2009 Fiscal Year Final Research Report
Study of Dinuclear Complexes Inducing Unique Bond
| Project/Area Number |
20750048
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Nagasaki University |
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Principal Investigator |
ARIKAWA Yasuhiro Nagasaki University, 生産科学研究科, 助教 (30346936)
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| Project Period (FY) |
2008 – 2009
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| Keywords | 一酸化窒素 / ニトロシル / N-Nカップリング / NO還元サイクル / 二核錯体 / ピラゾリルボラト / ルテニウム |
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| Research Abstract |
We have found unique N-N coupling of two NO ligands on dinuclear ruthenium complexes. Use of the N-N coupling complexes led to release of N_2O along with the formation of oxo-bridged dinuclear complexes. Their double protonation, followed by treatment with NO, afforded dinitrosyl complexes, completing NO reduction cycle. This indicates reproduction of the function of metalloenzyme, bacterial nitric oxide reductase.
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