2009 Fiscal Year Final Research Report
Construction and dynamic structural control of hydrindacene-based macrocycles with dimensionally ordered array of functionalities
| Project/Area Number |
20750024
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
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| Research Institution | Hokkaido University |
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Principal Investigator |
KAWAI Hidetoshi Hokkaido University, 大学院・理学研究院, 助教 (50322798)
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| Project Period (FY) |
2008 – 2009
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| Keywords | 構造有機化学 / 化学合成 / マクロサイクル / 動的挙動 / X線構造 / 分子認識 / ナノチューブ |
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| Research Abstract |
Macrocycles having preorganized, defined cavities and structures of molecular dimensions have attracted great interest due to their novel properties and potential applications. We successfully constructed novel belt-shaped macrocycles with direction-persistent peripheral functionalities in both horizontal and vertical directions to the macrocyclic backbone by using hydrindacene derivatives.
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[Journal Article] Multi-input-multi-output molecular response system based on dynamic redox behavior of 3, 3, 4, 4-tetraaryldihydro[5]helicene derivatives: Reversible formation/ destruction of chiral fluorophore and modulation of chiroptical properties by solvent polarity2009
Author(s)
T.Suzuki, Y.Ishigaki, T.Iwai, H.Kawai, K.Fujiwara, H.Ikeda, Y.Kano, K.Mizuno
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Journal Title
Chem.Eur.J. vol.15,No.37
Pages: 9434-9441
Peer Reviewed
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[Journal Article] Negligible diradical character for the ultralong C-C bond in 1, 1, 2, 2- tetraarylpyracene derivatives2009
Author(s)
T.Takeda, H.Kawai, R.Herges, E.Mucke, Y.Sawai, K.Murakoshi, K.Fujiwara, T.Suzuki
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Journal Title
Tetrahedron Lett. vol.50,No.26
Pages: 3693-3697
Peer Reviewed
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