3 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Surface modification of DLC film due to oxygen plasma exposure, observed by IR absorption spectroscopy in multipleinternal- reflection geometry2012

    • Author(s)
      M. Shinohara, Y. Takaki, Y. Takami, Y. Matuda, and H. Fujiyama
    • Journal Title

      IEEE Trans. of Plasma Science

      Volume: Vo l . 40, No. 10 Pages: 2756-2761

    • DOI

      DOI:10.1109/TPS.2012.2208766

    • Peer Reviewed
  • [Journal Article] Substrate Bias Effects on Amorphous Carbon Film Deposition Process during Acetylene Plasma, Investigated with Infrared Spectroscopy2010

    • Author(s)
      M. Shinohara, H. Kawazoe, T. Kawakami, T. Inayoshi, Y. Matuda, and H. Fujiyama, Y. Nitta, and T. Nakatani
    • Journal Title

      Trans. of MRS-Japan

      Volume: Vol. 35, No. 3 Pages: 563-566

    • Peer Reviewed
  • [Journal Article] Difference of deposition process of an amorphous carbon film due to source gases2010

    • Author(s)
      M. Shinohara, H. Kawazoe, T. Inayoshi, T. Kawakami, Y. Matsuda, H. Fujiyama, Y. Nitta, and T. Nakatani
    • Journal Title

      Thin Solid Films

      Volume: Vol. 518, No. 13 Pages: 3497-3501

    • DOI

      DOI:10.1016/j.tsf.2009.11.033

    • Peer Reviewed
  • [Journal Article] ubstrate temperature effects on amorphous carbon film growth, Investigated by infrared spectroscopy in multiple internal reflection geometry2009

    • Author(s)
      M. Shinohara, K. Cho, Y. Matsuda, T. Inayoshi, H. Kawazoe, H. Fujiyama, Y. Nitta, and T. Nakatani
    • Journal Title

      J. of Vac. Sci. and Technol. A

      Volume: Vol. 27, No. 4 Pages: 813-817

    • DOI

      DOI:10.1116/1.3077278

    • Peer Reviewed
  • [Presentation] In-situ Monitoring of Plasma-induced Reactions with Infrared Spectroscopy2011

    • Author(s)
      M. Shinohara
    • Organizer
      3rd International Workshop on Plasma Scientech for All Something
    • Place of Presentation
      北京/中国
    • Year and Date
      20111007-09
  • [Presentation] In-situ Infrared Spectroscopy of Plasma Induced Surface Reactions2011

    • Author(s)
      M. Shinohara, K. Hara, Y. Takami, Y. Takaki, A. Fukae, K. Amano, Y. Matsuda, and H. Fujiyama
    • Organizer
      The 8thAsian-European International Conference on Plasma Surface Engineering (AEPSE 2011)
    • Place of Presentation
      大連/中国
    • Year and Date
      20110920-22
  • [Presentation] Investigation of amorphous carbon film deposition process2010

    • Author(s)
      M. Shinohara
    • Organizer
      1st International Workshopon Plasma Scientech for All Something
    • Place of Presentation
      北京/中国
    • Year and Date
      20100515-16
  • [Patent(Industrial Property Rights)] ダイヤモンド様薄膜、その製造方法及び製造装置2012

    • Inventor(s)
      篠原正典,松田良信,藤山 寛,中谷達行,岡本圭司
    • Industrial Property Rights Holder
      国立大学法人 長崎大学トーヨーエイテック株式会社
    • Industrial Property Number
      特許第5092623
    • Filing Date
      2012-09-24
  • [Patent(Industrial Property Rights)] 親水性炭素質膜の製造方法及び製造装置2010

    • Inventor(s)
      中谷達行,新田祐樹,篠原正典,藤山 寛
    • Industrial Property Rights Holder
      国立大学法人 長崎大学トーヨーエイテック株式会社
    • Industrial Property Number
      特願2009-115707
    • Filing Date
      2010-05-12

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Published: 2014-08-29  

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