• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2009 Fiscal Year Final Research Report

Spectroscopic study on multichannel chemical reaction in the gas phase : Novel reaction theory beyond the transition state theory

Research Project

  • PDF
Project/Area Number 20750014
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Physical chemistry
Research InstitutionKyushu University

Principal Investigator

SAKOTA Kenji  Kyushu University, 大学院・理学研究院, 助教 (80346767)

Project Period (FY) 2008 – 2009
Keywordsクラスター / 気相分光 / 水素結合 / レーザー / 振動分光
Research Abstract

We investigated the high-energy/multichannel chemical reaction in which the system has much energy as compared with the transition state. The internal energy dependence of the water migration observed in acetanilide-water 1:1 cluster was investigated. Based on the experimental results, it was revealed that the water migration occurring in the higher internal energy region is essentially different from that occurring in the lower internal energy region.

  • Research Products

    (10 results)

All 2010 2009 2008 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (3 results) Remarks (1 results)

  • [Journal Article] Spectroscopic st udy on the structural isomers of 7-azaindole( ethanol)n (n=1-3) and multiple-proton transfe r reactions in the gas phase2009

    • Author(s)
      Kenji Sakota, Noriyuiki Komure, Wataru I shikawa, Hiroshi Sekiya
    • Journal Title

      J. Chem. Phys. 130

      Pages: 224307-1-7

    • Peer Reviewed
  • [Journal Article] Formation of a dual hydrogen bond in the N-H…C=O moiety inthe indole-(N-methylacetamide)1cluster revealed by IR-dip spectroscopy with natural bond orbital analysis2009

    • Author(s)
      Kenji Sakota, Yuiga Shimazaki, Hiroshi Sekiya
    • Journal Title

      130

      Pages: 231105

    • Peer Reviewed
  • [Journal Article] Charge Transfer Interaction of Intermolecular Hydrogen Bonds in 7-Azaindole(MeOH)n (n=1, 2) with IR-Dip Spectroscopy and Natural Bond Orbital Analysis2009

    • Author(s)
      Yutaka Kageura, Kenji Sakota, Hiroshi Sekiya
    • Journal Title

      J. Phys. Chem. A. 113

      Pages: 6880-6885

    • Peer Reviewed
  • [Journal Article] Probe of the NH Bond Strength in 1La and 1Lb Stat es of 7-azaindole with IR-Dip Spectroscopy2008

    • Author(s)
      Kenji Sakota, Hiroshi Sekiya
    • Journal Title

      J. Phys. Chem. A. 113

      Pages: 2663-2665

    • Peer Reviewed
  • [Journal Article] Excited-state double-proton transfer in a model DNA base pair:Resolution for stepwise and concerted mechanism controversy in the 7-azaindole dimer revealed by frequency- and time-resolved spectroscopy2008

    • Author(s)
      Hiroshi Sekiya, Kenji Sakota
    • Journal Title

      J. Photochem. Photobiol. C-Review 9

      Pages: 81-91

    • Peer Reviewed
  • [Journal Article] Cooperativity of hydrogen-bonded networks in 7-azaindole(CH3OH)n (n=2, 3) clusters evidenced by IR-UV ion-dip spectroscopy and natural bond orbital analysis2008

    • Author(s)
      Kenji Sakota, Yutaka Kageura, Hiroshi Sekiya
    • Journal Title

      J. Chem. Phys. 129

      Pages: 054303

    • Peer Reviewed
  • [Presentation] Multiple-proton transfer reactions on the hydrogen-bonded 7-azaindole clusters probed by spectroscopy2010

    • Author(s)
      迫田憲治
    • Organizer
      6th Asian conference on ultrafast phenomena
    • Place of Presentation
      National Taiwan University (台湾)
    • Year and Date
      2010-01-11
  • [Presentation] Excited-state multiple-proton transfer on solvated 7-azaidole clusters in the gas phase2009

    • Author(s)
      迫田憲治
    • Organizer
      6th Korea-Japan symposium on frontier photoscience
    • Place of Presentation
      Korea University (韓国)
    • Year and Date
      2009-10-31
  • [Presentation] アセトアニリド水和クラスターにおけるイオン化誘起水分子転移反応に関する研究2009

    • Author(s)
      迫田憲治, 島崎結佳, 原田諭, 関谷博
    • Organizer
      分子科学討論会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2009-09-22
  • [Remarks]

    • URL

      http://www.scc.kyushu-u.ac.jp/Kouzou/str3j.html

URL: 

Published: 2011-06-18   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi