2009 Fiscal Year Final Research Report
Oxidations of saturated C-H bonds and their applications for multiple functionalizations of phenols using active organoiodine reagents
| Project/Area Number |
20790009
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Chemical pharmacy
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| Research Institution | Ritsumeikan University |
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Principal Investigator |
DOHI Toshifumi Ritsumeikan University, 薬学部, 助教 (50423116)
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| Project Period (FY) |
2008 – 2009
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| Keywords | 有機ヨウ素 / 酸化 / 環境対応 / C-H官能基化 / 機能性化合物 / 複素環化合物 / リサイクル / 有機触媒 |
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| Research Abstract |
We have clarified the reactivities of highly reactive reagents, which are prepared from hypervalent iodine reagents and inorganic bromides. Their unique oxidation abilities are applied in organic synthesis to prove the utility of the new reagents. In combination of these results with our unique technologies for oxidative conversions of aromatic rings, asymmetric synthesis, recycling and catalytic utilization of the reagents, the methods became to be more practical processes for synthesizing highly functionalized phenolic compounds.
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