2010 Fiscal Year Final Research Report
Development of Environmentally-Friendly Asymmetric Reaction System Based on Solvent -Free Organic Reactions
| Project/Area Number |
20750122
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Environmental chemistry
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| Research Institution | Kyushu University |
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Principal Investigator |
FURUNO Hiroshi Kyushu University, 先導物質化学研究所, 助教 (90335993)
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| Project Period (FY) |
2008 – 2010
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| Keywords | 合成化学 / 不斉合成 / 環境調和型反応 / 触媒設計 / 無溶媒反応 / 回収・再利用可能触媒 |
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| Research Abstract |
In order to develop environmentally-friendly asymmetric reaction systems, novel polymeric rare earth metal complexes were prepared from rare earth metal ions and ligands with multi-way spacers in a self-organized manner. These complexes effectively worked as a Lewis acid catalyst under solvent-free conditions, and could be recovered after the reaction and reused to the next one. Also, organic polymers could be used as a substitute reaction media for an organic solvent.
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