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2010 Fiscal Year Final Research Report

Development of a sensitive and selective mass spectrometer

Research Project

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Project/Area Number 20685007
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Analytical chemistry
Research InstitutionKyushu University

Principal Investigator

UCHIMURA Tomohiro  Kyushu University, 大学院・工学研究科, 准教授 (40346820)

Project Period (FY) 2008 – 2010
Keywords環境分析 / 環境化学 / 有害化学物質 / レーザー / 質量分析 / 多光子イオン化 / 超音速分子ジェット / 機器分析
Research Abstract

A novel sample introduction technique was developed for application to supersonic jet spectrometry. This approach leads to a substantial improvement in the duty cycle. In addition, the nozzle can be heated to high temperature and has a near-zero dead volume. Therefore, this sample introduction technique is suitable for use at the interface of the GC and MS.

  • Research Products

    (57 results)

All 2011 2010 2009 2008 Other

All Journal Article (20 results) (of which Peer Reviewed: 20 results) Presentation (34 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Gas chromatography/multiphoton ionization/time-of-flight mass spectrometry of polychlorinated biphenyls2011

    • Author(s)
      T.Matsui, T.Uchimura, T.Imasaka
    • Journal Title

      Anal.Chim.Acta 694

      Pages: 108-114

    • Peer Reviewed
  • [Journal Article] Analysis of Dioxins by Gas Chromatography/Resonance-Enhanced Multiphoton Ionization/Mass Spectrometry Using Nanosecond and Picosecond Lasers2011

    • Author(s)
      A.Li, T.Uchimura, Y.Watanabe-Ezoe, T.Imasaka
    • Journal Title

      Anal.Chem. 83

      Pages: 60-66

    • Peer Reviewed
  • [Journal Article] Selective Determination of 2,4-Xylenol by Gas Chromatography/Supersonic Jet/Resonance-Enhanced Multiphoton Ionization/Time-of-Flight Mass Spectrometry2010

    • Author(s)
      H.Tsukatani, H.Okudaira, O.Shitamichi, T.Uchimura, T.Imasaka
    • Journal Title

      Anal.Chim.Acta 682

      Pages: 72-76

    • Peer Reviewed
  • [Journal Article] Trace Analysis of Polycyclic Aromatic Hydrocarbons Using Gas Chromatography-Mass Spectrometry Based on Nanosecond Multiphoton Ionization2010

    • Author(s)
      A.Li, T.Uchimura, H.Tsukatani, T.Imasaka
    • Journal Title

      Anal.Sci. 26

      Pages: 841-846

    • Peer Reviewed
  • [Journal Article] A Pair of Concentric Capillaries As An Interface for Gas Chromatography and Supersonic Jet/Multiphoton Ionization/ Mass Spectrometry2010

    • Author(s)
      H.Okudaira, T.Uchimura, T.Imasaka
    • Journal Title

      Rev.Sci.Instrum. 81

      Pages: 084102(1-5)

    • Peer Reviewed
  • [Journal Article] Gas Chromatography/Femtosecond Multiphoton Ionization/Time-of-Flight Mass Spectrometry of Dioxins2010

    • Author(s)
      Y.Watanabe-Ezoe, X.Li, T.Imasaka, T.Uchimura, T.Imasaka
    • Journal Title

      Anal.Chem. 82

      Pages: 6519-6525

    • Peer Reviewed
  • [Journal Article] Enhancement of Molecular Ions in Mass Spectrometry Using An Ultrashort Optical Pulse in Multiphoton Ionization2010

    • Author(s)
      T.Shimizu, Y.Watanabe-Ezoe, S.Yamaguchi, H.Tsukatani, T.Imasaka, S.Zaitsu, T.Uchimura, T.Imasaka
    • Journal Title

      Anal.Chem. 82

      Pages: 3441-3444

    • Peer Reviewed
  • [Journal Article] Application of Hadamard Transform to Gas Chromatography/Nonresonant Multiphoton Ionization/Time-of-Flight Mass Spectrometry2010

    • Author(s)
      C.-C.Cheng, H.W.Chang, T.Uchimura, T.Imasaka, T.Kaneta, C.-H.Lin
    • Journal Title

      J.Sep.Sci. 33

      Pages: 626-630

    • Peer Reviewed
  • [Journal Article] Online Concentration by Analyte Adsorption/Laser Desorption for Application to Gas Chromatography/ Resonance-Enhanced Multiphoton Ionization Time-of-Flight Mass Spectrometry2010

    • Author(s)
      Y.Sakoda, T.Uchimura, T.Imasaka
    • Journal Title

      Anal.Chem. 82

      Pages: 1283-1287

    • Peer Reviewed
  • [Journal Article] Gas Chromatography/ Time-of-Flight Mass Spectrometry of Triacetone Triperoxide Based on Femtosecond Laser Ionization2009

    • Author(s)
      S.Yamaguchi, T.Uchimura, T.Imasaka, T.Imasaka
    • Journal Title

      Rapid Commun.Mass Spectrom. 23

      Pages: 3101-3106

    • Peer Reviewed
  • [Journal Article] Analysis of Highly Chlorinated Dibenzofurans Using Gas Chromatography/Multiphoton Ionization/Time-of-flight Mass Spectrometry2009

    • Author(s)
      Y.Watanabe-Ezoe, K.Ohi, T.Uchimura, T.Imasaka
    • Journal Title

      Organohalogen Compd. 71

      Pages: 271-174

    • Peer Reviewed
  • [Journal Article] Development of An Off-axis Sample Introduction System for Use in Multiphoton Ionization/Time-of-flight Mass Spectrometry2009

    • Author(s)
      T.Uchimura, S.Yamaguchi, T.Imasaka
    • Journal Title

      Chem.Lett. 38

      Pages: 744-745

    • Peer Reviewed
  • [Journal Article] Selective Ionization of 2,4-Xylenol in Mass Spectrometry Using A Tunable Laser and Supersonic Jet Technique2009

    • Author(s)
      H.Tsukatani, H.Okudaira, T.Uchimura, T.Imasaka, T.Imasaka
    • Journal Title

      Anal.Sci. 25

      Pages: 599-604

    • Peer Reviewed
  • [Journal Article] Data Processing Technique in Gas Chromatography/Time-of-Flight Mass Spectrometry2009

    • Author(s)
      T.Imasaka, N.Nakamura, Y.Sakoda, S.Yamaguchi, Y.Watanabe-Ezoe, T.Uchimura, T.Imasaka
    • Journal Title

      Analyst 134

      Pages: 712-718

    • Peer Reviewed
  • [Journal Article] 高感度・高選択的多光子イオン化質量分析法の開発2009

    • Author(s)
      内村智博
    • Journal Title

      分析化学 58

      Pages: 119-126

    • Peer Reviewed
  • [Journal Article] Near-Ultraviolet Femtosecond Laser Ionization of Dioxins in Gas Chromatography/Time-of-Flight Mass Spectrometry2009

    • Author(s)
      S.Yamaguchi, F.Kira, Y.Miyoshi, T.Uchimura, Y.Watanabe-Ezoe, S.Zaitsu, T.Imasaka, T.Imasaka
    • Journal Title

      Anal.Chim.Acta 632

      Pages: 229-233

    • Peer Reviewed
  • [Journal Article] Gas Chromatography/ Multiphoton Ionization/ Mass Spectrometry of Pentachlorodibenzofurans in Soils2008

    • Author(s)
      Y.Watanabe-Ezoe, N.Nakamura, T.Uchimura, S.Yamaguchi, T.Imasaka, T.Imasaka
    • Journal Title

      Organohalogen Compd. 70

      Pages: 2396-2399

    • Peer Reviewed
  • [Journal Article] GC-MPI-MS of Pentachlorodibenzofurans in Flue Gas Using A UV Picosecond Laser2008

    • Author(s)
      T.Itoh, T.Uchimura, T.Uchida, M.Kawano, T.Imasaka
    • Journal Title

      Chromatographia 68

      Pages: 89-94

    • Peer Reviewed
  • [Journal Article] On-Line Concentration by Analyte Adsorption and Subsequent Laser Desorption in Supersonic Jet Spectrometry2008

    • Author(s)
      T.Uchimura, Y.Sakoda, T.Imasaka
    • Journal Title

      Anal.Chem. 80

      Pages: 3798-3802

    • Peer Reviewed
  • [Journal Article] Polychlorinated Aromatic Hydrocarbons in a Soil Sample Measured Using Gas Chromatography/Multiphoton Ionization/ Time-of-flight Mass Spectrometry

    • Author(s)
      N.Nakamura, T.Uchimura, Y.Watanabe-Ezoe, T.Imasaka
    • Journal Title

      Anal.Sci. in press

    • Peer Reviewed
  • [Presentation] 爆発物"トリアセトントリペルオキシド"のガスクロマトグラフ/質量分析における複数ピークの帰属に関する理論的考察2010

    • Author(s)
      今坂智子, ら
    • Organizer
      日本分析化学会第59年会
    • Year and Date
      2010-09-15
  • [Presentation] Gas chromatography/ multiphoton ionization/time-of-flight mass spectrometry of pesticides using a femtosecond laser2010

    • Author(s)
      李阿丹, ら
    • Organizer
      日本分析化学会第59年会
    • Year and Date
      2010-09-15
  • [Presentation] レーザーを用いる環境・細胞計測2010

    • Author(s)
      内村智博
    • Organizer
      第23回九州分析化学若手の会 春の講演会
    • Year and Date
      2010-05-22
  • [Presentation] ガスクロマトグラフィー/多光子イオン化/飛行時間型質量分析法による鉱油中ポリ塩化ビフェニルの分析2010

    • Author(s)
      松井大宜, ら
    • Organizer
      第71回分析化学討論会
    • Year and Date
      2010-05-15
  • [Presentation] レーザーイオン化法による多臭素化ジフェニルエーテルのガスクロマトグラフィー-質量分析2010

    • Author(s)
      下道治, ら
    • Organizer
      日本化学会第90春季年会
    • Year and Date
      2010-03-26
  • [Presentation] 二重管式ガス導入インターフェースを用いたガスクロマトグラフィー/超音速分子ジェット/多光子イオン化質量分析装置の開発2010

    • Author(s)
      奥平裕貴, ら
    • Organizer
      日本化学会第90春季年会
    • Year and Date
      2010-03-26
  • [Presentation] Analysis of Dioxins Using Gas Chromatography/Multiphoton Ionization/Time-of-Flight Mass Spectrometry2010

    • Author(s)
      Y.Watanabe-Ezoe, et al.
    • Organizer
      Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy 2010
    • Year and Date
      2010-03-03
  • [Presentation] A Pair of Concentric Capillaries for Application to an Interface of Gas Chromatography and Supersonic Jet/Multiphoton Ionization Mass Spectrometry2009

    • Author(s)
      H.Okudaira, et al.
    • Organizer
      The International Symposium on Environmental Problems in East Asia 2009
    • Year and Date
      2009-12-08
  • [Presentation] Applications of Hadamard Transform to Gas Chromatography2009

    • Author(s)
      C.-H.Lin, et al.
    • Organizer
      The International Symposium on Environmental Problems in East Asia 2009
    • Year and Date
      2009-12-08
  • [Presentation] Ultraviolet Laser Ionization of Polybrominated Diphenyl Ethers in Mass Spectrometry2009

    • Author(s)
      O.Shitamichi, et al.
    • Organizer
      The International Symposium on Environmental Problems in East Asia 2009
    • Year and Date
      2009-12-08
  • [Presentation] Analysis of Dioxins Using Picosecond Laser Emission by Gas Chromatography/Mass Spectrometry2009

    • Author(s)
      李阿丹, ら
    • Organizer
      日本分析化学会第58年会
    • Year and Date
      2009-09-24
  • [Presentation] インパルシブイオン化質量分析法2009

    • Author(s)
      清水隆史, ら
    • Organizer
      日本分析化学会第58年会
    • Year and Date
      2009-09-24
  • [Presentation] レーザーイオン化飛行時間型質量分析法を用いた多臭素化ジフェニルエーテルの新規分析手法の開発2009

    • Author(s)
      下道治, ら
    • Organizer
      日本分析化学会第58年会
    • Year and Date
      2009-09-24
  • [Presentation] レーザーイオン化質量分析法における高繰り返しレーザー脱離試料導入法の開発2009

    • Author(s)
      中村奈未, ら
    • Organizer
      日本分析化学会第58年会
    • Year and Date
      2009-09-24
  • [Presentation] ガスクロマトグラフィー/超音速分子ジェット/多光子イオン化質量分析法における試料の冷却効果に影響を与える諸因子の検討2009

    • Author(s)
      奥平裕貴, ら
    • Organizer
      日本分析化学会第58年会
    • Year and Date
      2009-09-24
  • [Presentation] テロに利用される爆発物"トリアセトントリペルオキシド"の物性の理論予測2009

    • Author(s)
      今坂智子, ら
    • Organizer
      日本分析化学会第58年会
    • Year and Date
      2009-09-24
  • [Presentation] Analysis of Highly Chlorinated Debenzofurans Using Gas Chromatography/Multiphoton Ionization/Time-of-Flight Mass Spectrometry2009

    • Author(s)
      Y.Watanabe-Ezoe, et al.
    • Organizer
      29th International Symposium on Halogenated Persistent Organic Pollutants (Dioxin 2009)
    • Year and Date
      2009-08-25
  • [Presentation] Trace Analysis of Triacetone Triperoxide (TATP) by Means of Gas Chromatography Combined with Femtosecond Laser Ionization/Time-of-Flight Mass Spectrometry2009

    • Author(s)
      T.Imasaka, et al.
    • Organizer
      Asianalysis X
    • Year and Date
      2009-08-11
  • [Presentation] Determination of 2,4-Xylenol by Gas Chromatography/Resonannce-Enhanced Multiphoton Ionization/Time-of-Flight Mass Spectrometry Combined with Supersonic Jet Spectrometry2009

    • Author(s)
      H.Tsukatani, et al.
    • Organizer
      Asianalysis X
    • Year and Date
      2009-08-11
  • [Presentation] A Novel Sample Introduction Technique for Signal Enhancement by On-Line Concentration and Subsequent Laser Desorption in Supersonic Jet Spectrometry2009

    • Author(s)
      T.Uchimura, et al.
    • Organizer
      60th Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy
    • Year and Date
      2009-03-08
  • [Presentation] Gas Chromatography/ nanosecond Multiphoton Ionization/Mass Spectrometry of Persistant Organic Pollutantsq2009

    • Author(s)
      A.Li, et al.
    • Organizer
      60th Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy
    • Year and Date
      2009-03-08
  • [Presentation] Analysis of Dioxins Using Picosecond Laser Emission by Gas Chromatography/ Mass Spectrometry2008

    • Author(s)
      A.Li, et al.
    • Organizer
      International Symposium on Environmental Analysis 2008
    • Year and Date
      2008-11-26
  • [Presentation] Novel sample introduction technique based on on-line concentration/laser desorption in supersonic jet spectrometry2008

    • Author(s)
      Y.Sakoda, et al.
    • Organizer
      International Symposium on Environmental Analysis 2008
    • Year and Date
      2008-11-26
  • [Presentation] Gas Chromatography/Multiphoton Ionization/ Time-of-Flight Mass Spectrometry of Dioxins Using Femtosecond Laser2008

    • Author(s)
      Y.Watanabe-Ezoe, et al.
    • Organizer
      International Symposium on Environmental Analysis 2008
    • Year and Date
      2008-11-26
  • [Presentation] Selective Ionization of 2,4-Xylenol in Mass Spectrometry Based on Tunable Laser/Supersonic Jet Technique2008

    • Author(s)
      H.Tsukatani, et al.
    • Organizer
      International Symposium on Environmental Analysis 2008
    • Year and Date
      2008-11-26
  • [Presentation] Gas chromatography/multiphoton ionization/ time-of-flight mass spectroscopy of tetra and pentaCDD/Fs in soil2008

    • Author(s)
      N.Nakamura, et al.
    • Organizer
      International Symposium on Environmental Analysis 2008
    • Year and Date
      2008-11-26
  • [Presentation] Data Processing Technique in Gas Chromatography/ Multiphoton Ionization/Time-of-Flight Mass Spectrometry2008

    • Author(s)
      T.Imasaka, et al.
    • Organizer
      International Symposium on Environmental Analysis 2008
    • Year and Date
      2008-11-26
  • [Presentation] フェムト秒レーザーを用いたポンプ-プローブ法による多塩素化ジベンゾフランの励起一重項状態寿命測定2008

    • Author(s)
      山口智志, ら
    • Organizer
      日本分析化学会第57年会
    • Year and Date
      2008-09-10
  • [Presentation] ダイオキシン分析におけるレーザーイオン化質量分析法の信頼性評価及び土壌試料の測定2008

    • Author(s)
      中村奈未, ら
    • Organizer
      日本分析化学会第57年会
    • Year and Date
      2008-09-10
  • [Presentation] 多光子イオン化/質量分析における高感度化のためのレーザー脱離試料導入法の開発2008

    • Author(s)
      迫田裕司, ら
    • Organizer
      日本分析化学会第57年会
    • Year and Date
      2008-09-10
  • [Presentation] 多光子イオン化質量分析法の高性能化とその応用2008

    • Author(s)
      内村智博
    • Organizer
      日本分析化学会第57年会
    • Year and Date
      2008-09-10
  • [Presentation] Analysis of Polychlorinated Dibenzofurans Using Nanosecond Laser Emision by Gas Chromatography/Time-of-Flight Mass Spectrometry2008

    • Author(s)
      A.Li, et al.
    • Organizer
      東京コンファレンス2008
    • Year and Date
      2008-09-05
  • [Presentation] ダイオキシン類分析におけるレーザーイオン化質量分析法の信頼性評価並びに土壌試料の測定2008

    • Author(s)
      中村奈未, ら
    • Organizer
      第26回九州分析化学若手の会夏季セミナー
    • Year and Date
      2008-07-28
  • [Presentation] 超音速分子ジェット分光法によるキシレノール類の多光子イオン化スペクトルの測定2008

    • Author(s)
      塚谷裕子, ら
    • Organizer
      第69回分析化学討論会
    • Year and Date
      2008-05-16
  • [Book] A Pulsed Nozzle for Application to Gas Chromatography/ Supersonic Jet/Multiphoton Ionization- Mass Spectrometry2008

    • Author(s)
      T.Uchimura, et al.
    • Total Pages
      57-62
    • Publisher
      Persistent Organic Pollutants (POPS) Research in Asia
  • [Remarks] ホームページ等

    • URL

      http://matse.u-fukui.ac.jp/~uchimura/

  • [Patent(Industrial Property Rights)] レーザー蒸発法に基づくパルス試料導入方法2009

    • Inventor(s)
      迫田裕司, 内村智博, 今坂藤太郎
    • Industrial Property Rights Holder
      今坂藤太郎
    • Industrial Property Number
      特許,特許公開2009-69088
    • Acquisition Date
      2009-04-02

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Published: 2012-02-13   Modified: 2016-04-21  

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