Functional Supramolecular/Macromolecular Hybrid Materials

2010 Fiscal Year Final Research Report

• Project/Area Number: 20750097
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Polymer chemistry
• Research Institution: National Institute for Materials Science
• Principal Investigator: SUGIYASU Kazunori National Institute for Materials Science, ナノ有機センター, 主任研究員 (80469759)
• Project Period (FY): 2008 – 2010
• Keywords: 機能性高分子 / 超分子集合体

Research Abstract

We have designed and fabricated "supramolecular/macromolecular hybrid materials". We have succeeded in creating, for examples, (1) optoeletronic functional films and (2) mechano-responsive light-harvesting systems by means of the hybridization between supramolecular functions and polymeric networks.

Research Products

• [Journal Article] Synthesis of a Doubly Strapped Light-Harvesting Porphyrin Bearing Energy Donor Molecules Hanging on to the Straps : An Attempt toward Macroscopic Control over Molecular Conformation that Affects the Efficiency of Fluorescence Resonance Energy Transfer (2011)
  • Author(s): S.Ogi, K.Sugiyasu^*, M.Takeuchi^*
  • Journal Title: Bull.Chem.Soc.Jpn. 84 Pages: 40
  • Peer Reviewed
• [Journal Article] A Self-Threading Polythiophene : Defect-Free Insulated Molecular Wires Endowed with Long Effective Conjugation Length (2010)
  • Author(s): K.Sugiyasu^*, Y.Honsho, R.M.Harrison, A.Sato, T.Yasuda, S.Seki, M.Takeuchi^*
  • Journal Title: J.Am.Chem.Soc. 132 Pages: 14754
  • Peer Reviewed
• [Journal Article] Conducting Polymer Networks Cross-Linked by "Isolated" Functional Dyes : Design, Synthesis, and Electrochemical Polymerization of Doubly Strapped Light-Harvesting Porphyrin/Oligothiophene Monomers (2009)
  • Author(s): K.Sugiyasu^*, M.Takeuchi^*
  • Journal Title: Chem.Eur.J. 15 Pages: 6350
  • Peer Reviewed
• [Presentation] Self-Threading Polythiophene : Defect-Free Insulated Molecular Wires Endowed with Long Effective Conjugation Length (2010)
  • Author(s): K.Sugiyasu^*, M.Takeuchi^*
  • Organizer: Pacifichem, Hawaii
  • Place of Presentation: 高島
  • Year and Date: 2010-12-19
• [Presentation] 自己貫通ポリチオフェン(口頭) (2010)
  • Author(s): 杉安和憲^*, 大内祐輝, 本庄義人, 関修平, 竹内正之^*
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学
  • Year and Date: 2010-09-15
• [Presentation] Space Design around Conducting Polymers (口頭) (2010)
  • Author(s): K.Sugiyasu^*, Y.Ouchi, M.Takeuchi^*
  • Organizer: International Conference on Science and Technology of Synthetic Metals
  • Place of Presentation: Kyoto
  • Year and Date: 2010-07-05
• [Presentation] 自己貫通ポリチオフェン(口頭) (2010)
  • Author(s): 杉安和憲^*, 竹内正之^*
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学
  • Year and Date: 2010-03-26
• [Presentation] Isolated Functional Molecules in Conjugated Polymers(口頭) (2009)
  • Author(s): K.Sugiyasu^*, M.Takeuchi^*
  • Organizer: 1st Federation of Asian Polymer Societies Polymer Congress
  • Place of Presentation: Nagoya
  • Year and Date: 2009-10-22
• [Presentation] Polythiophene Networks Cross-Linked by "Isolated" Functional Dyes: Design, Synthesis, and Electrochemical Polymerization of Doubly Strapped Light-Harvesting Porphyrin/Oligothiophene Monomers (2009)
  • Author(s): K.Sugiyasu^*, M.Takeuchi^*
  • Organizer: 13^<th> International IUPAC Conference on Polymers and Organic Chemistry, Montreal
  • Place of Presentation: ポスター
  • Year and Date: 2009-07-05
• [Remarks] ホームページ等
• [Remarks] 有機材料グループ
  • URL: http://www.nims.go.jp/macromol/
• [Remarks] Bull.Chem.Soc.Jpn., 2011, 84, 40.へのオープンアクセス
  • URL: http://www.jstage.jst.go.jp/article/bcsj/84/1/40/_pdf/-char/ja/
• [Patent(Industrial Property Rights)] 導電性モノマーとそのポリマー又はオリゴマーおよび (2009)
  • Inventor(s): 杉安和憲、竹内正之、大内祐輝、ライアンエムハリソン
  • Industrial Property Rights Holder: 独立行政法人物質・材料研究機構
  • Industrial Property Number: 特願2009-178991
  • Filing Date: 2009-07-31