2009 Fiscal Year Final Research Report
Development of Chiral Azolium Salts as a Phase-Transfer Catalyst
| Project/Area Number |
20850021
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| Research Category |
Grant-in-Aid for Young Scientists (Start-up)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
OHMATSU Kohsuke Nagoya University, 大学院・工学研究科, 助教 (00508997)
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| Project Period (FY) |
2008 – 2009
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| Keywords | 有機分子触媒 / 不斉合成 / オニウム塩 / 相間移動触媒 |
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| Research Abstract |
A series of chiral triazolium salts have been designed as a new class of chiral phase-transfer catalyst, and readily prepared from easily available optically pure α-amino acids. The reactivity and selectivity of these chiral triazolium salts as chiral phase-transfer catalysts have been evaluated in the asymmetric cyanation and alkylation under mild liquid-liquid phase-transfer conditions.
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