2010 Fiscal Year Final Research Report
Solubility and diffusion coefficient in polymer of disperse dyes in supercritical carbon dioxide
| Project/Area Number |
20686052
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Properties in chemical engineering process/Transfer operation/Unit operation
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| Research Institution | Kanazawa University |
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Principal Investigator |
HIGASHI Hidenori Kanazawa University, 自然システム学系, 助教 (40294889)
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| Project Period (FY) |
2008 – 2010
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| Keywords | 理論物性 / 実験物性 / 二酸化炭素 / 溶解度 / 拡散係数 / 分子シミュレーション |
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| Research Abstract |
Solubilities of disperse dyes in supercritical carbon dioxide and diffusion coefficients of disperse dyes to polymer in supercritical carbon dioxide were measured and correlated by thermodynamic models. Molecular simulation for diffusion coefficients in supercritical fluids were carried out. The temperature and pressure dependences of solubility were clarified and the activation energy of diffusion to polymer in supercritical carbon dioxide was estimated. The method for mutual diffusivity by non-equilibrium molecular dynamics was proposed.
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Research Products
(9 results)
