2010 Fiscal Year Final Research Report
Development of novel C-C bond formation based on activation of multiple bonds using cationic species
| Project/Area Number |
20750026
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
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| Research Institution | Chiba University |
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Principal Investigator |
MATSUMOTO Shoji Chiba University, 大学院・工学研究科, 准教授 (50302534)
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| Project Period (FY) |
2008 – 2010
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| Keywords | 合成化学 / カチオン / 多重結合 / 環化反応 / 光反応 / ヨウ素 / 環境調和 |
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| Research Abstract |
I achieved the development of new types of reaction including carbon-carbon bond and carbon-sulfur bond formations based on the activation of multiple bonds using cationic species derived from molecular iodine or hydrogen iodide. The intra- and intermolecular reactions gave the corresponding cyclic compounds. In the case of the intramolecular reactions, I found that a structure as well as a substituent of the reactant are important to make the cyclization reaction. I also obtained the luminescent materials when the reaction of intermolecular carbon-carbon bond formation proceeded. It is suggested that these reactions can be applied to the formation of useful functional materials.
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