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2009 Fiscal Year Final Research Report

Production of transient molecules and their detections by using highly sensitive spectroscopic methods and a new type slit nozzle

Research Project

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Project/Area Number 20850006
Research Category

Grant-in-Aid for Young Scientists (Start-up)

Allocation TypeSingle-year Grants
Research Field Physical chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

SUMA Kohsuke  The University of Tokyo, 大学院・工学系研究科, 助教 (10506728)

Project Period (FY) 2008 – 2009
Keywords高感度分光 / 放電後混合型ノズル / ラジカル / ラジカル錯体
Research Abstract

The Laser Induced Fluorescence (LIF) and Cavity Ringdown (CRD) spectrometers combined with the pulsed discharged nozzle have been constructed. This apparatus were optimized by monitoring the intensities of the absorption spectra of the CN radical. It was confirmed that these spectrometer have enough sensitivity to observe spectra of radicals. A new type slit discharge nozzle was constructed. Now, we are trying to observe electronic transition spectra of rare gas-molecule/radical-molecule complexes, such as H_2O-OH or Ar-CN by using the CRD spectrometer and new type slit nozzle.

  • Research Products

    (3 results)

All 2010 2009 2008

All Journal Article (2 results) Presentation (1 results)

  • [Journal Article] Rate constants and kinetic isotope effects on the reaction of C_2(X^Σ_g^+) with CH_4 and CD42010

    • Author(s)
      A. Matsugi, K. Suma, A. Miyoshi
    • Journal Title

      J. Phys.Chem.A 114

      Pages: 4580-4585

  • [Journal Article] Spectroscopic detection of isolated carbonic acid2009

    • Author(s)
      T. Mori, K. Suma, Y. Sumiyoshi, Y. Endo
    • Journal Title

      J.Chem.Phys. 130

      Pages: 204308-204315

  • [Presentation] 酸素を含むラジカル、ラジカル分子錯体のマイクロ波分光2008

    • Author(s)
      須磨航介
    • Organizer
      日本分光学会年次講演会
    • Place of Presentation
      東北大学
    • Year and Date
      2008-11-19

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Published: 2011-06-18   Modified: 2016-04-21  

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