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2009 Fiscal Year Final Research Report

Preparation of honeycomb structure via unidirectional freezing of polymer solution

Research Project

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Project/Area Number 20760513
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionKyoto University

Principal Investigator

TAKI Kefntaro  Kyoto University, 大学院・工学研究科, 助教 (70402964)

Project Period (FY) 2008 – 2009
Keywords凍結 / 乾燥 / 高分子 / 相分離 / 結晶
Research Abstract

We developed a facile preparation method of porous polymer monolith by means of unidirectionally freezing of polymer solution and subsequent sublimation of the frozen-solvent in freeze-drying process. The obtained porous structure of the monolith had 1 to 100 micrometer pores aligning along the freezing direction regularly. We demonstrated the potential of our method applying to poly(L-lactide)/1,4-dioxane, poly(L-lactide)/water/1,4-dioxane, poly(L-lactide)/poly(ethylene glycol), polyurethane diacrylate UV curable resin solutions.

  • Research Products

    (5 results)

All 2009

All Journal Article (2 results) Presentation (2 results) Book (1 results)

  • [Journal Article] Preparation of Porous Poly(l-lactic acid) Honeycomb Monolith Structure by Phase2009

    • Author(s)
      Kim JW, K. Taki, S. Nagamine, M. Ohshima, Langmuir
    • Journal Title

      Separation and Unidirectional Freezing 25(9)

      Pages: 5304-5312

  • [Journal Article] Preparation of a polymeric membrane with a fine porous structure by dry casting2009

    • Author(s)
      Kim, JK, K. Taki, S. Nagamine, M. Ohshima
    • Journal Title

      J Appl. Polym. Sci. 111(5)

      Pages: 2518-2526

  • [Presentation] UV硬化性溶液の凍結と硬化による多孔膜の形成と構造制御2009

    • Author(s)
      岡地理佳、金鎮雄、瀧健太郎、長嶺信輔、大嶋正裕
    • Organizer
      化学工学会第41回秋季大会(2009)
    • Place of Presentation
      広島大学東広島キャンパス
    • Year and Date
      20090916-20090918
  • [Presentation] Preparation of well-controlled macroporous polymeric foam from UV curable monomer/dioxane solution via uni-directionally freezing with UV irradiation2009

    • Author(s)
      Rika Okaji, Kentaro Taki, Shinsuke Nagamine, Masahiro Ohshima
    • Organizer
      Biofoams 2009
    • Place of Presentation
      Niagaral Falls, Canada.
    • Year and Date
      2009-10-28
  • [Book] 最近の化学工学60先端産業における最新塗布技術の応用事例2009

    • Author(s)
      瀧健太郎, 他
    • Total Pages
      115-122
    • Publisher
      化学工業社

URL: 

Published: 2011-06-18   Modified: 2014-08-15  

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