2009 Fiscal Year Final Research Report
Development of Efficient Synthetic Method of Oligoenes via Selective Linear Oligomerization of Alkynes
| Project/Area Number |
20750160
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic industrial materials
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| Research Institution | Hokkaido University |
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Principal Investigator |
KANNO Ken-Ichiro Hokkaido University, 触媒化学研究センター, 助教 (20360951)
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| Project Period (FY) |
2008 – 2009
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| Keywords | 機能性有機材料 |
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| Research Abstract |
Highly selective synthesis of tri-and tetraene derivatives as single products was achieved via linear oligomerization of different alkynes via a zirconocene and copper-mediated reaction. And, interesting 7-membered-ring formation of a triene derivatives obtained from the above-mentioned reaction was found. These reactions were applicable for variously substituted substrates.
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