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2009 Fiscal Year Final Research Report

Structural Control and Functionalization of Giant Porphyrin Arrays

Research Project

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Project/Area Number 20750031
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Organic chemistry
Research InstitutionKyoto University

Principal Investigator

ARATANI Naoki  Kyoto University, 大学院・理学研究科, 助教 (60372562)

Project Period (FY) 2008 – 2009
Keywords構造有機化学 / 物理有機化学 / ポルフィリン / 励起エネルギー移動 / 機能性有機分子
Research Abstract

As an effective synthetic protocol, Pd-catalyzed Suzuki-Miyaura reaction between arylbromide and boryl-porphyrin was explored, which has been used for the construction of various functional oligomeric porphyrinoids. The application of such methodologies has proven to be very powerful to create new types of porphyrin arrays, which have their own intriguing structures and properties. On the basis of this strategy, we have prepared bithiophene-porphyrin hybrid nanorings, 2,6-pyridylene-bridged β-to-β porphyrin nanorings, and a series of directly meso-β doubly linked porphyrin rings.

  • Research Products

    (30 results)

All 2010 2009 2008 Other

All Journal Article (18 results) (of which Peer Reviewed: 18 results) Presentation (10 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Porphyrin " LEGO Block" Strategy To Construct Directly meso-βDoubly Linked Porphyrin Rings2010

    • Author(s)
      Jianxin Song, Naoki Aratani, Pyosang Kim, Dongho Kim, Hiroshi Shinokubo, Atsuhiro Osuka
    • Journal Title

      Angew. Chem. Int. Ed. 49(印刷中)

    • Peer Reviewed
  • [Journal Article] Bithiophene - Porphyrin Hybrid Nanorings2010

    • Author(s)
      Kenta Osawa, Jianxin Song, Ko Furukawa, Hiroshi Shinokubo, Naoki Aratani, Atsuhiro Osuka
    • Journal Title

      Chem. Asian J. 5

      Pages: 764-767

    • Peer Reviewed
  • [Journal Article] Strategic Synthesis of 2, 6-Pyridylene-Bridged β-to-βPorphyrin Nanorings through Cross-Coupling2010

    • Author(s)
      Jianxin Song, Pyosang Kim, Naoki Aratani, Dongho Kim, Hiroshi Shinokubo, Atsuhiro Osuka
    • Journal Title

      Chem. Eur. J. 16

      Pages: 3009-3012

    • Peer Reviewed
  • [Journal Article]2010

    • Author(s)
      Harapriya Rath, Sumito Tokuji, Naoki Aratani, Ko Furukawa, Jong Min Lim, Dongho Kim, Hiroshi Shinokubo, Atsuhiro Osuka
    • Journal Title

      Angew. Chem. Int. Ed. 49

      Pages: 1489-1491

    • Peer Reviewed
  • [Journal Article] Wasielewski2010

    • Author(s)
      Thea M. Wilson, Takaaki Hori, Min-Chul Yoon, Naoki Aratani, Atsuhiro Osuka, Dongho Kim, Michael R.
    • Journal Title

      J. Am. Chem. Soc. 132

      Pages: 1383-1388

    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Dimerization of meso- Bromoporphyrins: Highly Regioselective meso -βCoupling through Unprecedented Remote C-H Bond Cleavage2009

    • Author(s)
      Sumito Tokuji, Taiga Yurino, Naoki Aratani, Hiroshi Shinokubo, Atsuhiro Osuka
    • Journal Title

      Chem. Eur. J. 15

      Pages: 12208-12211

    • Peer Reviewed
  • [Journal Article] Structural Dependence on Excitation Energy Migration Processes in Artificial Light Harvesting Cyclic Zinc(II) Porphyrin Arrays2009

    • Author(s)
      Min-Chul Yoon, Sung Cho, Pyosang Kim, Takaaki Hori, Naoki Aratani, Atsuhiro Osuka, Dongho Kim
    • Journal Title

      J. Phys. Chem. B 113

      Pages: 15074-15082

    • Peer Reviewed
  • [Journal Article] Selective Formation of a Single Atropisomer of meso - meso-Linked ZnII Diporphyrin through Supramolecular Self-Assembly2009

    • Author(s)
      Chihiro Maeda, Taisuke Kamada, Naoki Aratani, Takahiro Sasamori, Norihiro Tokitoh, Atsuhiro Osuka
    • Journal Title

      Chem. Eur. J. 15

      Pages: 9681-9684

    • Peer Reviewed
  • [Journal Article] Synthesis of Extremelyπ-Extended Porphyrin Tapes from Hybrid meso-meso Linked Porphyrin Arrays: An Approach Towards the Conjugation Length2009

    • Author(s)
      Toshiaki Ikeda, Naoki Aratani, Atsuhiro Osuka
    • Journal Title

      Chem. Asian J. 4

      Pages: 1248-1256

    • Peer Reviewed
  • [Journal Article] Structural Factors Determining Photophysical Properties of Directly Linked Zinc(II) Porphyrin Dimers: Linking Position, Dihedral Angle, and Linkage Length2009

    • Author(s)
      Sung Cho, Min-Chul Yoon, Jong Min Lim, Pyosang Kim, Naoki Aratani, Yasuyuki Nakamura, Toshiaki Ikeda, Atsuhiro Osuka, Dongho Kim
    • Journal Title

      J. Phys. Chem. B 113

      Pages: 10619-10627

    • Peer Reviewed
  • [Journal Article] Meso-βDoubly Linked Zn(II) Porphyrin Trimers: Distinct anti-versus-syn Effects on Their Photophysical Properties2009

    • Author(s)
      Toshiaki Ikeda, Naoki Aratani, Shanmugam Easwaramoorthi, Dongho Kim, Atsuhiro Osuka
    • Journal Title

      Org. Lett. 11

      Pages: 3080-3083

    • Peer Reviewed
  • [Journal Article] Post- Modification of meso - meso-Linked Porphyrin Arrays by Iridium and Rhodium Catalyses for Tuning of Energy Gap2009

    • Author(s)
      Jinping Chen, Naoki Aratani, Hiroshi Shinokubo, Atsuhiro Osuka
    • Journal Title

      Chem. Asian J. 4

      Pages: 1126-1133

    • Peer Reviewed
  • [Journal Article] Bis-rhodium hexaphyrins: metalation of [28]hexaphyrin and a smooth Huckel aromatic - antiaromatic interconversion2009

    • Author(s)
      Harapriya Rath, Naoki Aratani, Jong Min Lim, Jae Seok Lee, Dongho Kim, Hiroshi Shinokubo, Atsuhiro Osuka
    • Journal Title

      Chem. Commun.

      Pages: 3762-3764

    • Peer Reviewed
  • [Journal Article] Determination of the Superradiance Coherence Length of Directly Linked Linear Porphyrin Arrays at the Single-Molecule Level2009

    • Author(s)
      Jaesung Yang, Hyejin Yoo, Naoki Aratani, Atsuhiro Osuka, Dongho Kim
    • Journal Title

      Angew. Chem. Int. Ed. 48

      Pages: 4323-4327

    • Peer Reviewed
  • [Journal Article] Facile synthesis and photophysical properties of 1, 2- phenylene-bridged porphyrin dimers2009

    • Author(s)
      Kenta Osawa, Naoki Aratani, Atsuhiro Osuka
    • Journal Title

      Tetrahedron Lett. 50

      Pages: 3333-3337

    • Peer Reviewed
  • [Journal Article] Zwitterionic Corroles: Regioselective Nucleophilic Pyridination of a Doubly Linked Biscorrole2009

    • Author(s)
      Satoru Hiroto, Naoki Aratani, Naoki Shibata, Yoshiki Higuchi, Takahiro Sasamori, Norihiro Tokitoh, Hiroshi Shinokubo, Atsuhiro Osuka
    • Journal Title

      Angew. Chem. Int. Ed. 48

      Pages: 2388-2390

    • Peer Reviewed
  • [Journal Article] Fluorescence Dynamics of Directly Meso-Meso Linked Porphyrin Rings Probed by Single Molecule Spectroscopy2009

    • Author(s)
      Hyejin Yoo, Jaesung Yang, Yasuyuki Nakamura, Naoki Aratani, Atsuhiro Osuka, Dongho Kim
    • Journal Title

      J. Am. Chem. Soc. 131

      Pages: 1488-1494

    • Peer Reviewed
  • [Journal Article] Synthesis and characterizations of free base and Cu(II) complex of a porphyrin sheet2008

    • Author(s)
      Yasuyuki Nakamura, Naoki Aratani, Ko Furukawa, Atsuhiro Osuka
    • Journal Title

      Tetrahedron 64

      Pages: 11433-11439

    • Peer Reviewed
  • [Presentation] 構造の明確な巨大ポルフィリンアレイの構築2010

    • Author(s)
      荒谷直樹
    • Organizer
      (若い世代の特別講演)日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪)
    • Year and Date
      20100326-20100329
  • [Presentation] Development of large photofunctionalπ-conjugated systems2010

    • Author(s)
      Naoki Aratani
    • Organizer
      International Symposium on Chemical Conversion of Light Energy
    • Place of Presentation
      近畿大学(大阪)
    • Year and Date
      2010-03-29
  • [Presentation] Electronically Interactive Giant Porphyrin Arrays2010

    • Author(s)
      Naoki Aratani
    • Organizer
      Kyushu University Global COE Program The 10th International Workshop "Science for Future Molecular Systems "招待講演
    • Place of Presentation
      Kyushu University(福岡)
    • Year and Date
      2010-02-19
  • [Presentation] Electronically Interactive Giant Porphyrin Arrays2009

    • Author(s)
      Naoki Aratani
    • Organizer
      JSPS Asian CORE Program China - Japan Joint Symposium招待講演
    • Place of Presentation
      Sapporo
    • Year and Date
      20090802-20090805
  • [Presentation] Synthesis of Large Oligoacenequinones2009

    • Author(s)
      Naoki Aratani, Ryotaro Aso, Atsuhiro Osuka
    • Organizer
      13th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Luxembourg
    • Year and Date
      20090719-20090724
  • [Presentation] ノナセンキノンの合成・物性とその反応性(1)2009

    • Author(s)
      麻生亮太郎・荒谷直樹・大須賀篤弘
    • Organizer
      第89日本化学会春季年会
    • Place of Presentation
      日大理工学部船橋キャンパス
    • Year and Date
      20090327-20090330
  • [Presentation] ノナセンキノンの合成・物性とその反応性(2)2009

    • Author(s)
      荒谷直樹・麻生亮太郎・大須賀篤弘
    • Organizer
      第89日本化学会春季年会
    • Place of Presentation
      日大理工学部船橋キャンパス
    • Year and Date
      20090327-20090330
  • [Presentation] 巨大分子の有機合成2009

    • Author(s)
      荒谷直樹
    • Organizer
      第五回有機元素化学シンポジウム(招待講演)
    • Place of Presentation
      京都大学大学宇治キャンパス木質ホール
    • Year and Date
      20090219-20090220
  • [Presentation] 構造の明確な巨大分子を創る2008

    • Author(s)
      荒谷直樹
    • Organizer
      グローバルCOE有機若手ワークショップ(招待講演)
    • Place of Presentation
      京都大学大学院理学研究科2号館120号室
    • Year and Date
      20080911-20080912
  • [Presentation] Synthesis of phenylene-linked porphyrin arrays by Pd-catalyzed coupling reaction2008

    • Author(s)
      Naoki Aratani, Atsuhiro Osuka
    • Organizer
      International Symposium on Porphyrins and Phthalocyanines
    • Place of Presentation
      Moscow, Russia
    • Year and Date
      20080706-20080711
  • [Book] 配位空間の化学・第IV編第3章・自己識別会合(北川進監修)2009

    • Author(s)
      荒谷直樹・大須賀篤弘
    • Total Pages
      320-327
    • Publisher
      CMC出版
  • [Remarks]

    • URL

      http://kuchem.kyoto-u.ac.jp/shuyu/j/aratani.html

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Published: 2011-06-18   Modified: 2016-04-21  

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